无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (6): 47-.

• 论文 • 上一篇    下一篇

碳分法制备易溶氢氧化铝研究

韩东战,樊大林,尹中林   

  1. 中国铝业股份有限公司郑州研究院,河南郑州 450041
  • 出版日期:2015-06-10 发布日期:2015-05-22

Study on synthesis of easing soluble aluminum hydroxide by carbonation decomposition

Han Dongzhan,Fan Dalin,Yin Zhonglin   

  1. Zhengzhou Research Institute of Chalco,Zhengzhou 450041,China
  • Online:2015-06-10 Published:2015-05-22

摘要: 通过无晶种碳分法制备了易溶氢氧化铝。研究了反应温度、通气速度、二氧化碳体积分数、铝酸钠溶液苛性比(氧化钠与氧化铝物质的量比)等条件对氢氧化铝酸溶率的影响。适宜工艺条件:反应温度为65~75 ℃、通气速度为400 L/h、二氧化碳体积分数为30%~38%、铝酸钠溶液苛性比为1.48。在此条件下制得氢氧化铝酸溶率大于95%。X射线衍射(XRD)和扫描电镜(SEM)表征表明,物相组成是影响氢氧化铝产品酸溶性的主要原因。

关键词: 易溶氢氧化铝, 碳分, 二氧化碳, 酸溶率, 晶体结构

Abstract: The easily soluble aluminum hydroxide was prepared by carbonation decomposition.The effects of decomposition temperature,gas passing velocity,volume fraction of CO2,and caustic molar ratio(amount?鄄of?鄄substance ratio of sodium oxide to alumina) of sodium aluminate solution etc.on the aluminum hydroxide′s acid solubility were investigated.Results showed that the optimum conditions:the carbonation decomposition temperature was 65~75 ℃,gas passing velocity was 400 L/h,the volume fraction of CO2 was 30%~38%,and the caustic molar ratio of sodium aluminate solution was 1.48.The acid soluble rate of the product was more than 95% under those conditions.The product was characterized by XRD and SEM,and the results showed the acid solubility mainly depended on the phase composition of aluminum hydroxide.

Key words: easing soluble aluminum hydroxide, carbonation decomposition, CO2, acid solubility, crystal structure