水溶液中均匀硫化镉微球的制备及其在结构色中的应用

doi:10.19964/j.issn.1006-4990.2021-0618

Abstract

Abstract:

Uniform cadmium sulfide（CdS） microspheres have high refractive index,and the photonic crystals composed of them have bright color and low angle dependence,which have been widely used in the field of structural color in recent years.However,the current mature methods for the preparation of uniform CdS microspheres have some problems,such as the large use of organic solvents and high energy consumption at high temperature.Therefore,a green preparation method for preparing uniform CdS microspheres in aqueous solution was designed.The controlled injection assisted feeding solved the problem of unbalanced growth of microspheres caused by too fast hydrolysis of metal salt precursors in water.At the same time,the controlled injection method could be more conducive to controlling the concentration of Cd²⁺ in the system and successfully synthesized uniform CdS microspheres with 180~410 nm.Further,three-dimensional photonic crystal structures based on CdS microspheres with different particle sizes were constructed by horizontal induced assembly.This photonic crystal film showed bright and low angle dependent structural color,which was more conducive to the application of structural color in color display and other fields.

Key words: CdS microspheres, synthesis in aqueous solution, bright structural color, low-angle dependence

CLC Number:

TQ132.44

NAN Jinjian,WU Suli. Preparation of uniform cadmium sulfide microspheres in aqueous solution and their application in structural color[J]. Inorganic Chemicals Industry, 2022, 54(4): 94-99.

Figures/Tables 7

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References 23

[1]	DAQIQEH R S, DONG Z G, CHAN J Y E, et al. Nanophotonic structural colors[J]. ACS Photonics, 2020, 8(1):18-33. doi: 10.1021/acsphotonics.0c00947
[2]	WU S L, LIU B Q, SU X, et al. Structural color patterns on paper fabricated by inkjet printer and their application in anticounterfeiting[J]. Journal of Physical Chemistry Letters, 2017, 8(13):2835-2841. doi: 10.1021/acs.jpclett.7b01372
[3]	ZHANG Y, WANG Y, WANG H, et al. Super-elastic magnetic structural color hydrogels[J]. Small, 2019, 15(35).Doi: 10.1002/smll.201902198. doi: 10.1002/smll.201902198
[4]	WU Y, REN J, ZHANG S, et al. Nanosphere-aggregation-induced reflection and its application in large-area and high-precision panchromatic inkjet printing[J]. ACS Applied Materials & Interfaces, 2020, 12(9):10867-10874.
[5]	ZHONG K, LI J, LIU L, et al. Instantaneous,simple,and reversible revealing of invisible patterns encrypted in robust hollow sphere colloidal photonic crystals[J]. Advanced Materials, 2018, 30(25).Doi: 10.1002/adma.201707246. doi: 10.1002/adma.201707246
[6]	WU Y, WANG Y, ZHANG S, et al. Artificial chameleon skin with super-sensitive thermal and mechanochromic response[J]. ACS Nano, 2021, 15(10):15720-15729. doi: 10.1021/acsnano.1c05612
[7]	WU S, LIU T, TANG B, et al. Structural color circulation in a bilayer photonic crystal by increasing the incident angle[J]. ACS Applied Materials & Interfaces, 2019, 11(10):10171-10177.
[8]	MENG Y, QIU J, WU S, et al. Biomimetic structural color films with a bilayer inverse heterostructure for anticounterfeiting applications[J]. ACS Applied Materials & Interfaces, 2018, 10(44):38459-38465.
[9]	MENG Z, HUANG B, WU S, et al. Bio-inspired transparent structural color film and its application in biomimetic camouflage[J]. Nanoscale, 2019, 11(28):13377-13384. doi: 10.1039/C9NR04360H
[10]	LIU P, BAI L, YANG J, et al. Self-assembled colloidal arrays for structural color[J]. Nanoscale Advances, 2019, 1(5):1672-1685. doi: 10.1039/C8NA00328A
[11]	MENG Z, WU Y, ZHANG S, et al. Sharp scattering spectra induced brilliant and directional structural colors[J]. Science China Materials, 2021, 64(2):420-429. doi: 10.1007/s40843-020-1402-x
[12]	MENG Z P, WU S L, TANG B T, et al. Structurally colored polymer films with narrow stop band,high angle-dependence and good mechanical robustness for trademark anti-counterfeiting[J]. Nanoscale, 2018, 10(30):14755-14762. doi: 10.1039/C8NR04058C
[13]	LOTITO V, ZAMBELLI T. Playing with sizes and shapes of colloidal particles via dry etching methods[J]. Advances in Colloid and Interface Science, 2021.Doi: 10.1016/j.cis.2021.102538. doi: 10.1016/j.cis.2021.102538
[14]	WANG Z, MENG F, ZHANG S, et al. Robust,portable,and specific water-response silk film with noniridescent pattern encryption for information security[J]. ACS Applied Materials & Interfaces, 2020, 12(50):56413-56423.
[15]	ZHAO T H, JACUCCI G, CHEN X, et al. Angular-independent photonic pigments via the controlled micellization of amphiphilic bottlebrush block copolymers[J]. Advanced Materials, 2020, 32(47).Doi: 10.1002/adma.202002681. doi: 10.1002/adma.202002681
[16]	SU X, XIA H B, ZHANG S F, et al. Vivid structural colors with low angle dependence from long-range ordered photonic crystal films[J]. Nanoscale, 2017, 9(9):3002-3009. doi: 10.1039/C6NR07523A
[17]	LI X-H, LI J-X, LI G-D, et al. Controlled synjournal,growth mechanism,and properties of monodisperse CdS colloidal spheres[J]. Chemistry-a European Journal, 2007, 13(31):8754-8761. doi: 10.1002/chem.200700754
[18]	TANG C J, YANG Y X, ZHANG D M, et al. Facile synjournal of monodisperse CdS nanospheres capped with allyl thiourea[J]. Materials Science and Technology, 2013, 29(3):370-373. doi: 10.1179/1743284712Y.0000000195
[19]	LI G, JIANG L, PENG H, et al. Self-assembled cadmium sulfide microspheres from nanorods and their optical properties[J]. Materials Letters, 2008, 62(12):1881-1883. doi: 10.1016/j.matlet.2007.10.029
[20]	ZHANG B, JIAN J K, ZHENG Y, et al. Low temperature hydrothermal synjournal of CdS submicro- and microspheres self-assembled from nanoparticles[J]. Materials Letters, 2008, 62(12/13):1827-1830. doi: 10.1016/j.matlet.2007.10.013
[21]	SUGIMOTO T, DIRIGE G E, MURAMATSU A. Synjournal of monodisperse CdS and ZnS particles from concentrated solutions of the EDTA-metal complexes[J]. Journal of Colloid and Interface Science, 1996, 180(1):305-308. doi: 10.1006/jcis.1996.0307
[22]	LIBERT S, GOIA D V, MATIJEVIC E. Internally composite uniform colloidal cadmium sulfide spheres[J]. Langmuir, 2003, 19(26):10673-10678. doi: 10.1021/la030205w
[23]	WANG C, ZHANG H, LIN Z, et al. Cationic ligand protection:A novel strategy for one-pot preparation of narrow-dispersed aqueous CdS spheres[J]. Langmuir, 2009, 25(17):10237-10242. doi: 10.1021/la9010407

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Inorganic Acid-Base-Salt Committee of CIESC

Preparation of uniform cadmium sulfide microspheres in aqueous solution and their application in structural color

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