金属有机框架材料在天然气纯化和存储领域的应用

doi:10.19964/j.issn.1006-4990.2022-0392

Abstract

Abstract:

Metal-organic frameworks（MOFs） have received wide attention as new adsorbent materials for gas separation and storage due to their excellent pore characteristics and flexible structure adjustability.However，MOFs solid adsorbents need to be systematically design in the field of natural gas purification and storage.The separation of carbon dioxide and hydrogen sulfide in natural gas purification process was briefly reviewed，which would improve the purity of gas and lay a foundation for efficient storage.Then，the consideration of using MOFs for natural gas storage from two angles of adsorption and desorption was discussed.Finally，the thought of MOFs design and synthesis and the challenge of stability and versatility in the field of natural gas purification and storage were summarized to improve the possibility of MOFs adsorbents′ wide use in the future.

Key words: metal-organic frameworks, natural gas purification, natural gas storage

CLC Number:

TB383

CHEN Xinyi, ZHANG Hua, FANG Wei, XU Xiaofeng. Application of metal-organic frameworks in fields of natural gas purification and storage[J]. Inorganic Chemicals Industry, 2023, 55(4): 13-19.

Figures/Tables 4

Table 1

Fig.1

Fig.2

Fig.3

References 26

1	李鹭光.中国天然气工业发展回顾与前景展望[J].天然气工业，2021，41（8）：1-11.
	LI Luguang.Development of natural gas industry in China：Review and prospect[J].Natural Gas Industry，2021，41（8）：1-11.
2	孟凡飞，张雁玲，王海波，等.吸附天然气存储材料的研究进展[J].石油化工，2019，48（2）：209-216.
	MENG Fanfei， ZHANG Yanling， WANG Haibo，et al.Research progress of storage materials for adsorption natural gas[J].Petrochemical Technology，2019，48（2）：209-216.
3	李风亭，郑璐.金属有机框架化合物在气体存储和分离方面的研究进展[J].世界科学，2021（4）：35-36.
	LI Fengting， ZHENG Lu.Research progress of organometallic framework compounds in gas storage and separation[J].World Science，2021（4）：35-36.
4	LI Hao， LI Libo， LIN Ruibiao，et al.Porous metal-organic frameworks for gas storage and separation：Status and challenges[J].EnergyChem，2019，1（1）.Doi：10.1016/j.enchem.2019.100006 .
5	LI Jianrong， SCULLEY J， ZHOU Hongcai.Metal-organic frameworks for separations[J].Chemical Reviews，2012，112（2）：869-932.
6	MA Shengqian， ZHOU Hongcai.Gas storage in porous metal-organic frameworks for clean energy applications[J].Chemical Communications，2010，46（1）：44-53.
7	刘昌俊.溶剂吸附法回收熟料窑尾气中CO₂ [J].山东冶金，2004，26（5）：56-58.
	LIU Changjun.Ecovery of CO₂ from grog kiln tail gas by solvent adsorption[J].Shandong Metallurgy，2004，26（5）：56-58.
8	申屠佩兰.二氧化碳膜分离材料研究进展[J].能源化工，2021，42（5）：27-32.
	SHENTU Peilan.Research progress of carbon dioxide membrane separation materials[J].Energy Chemical Industry，2021，42（5）：27-32.
9	杨支秀，鲁博，郭丁丁，等.CO₂捕集及分离方法研究现状与进展[J].山东化工，2020，49（18）：62-64.
	YANG Zhixiu， LU Bo， GUO Dingding，et al.Research status and progress of CO₂ capture and separation methods[J].Shandong Chemical Industry，2020，49（18）：62-64.
10	杭咏平，李金昊，代钢，等.多孔固体吸附剂的CO₂吸附性能研究[J].应用化工，2020，49（11）：2877-2881.
	HANG Yongping， LI Jinhao， DAI Gang，et al.Research progress on CO₂ adsorption properties of porous solid adsorbents[J].Applied Chemical Industry，2020，49（11）：2877-2881.
11	李飒，林千果，徐冬，等.膜分离-变压吸附协同捕集低浓度烟气二氧化碳工艺模拟研究[J].现代化工，2021，41（9）：201-205.
	LI Sa， LIN Qianguo， XU Dong，et al.Simulation of low-concentration carbon dioxide captured by synergic process of membrane separation and pressure swing adsorption[J].Modern Chemical Industry，2021，41（9）：201-205.
12	CHAE H K， SIBERIO-PÉREZ D Y， KIM J，et al.A route to high surface area，porosity and inclusion of large molecules in crystals[J].Nature，2004，427（6974）：523-527.
