无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (7): 11-.

• 论文 • 上一篇    下一篇

多晶硅副产物四氯化硅的综合应用研究进展

赵 云,但建明,洪成林   

  1. 省部共建国家重点实验室培育基地,石河子大学化学化工学院,新疆生产建设兵团化工
    绿色过程重点实验室,新疆石河子832000
  • 出版日期:2014-07-10 发布日期:2014-07-07

Application research of silicon tetrachloride from polysilicon enterprises

 ZHAO   Yun, DAN  Jian-Ming, HONG  Cheng-Lin   

  1. Key Laboratory for Green Processing of Chemical Engineering of the Xinjiang Production and Construction Corps.,
    College of Chemistry and Chemical Engineering,Shihezi University,State Key Laboratory Cultivation Base Jointly
    Constructed by Province and the Ministry,Shihezi 832000,China
  • Published:2014-07-10 Online:2014-07-07

摘要: 随着清洁能源不断开发利用,光伏产业发展迅速,多晶硅产业应运而生。而生产多晶硅原料三氯氢硅的过程中会产生大量的副产物四氯化硅,其对环境污染较为严重。合理处理副产物四氯化硅,实现多晶硅绿色生产,意义重大。介绍了中国多晶硅副产物四氯化硅的应用现状,详细介绍了四氯化硅制备三氯氢硅、白炭黑、硅酸酯类、光纤原料高纯四氯化硅方面的制备原理、制备工艺及其优缺点,并对未来的发展趋势进行了展望。

关键词: 四氯化硅, 三氯氢硅, 白炭黑, 硅酸酯类, 光纤原料高纯四氯化硅

Abstract: With the sustainable development and utilization of clean energy,the development of photovoltaic industry was rapidly and poly-silicon industry emerged as the times demand.While producing trichlorosilane which was the raw material of preparing poly-silicon,a large amount of silicon tetrachloride as by-product was also manufactured,which was serious pollution to the environment.Therefore,rational treatment for silicon tetrachloride and realization of green production of poly-silicon industry was of great significance.The application status of silicon tetrachloride in China was reviewed.Principle and technology in the preparation of trichlorosilane,silica,silicate,and high purity silicon tetrachloride for optical fiber from silicon tetrachloride were introduced in detail and their merits and demerits were evaluated.The development trend of comprehensive utilization of silicon tetrachloride was also prospected.

Key words: silicon tetrachloride, trichlorosilane, silica, silicate, high purity silicon tetrachloride for optical fiber

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