超分子化合物［（4，4′-联吡啶）3H5］［PMo10V2O40］·3H2O

水热合成与表征

Abstract

Abstract: A novel Keggin-type supramolecular compound，［（4，4′-bipy）3H5］［PMo10V2O40］·3H2O，has been synthesized under hydrothermal condition and characterized by elemental analysis，IR，and single crystal X-ray diffraction.It crystallized in the monoclinic system， space group C2/c，cell parameter a=1.5349（9） nm，b=1.813 （1） nm，c=2.097 （8） nm，α=90°，β=101.36°，γ=90°，V=5.725（2） nm3，Z=4，R1=0.050 7，and wR2=0.163 8.

Key words: polyoxometalate, supramolecular, hydrothermal synthesis, crystal structure, Keggin

CAO Jian-Fang, HUANG Zi-Ping, SUN Chun-Yan, CHENG Chun-Chun. Hydrothermal synthesis and characterization of supramolecular compound ［（4，4′-bipy）3H5］［PMo10V2O40］·3H2O[J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(9): 72-.

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[2]	Chen Yanguang,Han Tong,Zhang Yanan,Yang Xiuqi,Han Hongjing,Wang Hao. Process regulation of ZSM-5 zeolite synthesis from hydrolyzed tetraethyl orthosilicate as silicon source in acidic medium [J]. Inorganic Chemicals Industry, 2020, 52(7): 88-93.
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[5]	Fu Xin. Hydrothermal synthesis of TiO2 nanoparticles and photoluminescence properties thereof [J]. Inorganic Chemicals Industry, 2019, 51(10): 32-35.
[6]	DI Jun, HUANG Chun-Hui, ZHANG Qin, ZHAO Na, ZONG Jun. Research on preparation of heavy MgO by brucite-alkali method [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(9): 33-.
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National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Hydrothermal synthesis and characterization of supramolecular compound ［（4，4′-bipy）3H5］［PMo10V2O40］·3H2O

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