锂/钠离子电池过渡金属氟磷酸盐正极材料研究进展

doi:10.11962/1006-4990.2019-0602

Abstract

Abstract:

With the rapid development of portable electronic products,electric vehicles and energy storage,the demand for high energy density batteries is more and more urgent.Cathode materials are the main limits for the energy-density of batteries.Transition metal fluoride phosphates（A₂MPO₄F;A=Li,Na;M=Mn,Fe,Co,Ni） is a type of competitive cathode materials with high-capacity（~300 mA·h/g） and high energy density（>1 000 W·h/kg）.The research progress related to the A₂MPO₄F cathode materials on the structures,synthesis methods and improving techniques for electrochemical performance were mainly introduced.The key challenges of A₂MPO₄F cathode materials faced,especially the difficulties in realizing the two electron reaction,were discussed.Finally,the future trends and perspectives for performance enhancement were prospected.

Key words: lithium-ion batteries, sodium-ion batteries, cathode materials, transition metal fluoride phosphates

CLC Number:

TQ126.35

Long Yunfei,Su Jing,Lü Xiaoyan,Wen Yanxuan. Advances in transition metal fluoride phosphate cathode materials for lithium-ion batteries and sodium-ion batteries[J]. Inorganic Chemicals Industry, 2020, 52(3): 28-34.

Figures/Tables 4

References 62

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A	M	A₂MPO₄F/AMPO₄F			AMPO₄F/MPO₄F			能量密度/（W· h·kg^-1）
A	M	电压/ V	ΔV/ %	Q/ （mA·h·g^-1）	电压/ V	ΔV/ %	Q/ （mA·h·g^-1）	能量密度/（W· h·kg^-1）
Li	Mn	4.1	-1.2	~147	4.9	5.6	~294	~1 325
	Fe	3.5	-0.7	~146	5.0	7.8	~292	~1 246
	Co	4.8	-0.1	~144	5.2	7.1	~288	~1 441
	Ni	5.0	3.0	~144	5.3	10.5	~288	~1 486
Na	Mn	3.7	8.0	~125	4.7	17.0	~250	~1 050

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Advances in transition metal fluoride phosphate cathode materials for lithium-ion batteries and sodium-ion batteries

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