无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (8): 83-87.doi: 10.11962/1006-4990.2018-0521

• 催化材料 • 上一篇    下一篇

氧化铝基质对催化裂化催化剂重油分子裂化性能的影响

熊晓云,胡清勋,赵红娟,高雄厚   

  1. 中国石油兰州化工研究中心,甘肃兰州 730060
  • 收稿日期:2019-02-10 出版日期:2019-08-10 发布日期:2020-06-15
  • 作者简介:熊晓云(1980— ),男,博士研究生,高级工程师,主要从事催化新材料和催化裂化催化剂研究,已公开发表论文10篇;E-mail:xiongxiaoyun@petrochina.com.cn。

Impact of alumina matrix on cracking performance of heavy oil molecule of FCC catalyst

Xiong Xiaoyun,Hu Qingxun,Zhao Hongjuan,Gao Xionghou   

  1. Lanzhou Petrochemical Research Center,PetroChina,Lanzhou 730060,China
  • Received:2019-02-10 Online:2019-08-10 Published:2020-06-15

摘要:

对工业拟薄水铝石做了深入表征,并详细研究了拟薄水铝石胶溶酸铝比、催化剂中拟薄水铝石含量以及铝溶胶含量对催化剂重油分子裂化性能的影响。研究显示,拟薄水铝石酸化酸铝比(体积质量比,mL/g)从0增至0.20,孔体积从0.39 cm3/g降至0.27 cm3/g,酸化后酸量先增加后减少,同时催化剂的孔体积下降,重油转化能力先增强后减弱;催化剂中拟薄水铝石质量分数从10%增至25%,催化剂重油转化能力逐渐增强,但随着拟薄水铝石含量的增加,重油产率下降趋势逐渐减小;铝溶胶含量增加将导致催化剂孔体积下降,催化剂重油转化能力下降。

关键词: 拟薄水铝石, 铝溶胶, 催化裂化, 重油转化

Abstract:

The industrial pseudo-boehmite was deeply characterized,and the impacts of pseudo-boehmite peptizing acid-to-alumina ratio,pseudo-boehmite content in the catalyst and alumina gel′s content on the cracking performance of heavy oil molecules of FCC catalysts were studied in detail.Results showed that when peptizing acid-to-alumina ratio(volume to massratio,mL/g) was increased from 0 to 0.20,pore volume of the catalyst was decreased from 0.39 cm3/g to 0.27 cm3/g.Acidity amount firstly increased and then decreased after acidification.Pore volume decreased and conversion ability of heavy oil firstly increased and then decreased.When pseudo-boehmite′s content in FCC catalyst was increased from 10% to 25%,conversion ability of heavy oil of the catalyst increased gradually,but with the increase of pseudo-boehmite content,the decreasing trend of heavy oil yield gradually decreased.The increase of alumina gel content would lead to a decrease in the pore volume of the catalyst and a decrease in the conversion capacity of the catalyst heavy oil.

Key words: pseudo-boehmite, alumina gel, catalytic cracking, heavy oil conversion

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