Inorganic Chemicals Industry >
Study on solidification effect of slag-based solidifying agent on coal bed methane drilling waste mud cake
Received date: 2024-09-09
Online published: 2025-09-23
In order to reduce the pollution and damage of drilling production to the surrounding environment,the drilling mud cake was took as the research object,different proportions of slag-based solidification agents were added to solidify the drilling mud cake.The strength of the solidified body and the pH,suspended solids(SS),chromaticity,CODCr and other indicators of the leachate were used to evaluate its solidification effect.X-ray diffraction(XRD) and scanning electron microscopy(SEM) were used to reveal its curing mechanism.The results showed that the compressive strength of the solidified body was increased with the increase of solidifying agent dosage and the extension of curing time.When the dosage was 20%,the compressive strength of the solidified body after 7 d was 0.17 MPa,which met the requirements of in-situ paving.When the content was 10% after 7 d,all indicators of the solidified leachate could meet the first level standard in GB 8978—1996“Integrate wastewater discharge standard”,and the solidifying effect of the slag-based solidifying agent was significantly better than that of cement.It was found that the slag-based solidification agent generated hydration products such as hydrated calcium silicate aluminate(C-A-S-H) and hydrated calcium aluminate(C-A-H) through microscopical test,which cemented with mud cake particles to form network structure,making the structure denser.The results of this research could provide some useful guidance and theoretical basis for the disposal of drilling waste mud cake.
ZHAO Wenwei , DONG Mingkun , HAN Ximeng , DENG Zhengyun , ZHAO Changmin . Study on solidification effect of slag-based solidifying agent on coal bed methane drilling waste mud cake[J]. Inorganic Chemicals Industry, 2025 , 57(9) : 96 -103 . DOI: 10.19964/j.issn.1006-4990.2024-0490
| [1] | 房凯,张忠苗,刘兴旺,等.工程废弃泥浆污染及其防治措施研究[J].岩土工程学报,2011,33(S2):238-241. |
| FANG Kai, ZHANG Zhongmiao, LIU Xingwang,et al.Pollution of construction waste slurry and prevention measures[J].Chinese Journal of Geotechnical Engineering,2011,33(S2):238-241. | |
| [2] | CHEN Zhong, ZHENG Zhijian, LI Dongyuan,et al.Continuous supercritical water oxidation treatment of oil-based drill cuttings using municipal sewage sludge as diluent[J].Journal of Hazardous Materials,2020,384:121225. |
| [3] | NJUGUNA J, SIDDIQUE S, BAKAH KWROFFIE L,et al.The fate of waste drilling fluids from oil & gas industry activities in the exploration and production operations[J].Waste Management,2022,139:362-380. |
| [4] | PEREIRA L B, SAD C M S, CASTRO E V R,et al.Environmental impacts related to drilling fluid waste and treatment methods:A critical review[J].Fuel,2022,310:122301. |
| [5] | 杨宾,李银月,董明坤,等.不同絮凝剂对钻井泥浆的处理效果及絮凝机理[J].无机盐工业,2024,56(4):34-41. |
| YANG Bin, LI Yinyue, DONG Mingkun,et al.Treatment effect and flocculation mechanism of abandoned drilling mud by different flocculants[J].Inorganic Chemicals Industry,2024,56(4):34-41. | |
| [6] | CHENG Xiaowei, LONG Dan, ZHANG Chi,et al.Utilization of red mud,slag and waste drilling fluid for the synthesis of slag-red mud cementitious material[J].Journal of Cleaner Production,2019,238:117902. |
| [7] | XIONG Deming, WANG Chaoqiang, WANG Peixin,et al.Study on environment-friendly disposal and utilization of oil-based drilling cuttings solidified body of shale gas[J].Construction and Building Materials,2022,327:127043. |
| [8] | 陈曦,郭丽梅,喻可喆,等.钻井废泥浆絮凝脱水固化处理研究[J].环境工程技术学报,2017,7(4):495-499. |
