无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (2): 53-.

• 论文 • 上一篇    下一篇

油页岩灰渣酸法制备纳米白炭黑碱浸工艺研究

周建敏,陈宇宁,谭丽泉,李泽胜,牛显春   

  1. 广东石油化工学院,广东茂名 525000
  • 出版日期:2016-02-10 发布日期:2016-02-18

Study on process of alkaline leaching for acidic preparation of nano-silica by oil shale ash

 ZHOU  Jian-Min, CHEN  Yu-Ning, TAN  Li-Quan, LI  Ze-Sheng, NIU  Xian-Chun   

  1. Guangdong University of Petrochemical Technology,Maoming 525000, China
  • Online:2016-02-10 Published:2016-02-18

摘要: 以茂名油页岩灰渣为原料,采用酸法制备白炭黑,考察了碱浸条件对二氧化硅产率的影响。实验得到制取白炭黑的最佳碱浸工艺:碱浓度为3 mol/L、碱用量(氢氧化钠与二氧化硅的物质的量比)为4∶1、碱浸时间为4.0 h、碱浸温度为90 ℃。在最佳条件下,白炭黑的产率为63.79%,粒径为54 nm。制得的白炭黑符合HG/T 3061—1999《橡胶配合剂 沉淀水合二氧化硅技术条件》的要求。

关键词: 油页岩灰渣, 纳米白炭黑, 酸法, 碱浸, 产率

Abstract: Using the oil shale ash in Maoming,Guangdong as the raw material,nano-silica was prepared by acid leaching process.The effect of parameters of alkaline leaching process on yield of silica was particularly studied,and the optimum conditions were obtained:concentration of NaOH was 3 mol/L,amount-of-substance ratio of NaOH to SiO2 was 4∶1,leaching time was 4 h,and leaching temperature was 90 ℃.Under the optimal conditions,the yield of silica was 63.79% and the size of silica was 54 nm.The quality of prepared product could meet the requirement of the standard of HG/T 3061—1999.

Key words: oil shale ash, nano-sized silica, acidic method, alkaline leaching, yield

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