micropore structure,chiral sodium zincophosphate,template,chiral control,"/> Synthesis of chiral sodium zincophosphate with micropore structure and study on effect of chiral structure

INORGANICCHEMICALSINDUSTRY ›› 2014, Vol. 46 ›› Issue (12): 41-.

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Synthesis of chiral sodium zincophosphate with micropore structure and study on effect of chiral structure

 SUN  Ya-Bo, LI   Jing, ZHAO  Zhi-Cai, HE  Xiao-Yun, TIAN  Ke-Qing   

  1. Department of Chemical and Environment Engineering,Hebei Chemical and Pharmaceutical College,Shijiazhuang 050026,China
  • Online:2014-12-10 Published:2014-12-08

Abstract: Chiral sodium zincophosphate with  micropore structure and P6122 space group was prepared by room temperature solid phase method with Na3PO4·12H2O and ZnSO4·7H2O as raw materials and with PEG-400 as template.The influence of amount-of-substance ratio of P/Zn,crystallization time,and different templates on the chiral performance of product was investigated.The morphology and composition of product were characterized by XRD,SEM,and IR.Experimental results indicated that the amount-of-substance ratio of P/Zn and template′s structure were the key factors to control the chiral product,and the crystallization time only influenced the crystallization degree.

Key words: micropore structure')">

micropore structure, chiral sodium zincophosphate, template, chiral control