无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (7): 10-.

• 论文 • 上一篇    下一篇

江陵凹陷地下卤水50 ℃等温蒸发研究

张秀峰1,2,谭秀民1,2,伊跃军1,2,张利珍1,2   

  1. 1.中国地质科学院郑州矿产综合利用研究所,河南郑州 450006;
    2.国家非金属矿资源综合利用工程技术研究中心
  • 出版日期:2016-07-10 发布日期:2016-07-25

Isothermal evaporation experiment at 50 ℃ on underground brine of Jiangling Depression

Zhang Xiufeng1,2,Tan Xiumin1,2,Yi Yuejun1,2,Zhang Lizhen1,2   

  1. 1.Zhengzhou Institute of Multipurpose Utilization of Mineral Resources,CAGS,Zhengzhou 450006,China;
    2.China National Engineering Research Center for Utilization of Industrial Minerals
  • Online:2016-07-10 Published:2016-07-25

摘要: 对江陵凹陷地下卤水进行了50 ℃等温蒸发实验。结果表明,江陵地下卤水在50 ℃等温蒸发过程中的析盐顺序为:氯化钠→氯化钠+氯化钾→氯化钠+氯化钾+氯化铵→氯化钠+氯化钾+氯化铵+硼酸,蒸发前期(蒸失率小于83.83%)只析出氯化钠,蒸发中期(蒸失率为83.83%~94.61%)开始析出氯化钾和氯化铵,蒸发末期(蒸失率大于94.61%)开始析出硼酸;微量元素锂、铷、铯、碘和溴高度富集于老卤中,有利于其综合利用。

关键词: 江陵凹陷, 地下卤水, 等温蒸发, 析盐规律

Abstract: The isothermal evaporation experiment at 50 ℃ on the underground brine of Jiangling Depression was carried out. Results showed that sodium chloride,potassium chloride,ammonium chloride,and sassolite were crystallizated out sequen- tially during the isothermal evaporation process,i.e.NaCl→NaCl+KCl→NaCl+KCl+NH4Cl→NaCl+KCl+NH4Cl+B(OH)3.In the early age of evaporation,there was only NaCl(evaporation loss less than 83.83%),in the medium age of evaporation,KCl and NH4Cl began to salt out(evaporation loss was at 83.83%~94.61%),and in the end,B(OH)3 started to crystallizate out (evaporation loss more than 94.61%).Also,the concentration of lithium,rubdium,cesium,iodine,and bromine were enriched greatly in the old brine.The study provided an important basis for comprehensive utilization of this underground brine.

Key words: Jiangling Depression, underground brine;isothermal evaporation;salt crystallization law

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