黑磷的液相法制备研究进展

doi:10.19964/j.issn.1006-4990.2021-0311

Abstract

Abstract:

Because of its unique structure and excellent performance,black phosphorus has performed good application prospects in many fields.At present,the application of black phosphorus is still limited by its preparation methods and stripping methods.Liquid phase method is a method of synthesizing black phosphorus under liquid phase conditions,mainly including mercury reflux method,bismuth melting method and solvent thermal method.Liquid phase method can prepare nano black phosphorus in one step,which has the advantages of simple operation,mild reaction conditions and strong controllabi-lity.It is the most likely method to realize the low-cost and controllable preparation of nano black phosphorus at present.The research status of preparation of black phosphorus by liquid phase method was reviewed.The advantages and disadvantages of this method were analyzed and discussed.In view of the problems of poor crystallinity,low yield and instability of the black phosphorus prepared by this method,it was proposed that choosing appropriate solvent and adjusting reaction temperature were expected to prepare a new structure of nano black phosphorous based materials and improve the crystallinity and yield of black phosphorous.At the same time,in the preparation process to achieve in situ doping or formation of composite materials were expected to improve the stability of black phosphorous,and then broadened the application field of black phosphorous and improved the performance of black phosphorous.

Key words: black phosphorus, liquid phase method, mercury reflux method, bismuth melting method, solvothermal method

CLC Number:

TQ126.31

LU Xiaomin,LI Xuemei,LIU Lanjun,SHEN Xiaofang,MEI Yi,LIAN Peichao. Research progress in preparation of black phosphorus by liquid phase method[J]. Inorganic Chemicals Industry, 2022, 54(3): 31-37.

Figures/Tables 11

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References 27

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样品	T/℃	t/h	d（红磷）/μm	ρ（红磷）/（g·L^-1）	带隙/eV	I（红磷）/a.u.^[a]	I（黑磷）/a.u.^[b]	I（黑磷）/I（红磷+黑磷）/%	d（黑磷晶体）/nm
1	140	12	23	15	1.88	397	14	3.3	—
2	150	12	23	15	1.56	288	35	10.7	—
3	160	12	23	15	1.55	183	108	37.2	68（17）
4	170	12	23	15	1.55	165	63	27.7	—
5	160	12	23	15	1.55	190	108	36.3	68（17）
6	160	24	23	15	1.55	190	280	59.6	298（16）
7	160	48	23	15	1.55	211	176	45.4	109（10）
8	160	24	23	15	1.55	142	280	66.3	298（16）
9	160	24	68	15	1.55	29	542	94.9	195（10）
10	160	24	1 300	15	1.88	247	3	1.2	—
11	160	24	68	3.75	1.60	222	9	3.8	—
12	160	24	68	7.5	1.60	176	101	36.5	178（7）
13	160	24	68	15	1.55	29	542	94.9	195（8）
14	160	24	68	30	1.56	18	551	96.8	219（7）

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Research progress in preparation of black phosphorus by liquid phase method

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