Reviews and Special Topics

Research progress on Bi2WO6-based photocatalyst modification

  • MA Liang ,
  • WANG Chunyan ,
  • LIU Haining ,
  • LI Mingzhen ,
  • SONG Zhongmei ,
  • ZHANG Siyuan ,
  • YE Xiushen
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  • 1. Qinghai Institute of Salt Lakes,Chinese Academy of Sciences,Key Laboratory of Green and High-end Utilization of Salt Lake Resources,Xi′ning 810008,China
    2. Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province,Xi′ning 810008,China
    3. University of Chinese Academy of Sciences,Beijing 101408,China

Received date: 2025-03-19

  Online published: 2025-04-18

Abstract

With the intensification of human industrial activities,wastewater discharge from multiple sectors,including chemical manufacturing,pharmaceuticals,textile dyeing,and electroplating,has become a critical challenge requiring urgent resolution in environmental governance.Photocatalytic technology offers an effective approach for removing organic pollutants from water bodies.Bi2WO6 is a photocatalyst responsive to visible light(bandgap 2.7 eV),featuring a two-dimensional olivine-type oxide semiconductor structure composed of alternating[Bi2O22+ and [WO42- octahedral layers.This material exhibits chemical stability and can degrade organic pollutants under sunlight-driven conditions.However,its overall photocatalytic performance is constrained by limitations such as restricted adsorption capacity and reactive oxygen species generation,high recombination rates of photo-generated carriers,and a narrow visible light response range(λ≤460 nm).Numerous researchers have addressed these limitations through various modification strategies,including morphological control,defect engineering,elemental doping,heterostructure construction,and metal particle deposition.The several modification methods and mechanisms for Bi2WO6 materials were summarized,relevant research progress were systematically organized,and future research directions were proposed to overcome existing limitations.It was aimed to provide theoretical guidance for the design and modification of bismuth-based photocatalytic materials.

Cite this article

MA Liang , WANG Chunyan , LIU Haining , LI Mingzhen , SONG Zhongmei , ZHANG Siyuan , YE Xiushen . Research progress on Bi2WO6-based photocatalyst modification[J]. Inorganic Chemicals Industry, 2025 , 57(12) : 1 -7 . DOI: 10.19964/j.issn.1006-4990.2025-0132

