无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (4): 46-.

• 论文 • 上一篇    下一篇

高温固相法制备片状氧化铝及表征

赵燕禹1,胡兴兰1,张志鸿1,商连弟2   

  1. 1.天津职业大学生物与环境工程学院,天津 300410;2.中海油天津化工研究设计院
  • 出版日期:2014-04-10 发布日期:2014-04-08

Preparation and characterization of flaky alumina by high temperature solid phase method

Zhao Yanyu1,Hu Xinglan1,Zhang Zhihong1,Shang Liandi2   

  1. 1.School of Biology and Environment Engineering,Tianjin Vocational Institute,Tianjin 300410,China;
    2.CNOOC Tianjin Chemical Research & Design Institute
  • Published:2014-04-10 Online:2014-04-08

摘要: 利用高温固相法以不同粒度的氢氧化铝为原料制备片状α-氧化铝。通过激光粒度分析仪、扫描电子显微镜及X射线衍射仪对产品进行了表征,得出了最佳制备工艺条件。结果表明,在最佳制备条件下制备的片状α-氧化铝粒度在20 μm左右,径厚比为(5~8)∶1,大多为六角形片状。并首次提出了利用吸附-脱附等温线的重叠程度来表征片状氧化铝,可在片状氧化铝制备中应用。

关键词: 片状氧化铝, 高温固相法, 吸附-脱附等温线

Abstract: The flaky α-alumina is prepared by high-temperature solid phase method using aluminum hydroxide with different particle sizes as raw material.The products were characterized by laser particle size analyzer,scanning electron microscopy, and X-ray diffraction,and the optimum preparation conditions were determined.Result showed that flaky α-alumina under the optimum preparation conditions had the particle size about 20 μm,diameter to thickness ratio of(5~8)∶1,and most of hexagonal flakes.And the degree of overlap of adsorption-desorption isotherms to characterize flaky alumina was first used in its preparation.

Key words: flaky alumina, high-temperature solid phase method, adsorption-desorption isotherms

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