| CHEN Xi, GUO Limei, YU Kezhe,et al.Study on solidification treatment for waste drilling fluid of flocculant dehydration[J].Journal of Environmental Engineering Technology,2017,7(4):495- 499. | |
| [9] | ZHANG Fawen, LI Yinyue, ZHANG Jinhui,et al.Effects of slag-based cementitious material on the mechanical behavior and heavy metal immobilization of mine tailings based cemented paste backfill[J].Heliyon,2022,8(9):e10695. |
| [10] | 杨子健,刘阳生.水基钻井固体废物处理处置技术研究进展[J].环境工程,2021,39(10):143-149. |
| YANG Zijian, LIU Yangsheng.Research progress on treatment and disposal of water-based drilling solid waste[J].Environmental Engineering,2021,39(10):143-149. | |
| [11] | 陈刚,王鹏,赵毅,等.废弃钻井液处理技术研究与应用进展[J].钻井液与完井液,2020,37(1):1-8. |
| CHEN Gang, WANG Peng, ZHAO Yi,et al.Progress in study and application of waste mud disposal technologies[J].Drilling Fluid & Completion Fluid,2020,37(1):1-8. | |
| [12] | 杨双春,佟双鱼,李东胜,等.废弃钻井液无害化处理技术研究进展[J].应用化工,2019,48(12):3037-3041. |
| YANG Shuangchun, TONG Shuangyu, LI Dongsheng,et al.Research progress on harmless disposal technology of waste drilling fluid[J].Applied Chemical Industry,2019,48(12):3037-3041. | |
| [13] | 蒋云云,范代娣,贾汉忠,等.新疆油田废弃水基钻井泥浆固化处理技术研究[J].石油化工应用,2015,34(6):88-90,98. |
| JIANG Yunyun, FAN Daidi, JIA Hanzhong,et al.Study on the solidification of Xinjiang waste water-based drilling mud[J].Petrochemical Industry Application,2015,34(6):88-90,98. | |
| [14] | 尹亚君,谢海燕,王博远,等.塔河油田钻井废弃泥浆无害化处理技术研究[J].环境科学与管理,2014,39(1):90-93. |
| YIN Yajun, XIE Haiyan, WANG Boyuan,et al.Research on harmless treatment of drilling mud waste from Tahe oilfield[J].Environmental Science and Management,2014,39(1):90-93. | |
| [15] | 国家环境保护总局. 污水综合排放标准: [S].北京:中国标准出版社,1998. |
| [16] | LEONARD S A, STEGEMANN J A.Stabilization/solidification of petroleum drill cuttings:Leaching studies[J].Journal of Hazardous Materials,2010,174(1/2/3):484-491. |
| [17] | DONG Wenkui, FENG Jianhua, YANG Xiaoqing.Synthesis and crystal structure of a five-coordinated Cu(Ⅱ) dimer with 4,4′-dibromo-2,2′-[ethylenedioxybis(nitrilomethylidyne)] diphenol[J].Synthesis and Reactivity in Inorganic,Metal-Organic,and Nano-Metal Chemistry,2007,37(3):189-192. |
| [18] | 张忠亮,金容旭,张雪梅,等.利用海上油气田水基钻井废物制备烧结砖[J].环境工程学报,2021,15(9):3020-3028. |
| ZHANG Zhongliang, JIN Rongxu, ZHANG Xuemei,et al.Preparation of sintered brick from water-based drilling wastes in offshore oil and gas field[J].Chinese Journal of Environmental Engineering,2021,15(9):3020-3028. | |
| [19] | 环境保护部. 固体废物浸出毒性浸出方法 水平振荡法: [S].北京:中国环境科学出版社,2010. |
| [20] | 刘志明,郑庆红,王树华,等.废弃钻井液固化研究[J].钻井液与完井液,2002,19(1):23-25. |
| LIU Zhiming, ZHENG Qinghong, WANG Shuhua,et al.Study on solidifying the waste drilling fluid[J].Driuing Fluid and Completion Fluld,2002,19(1):23-25. | |
| [21] | 杜森.大掺量粉煤灰混凝土的水化特性及性能提升机制研究[D].哈尔滨:哈尔滨工业大学,2020. |
| DU Sen.Study on the hydration characteristics and performance enhancement mechanism of high volume fly ash concrete[D].Harbin:Harbin Institute of Technology,2020. | |
| [22] | 董明坤.废弃钻井泥浆絮凝及固化处理试验研究[D].郑州:河南农业大学,2023. |
| DONG Mingkun.Experimental study on flocculation and solidification treatment of abandoned drilling mud[D].Zhengzhou:Henan Agricultural University,2023. | |
| [23] | 王进,韩朝江,王军霞,等.“碱-矿渣-粉煤灰-偏高岭土”水合陶瓷产物组成和微观结构[J].硅酸盐学报,2011,39(3):512- 517. |
| WANG Jin, HAN Chaojiang, WANG Junxia,et al.Composition and microstructure of “alkali-slag-coal fly ash-metakaolin” hydroceramics[J].Journal of the Chinese Ceramic Society,2011,39(3):512-517. | |
| [24] | 张发文,何禹龙,董明坤,等.矿渣基改性材料干化城市污泥的效果及微观分析[J].土木与环境工程学报(中英文),2022,44(3):177-185. |
| ZHANG Fawen, HE Yulong, DONG Mingkun,et al.Effect and microscopic analysis on drying municipal sludge with slag-based modified material[J].Journal of Civil and Environmental Engineering,2022,44(3):177-185. | |