References

[1] FUJISHIMA A, HONDA K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature1972238(5358):37-38.
[2] MA Liang, LU Miao, LI Kexin,et al.Photocatalytic degradation of octadecylamine and 4-dodecylmorpholine over titanium based photocatalyst:Activity and mechanism insights[J].Chemical Engineering Journal2023472:144782.
[3] CHEN Yan, YANG Weiyi, GAO Shuang,et al.Synthesis of Bi2MoO6 nanosheets with rich oxygen vacancies by postsynthesis etching treatment for enhanced photocatalytic performance[J].ACS Applied Nano Materials20181(7):3565-3578.
[4] FAISAL M, AHMED J, ALGETHAMI J S,et al.Facile synthesis of palladium nanoparticles/polypyrrole-carbon black/Bi2O3 ternary na-nocomposite for efficient photocatalytic degradation of colorless and colored pollutants under visible light[J].Arabian Journal of Chemistry202316(12):105349.
[5] MANDAL A, BHATTACHARYA G, KARGUPTA K.Enhanced yield of methanol using rGO-Bi2S3/CuO heterojunction photocatalyst for CO2 reduction[J].Journal of Materials Research202439(13):1935-1950.
[6] MENG Qingqiang, CAO Chihao, WANG Jing,et al.Atomically thin Bi2MoO6 nanosheets for efficient visible-light photocatalytic nitrogen fixation via O-vacancy tailored exposure of Mo sites[J].ACS Applied Nano Materials20247(13):15808-15818.
[7] ARORA I, GARG S, CHAWLA H,et al.Visible light active bismuth chromate/curcuma longa heterostructure for enhancing photocatalytic activity[J].Reaction Kinetics,Mechanisms and Catalysis2024137(6):2919-2931.
[8] JIMENEZ-RELINQUE E, DAPPOZZE F, BERHAULT G,et al.Bismuth oxyhalide as efficient photocatalyst for water,air treatment and bacteria inactivation under UV and visible light[J].Journal of Photochemistry and Photobiology A:Chemistry2024452:115554.
[9] PAN Chengsi, BIAN Gaoming, ZHANG Yaning,et al.Efficient and stable H2O2 production from H2O and O2 on BiPO4 photocatalyst[J].Applied Catalysis B:Environmental2022316:121675.
[10] LENG Weiqi, JIANG Xuefei, HE Sheng,et al.Advanced BiVO4-deoxygenated lignocellulosic photocatalyst for effective degradation of organic and heavy metal pollutants in aqueous system[J].International Journal of Biological Macromolecules2024283:137948.
[11] CUI Kuixin, QIAN Hui, HE Yuehui,et al.Novel chiral wire-like Bi nanoparticle assembly:In-situ studies on structural evolution from(BiO)2CO3 nanowires under electron-beam irradiation[J].Materials Today Chemistry202442:102394.
[12] QI Shuyan, GUAN Ling, ZHANG Ruiyan,et al.Mn doping enhances the photocatalytic performance of Bi2Fe4O9 photocataly- st[J].Optical Materials2023142:114112.
[13] ZHOU Yangen, ZHANG Yongfan, LIN Mousheng,et al.Monolayered Bi2WO6 nanosheets mimicking heterojunction interface with open surfaces for photocatalysis[J].Nature Communications20156:8340.
[14] CHEN Fang, MA Tianyi, ZHANG Tierui,et al.Atomic-level charge separation strategies in semiconductor-based photocatalysts[J].Advanced Materials202133(10):2005256.
[15] OSTERLOH F E.Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting[J].Chemical Society Reviews201342(6):2294-2320.
[16] GOU Zhenqiong, DAI Jinhang, BAI Jinwu.Synthesis of mesoporous Bi2WO6 flower-like spheres with photocatalysis properties under visible light[J].International Journal of Electrochemical Science202015(11):10684-10693.
[17] YANG Wu, ZHOU Fanghe, SUN Ningchao,et al.Constructing a 3D Bi2WO6/ZnIn2S4 direct Z-scheme heterostructure for improved photocatalytic CO2 reduction performance[J].Journal of Colloid and Interface Science2024662:695-706.
[18] ELAOUNI A, OUARDI M EL, BAQAIS A,et al.Bismuth tungstate Bi2WO6:A review on structural,photophysical and photocatalytic properties[J].RSC Advances202313(26):17476-17494.
[19] ZHAO Gang, LIU Suwen, LU Qifang,et al.Fabrication of electrospun Bi2WO6 microbelts with enhanced visible photocatalytic degradation activity[J].Journal of Alloys and Compounds2013578:12-16.
[20] WANG Xinjun, CHANG Linling, WANG Jinrui,et al.Facile hydrothermal synthesis of Bi2WO6 microdiscs with enhanced photocatalytic activity[J].Applied Surface Science2013270:685- 689.
[21] LIU Ying, WANG Weimin, FU Zhengyi,et al.Nest-like structures of Sr doped Bi2WO6:Synthesis and enhanced photocataly-tic properties[J].Materials Science and Engineering:B2011176(16):1264-1270.
[22] 马亮,张思远,路淼,等.可见光响应TiO2光催化降解钾肥浮选药剂[J].盐湖研究202331(2):25-35.
  MA Liang, ZHANG Siyuan, LU Miao,et al.Degradation of potassium fertilizer flotation agents by TiO2 with visible-light respon-se[J].Journal of Salt Lake Research202331(2):25-35.
[23] 马亮,刘伟朝,宋忠梅,等.氧缺陷型光催化剂构建、失活及其稳定性研究进展[J].应用化工202453(9):2165-2171.