13	BABARAO R， HU Zhongqiao， JIANG Jianwen，et al.Storage and separation of CO₂ and CH₄ in silicalite，C₁₆₈ schwarzite，and IRMOF-1：A comparative study from Monte Carlo simulation[J].Langmuir，2007，23（2）：659-666.
14	FLAIG R W， OSBORN POPP T M， FRACAROLI A M，et al.The chemistry of CO₂ capture in an amine-functionalized metal-organic framework under dry and humid conditions[J].Journal of the American Chemical Society，2017，139（35）：12125-12128.
15	XUE Wenlong， WANG Lu， LI Yukun，et al.Reticular chemistry for ionic liquid-functionalized metal-organic frameworks with high selectivity for CO₂ [J].ACS Sustainable Chemistry & Engineering，2020，8（50）：18558-18567.
16	朱学军，宋宛霖.天然气深度脱硫技术开发与工艺应用总结[J].炼油技术与工程，2022，52（5）：1-5.
	ZHU Xuejun， SONG Wanlin.Development and application of natural gas deep desulfurization technology[J].Petroleum Refinery Engineering，2022，52（5）：1-5.
17	朱雯钊，薛靖文，王毅，等.离子液体用于天然气脱硫脱碳研究进展[J].石油与天然气化工，2021，50（6）：14-20.
	ZHU Wenzhao， XUE Jingwen， WANG Yi，et al.Research progress in natural gas desulfurization and decarbonization by using ionic liquids[J].Chemical Engineering of Oil & Gas，2021， 50（6）：14-20.
18	HAMON L， SERRE C， DEVIC T，et al.Comparative study of hydrogen sulfide adsorption in the MIL-53（Al，Cr，Fe），MIL-47（V），MIL-100（Cr），and MIL-101（Cr） metal-organic frameworks at room temperature[J].Journal of the American Chemical Society，2009，131（25）：8775-8777.
19	PETIT C， MENDOZA B， BANDOSZ T J.Hydrogen sulfide adsorption on MOFs and MOF/graphite oxide composites[J].Chem PhysChem，2010，11（17）：3678-3684.
20	张园园，李红强.压缩天然气供气及CNG加气母站优化运行[J].电气防爆，2022（2）：43-46.
	ZHANG Yuanyuan， LI Hongqiang.Application of compressed natural gas supply in Hanzhong area and optimized operation of CNG filling bus station[J].Electric Explosion Protection， 2022（2）：43-46.
21	COOK T L， KOMODROMOS C， QUINN D F，et al.Carbon materials for advanced technologies[M].Amsterdam：Elsevier，1999：269-302.
22	MASON J A， VEENSTRA M， LONG J R.Evaluating metal-organic frameworks for natural gas storage[J].Chemical Science，2014，5（1）：32-51.
23	GARRONE E， BONELLI B， OTERO AREÁN C.Enthalpy-entropy correlation for hydrogen adsorption on zeolites[J].Chemical Physics Letters，2008，456（1/2/3）：68-70.
24	HUANG B L， NI Z， MILLWARD A，et al.Thermal conductivity of a metal-organic framework（MOF-5）：Part II.Measurement[J].International Journal of Heat and Mass Transfer，2007，50（3/4）：405-411.
25	LIU D， PUREWAL J J， YANG J，et al.MOF-5 composites exhibiting improved thermal conductivity[J].International Journal of Hydrogen Energy，2012，37（7）：6109-6117.
26	ETHIRAJ J， BONINO F， LAMBERTI C，et al.H₂S interaction with HKUST-1 and ZIF-8 MOFs：A multitechnique study[J].Microporous and Mesoporous Materials，2015，207：90-94.

[1]	CHEN Xingliang, FAN Wenjuan, CHANG Hui, HUANG Haiping, JIANG Zhiqiang. Study on collaborative strategy between Fe³⁺ and Ni-based metal-organic frameworks for boosting electrocatalytic oxygen evolution [J]. Inorganic Chemicals Industry, 2024, 56(2): 152-158.
[2]	DU Miao,MOU Yujin,WANG Shihao,QIU Xinjian,WANG Li,JI Changjian. Research progress on preparation technology of two-dimensional metal-organic frameworks materials [J]. Inorganic Chemicals Industry, 2021, 53(12): 49-53.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Application of metal-organic frameworks in fields of natural gas purification and storage

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 4

References 26

Related Articles 2

Metrics

Comments

Recommended 0