INORGANICCHEMICALSINDUSTRY ›› 2011, Vol. 43 ›› Issue (2): 53-.

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Research on equilibrium of extraction of wet-process phosphoric acid by alcohol-ester compound extractant

Zhang Li1,Ding Yao2,Ding Yigang2,Li Xin2   

  1. 1.School of Environment and Urban Construction,Wuhan Institute of Technology,Wuhan 430073,China;
    2.School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology
  • Published:2011-04-19

Abstract: With alcohol-ester compound extractant as the object,liquid equilibrium of extraction of wet-process phosphoric acid (WPA) solvent was studied.WPA distribution curves of compound extractant-WPA system at the phase equilibrium temperatures of 25,45,60,70 ℃ were measured.Relations of WPA distribution coefficient with temperature,phase ratio,and initial WPA concentration were investigated.Results showed that the compound extractant′s maximum mass fraction of WPA extration did not exceed 50%;the influences of temperature and phase ratio on distribution coefficient were very little,but initial concentration of aqueous phosphoric acid had large influence on distribution coefficient.   

Key words: compound extractant, liquid-liquid equilibrium, distribution coefficient

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