  MA Liang, LIU Weichao, SONG Zhongmei,et al.Research progress on the construction,deactivation and stability of oxygen deficient photocatalysts[J].Applied Chemical Industry202453(9):2165-2171.
[24] GAO Weihong, LI Geng, WANG Qiuwen,et al.Ultrathin porous Bi2WO6 with rich oxygen vacancies for promoted adsorption-photocatalytic tetracycline degradation[J].Chemical Engineering Jo- urnal2023464:142694.
[25] WANG Shengyao, XIONG Zhongliang, YANG Nan,et al.Iodine-doping-assisted tunable introduction of oxygen vacancies on bismuth tungstate photocatalysts for highly efficient molecular oxygen activation and pentachlorophenol mineralization[J].Chinese Journal of Catalysis202041(10):1544-1553.
[26] XIONG Jie, ZENG Hongyan, YANG Zhuolin,et al.Engineering oxygen vacancies in Bi2WO6 by introducing heteroatoms for enhancing photo-oxidation/reduction activities[J].Ceramics International202349(22):35927-35938.
[27] TAYYEBI A, SOLTANI T, HONG H,et al.Improved photocatalytic and photoelectrochemical performance of monoclinic bismuth vanadate by surface defect states(Bi1- x VO4)[J].Journal of Colloid and Interface Science2018514:565-575.
[28] ANKE B, ROHLOFF M, WILLINGER M G,et al.Improved photoelectrochemical performance of bismuth vanadate by partial O/F-substitution[J].Solid State Sciences201763:1-8.
[29] WANG Yinghui, HU Jingcong, GE Teng,et al.Gradient cationic vacancies enabling inner-to-outer tandem homojunctions:Strong local internal electric field and reformed basic sites boosting CO2 photoreduction[J].Advanced Materials202335(31):2302538.
[30] BIAN Yuan, ZENG Weixuan, HE Meng,et al.Boosting charge transfer via molybdenum doping and electric-field effect in bismuth tungstate:Density function theory calculation and potential applications[J].Journal of Colloid and Interface Science2019534:20-30.
[31] ZHANG Liwu, MAN Yi, ZHU Yongfa.Effects of Mo replacement on the structure and visible-light-induced photocatalytic performances of Bi2WO6 photocatalyst[J].ACS Catalysis20111(8):841-848.
[32] 王泽普,付念,于涵,等.铟掺杂钨位增强钨酸铋氧空位光催化效率[J].物理学报201968(21):263-269.
  WANG Zepu, FU Nian, YU Han,et al.Enhancing oxygen vacancy photocatalytic efficiency of bismuth tungstate using in-doped W site[J].Acta Physica Sinica201968(21):263-269.
[33] YU Hongguang, CHU Chenglin.Enhanced visible-light-driven photocatalytic activities for assembled hierarchical Bi2WO6 microspheres by fluorine substitution[J].IOP Conference Series:Materials Science and Engineering2018284(1):012002.
[34] LI Chunmei, CHEN Gang, SUN Jingxue,et al.Doping effect of phosphate in Bi2WO6 and universal improved photocatalytic activity for removing various pollutants in water[J].Applied Catalysis B:Environmental2016188:39-47.
[35] DING Xing, ZHAO Kun, ZHANG Lizhi.Enhanced photocatalytic removal of sodium pentachlorophenate with self-doped Bi2WO6 under visible light by generating more superoxide ions[J].Environmental Science & Technology201448(10):5823-5831.
[36] WANG Fangzhi, LI Wenjun, GU Shaonan,et al.Samarium and nitrogen Co-doped Bi2WO6 photocatalysts:Synergistic effect of Sm3+/Sm2+ redox centers and N-doped level for enhancing visible-light photocatalytic activity[J].Chemistry:A European Journal201622(36):12859-12867.
[37] PENG Diyang, ZENG Hongyan, XIONG Jie,et al.Tuning oxygen vacancy in Bi2WO6 by heteroatom doping for enhanced photooxidation-reduction properties[J].Journal of Colloid and Interface Science2023629:133-146.
[38] Kang DA, MAO Xiqiang, MA Yuqian,et al.Fabricating BiOBr/Bi2WO6 S-scheme heterojunction with interface modification strategy for efficient photocatalytic degradation of gaseous tolue-ne[J].Materials Today Communications202440:109612.
[39] AL-ANAZI A, AL-HAJJI L A, ISMAIL A A,et al.Enhanced Hg(Ⅱ) reduction activity over two-dimensional n-n heterojunction MoS2/Bi2WO6 nanocomposites under visible light illumination[J].Optical Materials2024157:116327.
[40] LIU Lizhong, WANG Zhongliao, ZHANG Jinfeng,et al.Tunable interfacial charge transfer in a 2D-2D composite for efficient visible-light-driven CO2 conversion[J].Advanced Materials202335(26):2300643.
[41] WEN Shengwu, ZHANG Weiyun, YANG Jinlong,et al.Ternary Bi2WO6/TiO2-Pt heterojunction sonosensitizers for boosting sonodynamic therapy[J].ACS Nano202418(34):23672-23683.
[42] ZHU Shengbao, XU Tongguang, FU Hongbo,et al.Synergetic effect of Bi2WO6 photocatalyst with C60 and enhanced photoactivity under visible irradiation[J].Environmental Science & Technology200741(17):6234-6239.
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