新型无机磷基阻燃剂的研究进展

doi:10.19964/j.issn.1006-4990.2022-0047

Abstract

Abstract:

Black phosphorus-based flame retardants，the representative of new nano inorganic phosphorus-based flame retardants，can achieve simultaneous improvement of the flame retardancy and mechanical properties of polymers at a low addition amount，showing good application prospects.The research progress on new inorganic phosphorus-based flame retardants was reviewed.The functional strategy，preparation process，flame retardant mechanism and application progress of black phosphorus-based flame retardants were mainly introduced.Finally，the development trend was prospected.The preparation of black phosphorus by nanoscale processes such as ultrasonic exfoliation，ball-milling exfoliation，electrochemical intercalation exfoliation，and targeted covalent or non-covalent modification strategies using flame-retardant organic/inorganic substances were reviewed.The advantages and disadvantages of composite preparation processes including solution blending，melt blending，in-situ polymerization and coating were analyzed.The rules between the structure and properties of black phosphorus-based flame retardants were summarized.Future research priorities in both scientific innovation and engineering breakthroughs were proposed.

Key words: inorganic phosphorus-based flame retardant, black phosphorus, modification strategy, flame-retardant mechanism

CLC Number:

TQ115

LIU Chang,DUAN Zunbin,WANG Jiannan,MA Huijuan,WANG Jiahong,YU Xuefeng. Research progress on new inorganic phosphorus-based flame retardants[J]. Inorganic Chemicals Industry, 2022, 54(11): 8-17.

Figures/Tables 3

Fig.1

Table 1

Fig.2

References 78

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阻燃剂	纳米化工艺	修饰策略	添加量/%	基材	复合工艺	φ_pHHR/%	φ_THR/%	LOI/%	UL94
BP^[9]	超声剥离	—	0.2	WPU	溶液共混	51.5	—	24.2	—
BP/G^[49]	超声剥离	无机非共价	3.6	WPU	溶液共混	13.6	10.9	—	—
BP-PZN^[50]	超声剥离	有机共价	2.0	EP	溶液共混	29.7	31.8	—	—
BP-Exf^[44]	电化学剥离	有机共价	3.0	PUA	溶液共混	14.8	11.5	—	—
BP-CNTs^[68]	球磨剥离	无机共价	2.0	EP	溶液共混	27.9	20.6	—	—
BP/MF^[52]	超声剥离	有机非共价	1.2	EP	溶液共混	36.1	—	31.1	V-0
BP/TA^[59]	超声剥离	有机非共价	2.0	TPU	溶液共混	28.3	21.5	—	—
BP-CTAB^[41]	超声剥离	有机共价	2.0	PLA	溶液共混	19.4	4.1	23.0	—
BP/RuL₃^[64]	超声剥离	有机非共价	3.0	EP	溶液共混	20.7	11.7	31.3	V-0
BP/PDA^[65]	超声剥离	有机非共价	5.0	PVA	溶液共混	11.4	9.6	—	—
BP/PEI^[62]	电化学剥离	有机非共价	2.0	WPU	溶液共混	17.2	10.6	23.5	V-2
BP/CNTs^[51]	球磨剥离	无机非共价	20.0	NFC	溶液共混	1.9	2.2	29.9	V-0
BP-MoS₂^[55]	球磨剥离	无机共价	20.0	GOF	涂层	2.7	—	—	—
BP/PDA^[70]	超声剥离	有机非共价	1.2	PU	溶液共混	26.8	17.8	—	—
BP/CN^[56]	超声剥离	无机非共价	2.0	EP	溶液共混	23.9	24.8	31.0	V-1
BP-HAN^[63]	超声剥离	有机共价	2.0	EP	溶液共混	28.0	24.1	31.5	V-0
BP-HPL^[60]	球磨剥离	有机共价	2.0	TPU	溶液共混	25.0	24.5	—	—
BP/G-MF^[73]	超声剥离	有机无机非共价	3.0	EP	溶液共混	14.6	9.2	—	—
BP-G^[42]	球磨剥离	无机共价	5.0	EP	原位聚合	—	—	27.5	V-0
BP-ZHS^[58]	球磨剥离	无机共价	2.0	PP	熔融共混	16.3	8.9	22.7	—
BP/BN^[57]	超声剥离	无机非共价	0.4	WPU	溶液共混	—	59.8	33.8	—

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Research progress on new inorganic phosphorus-based flame retardants

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