| [25] | 杨爱武,王韬,许再良.石灰及其外加剂固化天津滨海软土的试验研究[J].工程地质学报,2015,23(5):996-1004. |
| YANG Aiwu, WANG Tao, XU Zailiang.Experimental study on lime and its additional agent to cure Tianjin marine soft soil[J].Journal of Engineering Geology,2015,23(5):996-1004. | |
| [26] | 肖建敏,李辉,雷睿欣.碱矿渣水泥早期反应产物微观结构演化过程[J].建筑材料学报,2024,27(5):381-390. |
| XIAO Jianmin, LI Hui, LEI Ruixin.Microstructural evolution of early reaction products in alkali-activated slag cement at early age[J].Journal of Building Materials,2024,27(5):381-390. | |
| [27] | 徐日庆,朱坤垅,黄伟,等.淤泥质土固化及路用性能试验研究[J].湖南大学学报(自然科学版),2022,49(3):167-174. |
| XU Riqing, ZHU Kunlong, HUANG Wei,et al.Experimental study on solidification and road performance of mucky soil[J].Journal of Hunan University(Natural Sciences),2022,49(3):167-174. | |
| [28] | 张会芳,龚琳洋,任娅娜,等.固废复合材料灌浆料复合试验设计、力学性能及微观结构分析[J].硅酸盐通报,2023,42(11):4006-4016,4034. |
| ZHANG Huifang, GONG Linyang, REN Yana,et al.Composite experiments design,mechanical properties and microstructure analysis of solid waste composite grouting material[J].Bulletin of the Chinese Ceramic Society,2023,42(11):4006-4016,4034. | |
| [29] | 田均兵.矿渣基固化剂的应用研究[D].贵阳:贵州大学,2016. |
| TIAN Junbing.Research on the application of slag-based solidifying agents [D].Guiyang:Guizhou University,2016. | |
| [30] | 吴俊,征西遥,杨爱武,等.矿渣-粉煤灰基地质聚合物固化淤泥质黏土的抗压强度试验研究[J].岩土力学,2021,42(3):647-655. |
| WU Jun, ZHENG Xiyao, YANG Aiwu,et al.Experimental study on the compressive strength of muddy clay solidified by the one-part slag-fly ash based geopolymer[J].Rock and Soil Mechanics,2021,42(3):647-655. | |
| [31] | 嵇鹰,尚成成,冯云,等.水泥熟料固化重金属Cu2+和Zn2+及水化浸出行为分析[J].材料科学与工程学报,2022,40(1):62- 69. |
| JI Ying, SHANG Chengcheng, FENG Yun,et al.Behavior of cement clinker solidified heavy metal Cu2+ and Zn2+ and hydration leaching[J].Journal of Materials Science and Engineering,2022,40(1):62-69. | |
| [32] | 赵丕琪,孙乾,杨新月,等.水化硅酸钙凝胶的研究进展[J].硅酸盐学报,2024,52(5):1710-1721. |
| ZHAO Piqi, SUN Qian, YANG Xinyue,et al.Calcium silicate hydrate gels:A short review[J].Journal of the Chinese Ceramic Society,2024,52(5):1710-1721. | |
| [33] | LI Wangda, ASL H Y, XIE Qiang,et al.Collapse of LiNi1- x-y Co x Mn y O2 lattice at deep charge irrespective of nickel content in lithium-ion batteries[J].Journal of the American Chemical Society,2019,141(13):5097-5101. |
| [34] | HUA Weibo, SCHWARZ B, KNAPP M,et al.Lithiation mechanism of hierarchically layered LiNi1/3Co1/3Mn1/3O2 cathodes during high-voltage cycling[J].Journal of the Electrochemical Society,2019,166(3):A5025-A5032. |
| [35] | PARK N Y, KIM M C, HAN S M,et al.Mechanism behind the loss of fast charging capability in nickel-rich cathode materials[J].Angewandte Chemie International Edition,2024,63(12):e202319707. |
| [36] | LI Puliang, XUE Longlong, LI Yunjiao,et al.Modification of LiNi0.5Co0.2Mn0.3O2 cathode material using nano TiO2 to enhance the cycle stability in high-voltage ranges[J].Materials Letters,2017,207:217-220. |
| [37] | SHEN Yabin, XUE Hongjin, WANG Shaohua,et al.A highly promising high-nickel low-cobalt lithium layered oxide cathode material for high-performance lithium-ion batteries[J].Journal of Colloid and Interface Science,2021,597:334-344. |
| [38] | ZHAO Ruirui, YANG Zilian, LIANG Jiaxing,et al.Under-standing the role of Na-doping on Ni-rich layered oxide LiNi0.5Co0.2Mn0.3O2 [J].Journal of Alloys and Compounds,2016,689:318-325. |
| [39] | BI Yujing, TAO Jinhui, WU Yuqin,et al.Reversible planar gliding and microcracking in a single-crystalline Ni-rich cathode[J].Science,2020,370(6522):1313-1317. |
/
| 〈 |
|
〉 |