无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (9): 34-.

• 论文 • 上一篇    下一篇

醇析法合成过碳酸钠工艺优化研究

王友承,杨虎,吕亮,邓棹栩   

  1. 四川理工学院材料与化学工程学院,四川自贡 643000
  • 出版日期:2011-09-10 发布日期:2011-09-07

Study on optimization of synthesis technology of sodium percarbonate by ethanol deposition method

 WANG  You-Cheng, YANG  Hu, 吕Liang , DENG  Zhao-Xu   

  1. School of Materials and Chemical Engineering,Sichuan University of Science and Engineering,Zigong 643000,China
  • Published:2011-09-10 Online:2011-09-07

摘要: 为确定醇析法合成过碳酸钠工艺,对反应温度、原料配比、反应时间及乙醇加入量对产品活性氧含量与收率的影响进行了考察。最后得出,反应温度对产品收率和活性氧含量的影响最大,乙醇加入量次之,反应时间和原料配比也有一定影响。通过实验得出最佳实验条件:反应温度为15 ℃,原料配比(碳酸钠与过氧化氢物质的量比)为1∶1.5,双氧水滴加时间为15 min,乙醇加入量为60 mL,反应时间为60 min。

关键词: 过碳酸钠, 收率, 活性氧含量

Abstract: For sure the process conditions of sodium percarbonate by ethanol deposition method,effects of reaction temperature,mix ratio of raw materials,reaction time,and dosage of ethanol on the content of active oxygen and yield of product were investigated.Finally concluded that the reaction temperature had biggest influence on the product yield and active oxygen content,dosage of ethanol secondly and reaction time and mix ratio also had some influences.Through the experiment,the best experimental conditions were obtained as follows:reaction temperature was 15 ℃,mix ratio of raw materials (amount-of-substance ratio of sodium carbonate to hydrogen peroxide) was 1∶1.5,hydrogen peroxide droped for 15 min,ethanol dosage was 60 mL,and reaction time was 60 min. 

Key words: sodium percarbonate, yield, active oxygen content

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