Inorganic Chemicals Industry >
Research progress on Bi2WO6-based photocatalyst modification
Received date: 2025-03-19
Online published: 2025-04-18
With the intensification of human industrial activities,wastewater discharge from multiple sectors,including chemical manufacturing,pharmaceuticals,textile dyeing,and electroplating,has become a critical challenge requiring urgent resolution in environmental governance.Photocatalytic technology offers an effective approach for removing organic pollutants from water bodies.Bi2WO6 is a photocatalyst responsive to visible light(bandgap 2.7 eV),featuring a two-dimensional olivine-type oxide semiconductor structure composed of alternating[Bi2O2]2+ and [WO4]2- octahedral layers.This material exhibits chemical stability and can degrade organic pollutants under sunlight-driven conditions.However,its overall photocatalytic performance is constrained by limitations such as restricted adsorption capacity and reactive oxygen species generation,high recombination rates of photo-generated carriers,and a narrow visible light response range(λ≤460 nm).Numerous researchers have addressed these limitations through various modification strategies,including morphological control,defect engineering,elemental doping,heterostructure construction,and metal particle deposition.The several modification methods and mechanisms for Bi2WO6 materials were summarized,relevant research progress were systematically organized,and future research directions were proposed to overcome existing limitations.It was aimed to provide theoretical guidance for the design and modification of bismuth-based photocatalytic materials.
Key words: Bi2WO6; modification; mechanism; photocatalytic application
MA Liang , WANG Chunyan , LIU Haining , LI Mingzhen , SONG Zhongmei , ZHANG Siyuan , YE Xiushen . Research progress on Bi2WO6-based photocatalyst modification[J]. Inorganic Chemicals Industry, 2025 , 57(12) : 1 -7 . DOI: 10.19964/j.issn.1006-4990.2025-0132
| [1] | FUJISHIMA A, HONDA K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38. |
| [2] | MA Liang, LU Miao, LI Kexin,et al.Photocatalytic degradation of octadecylamine and 4-dodecylmorpholine over titanium based photocatalyst:Activity and mechanism insights[J].Chemical Engineering Journal,2023,472:144782. |
| [3] | CHEN Yan, YANG Weiyi, GAO Shuang,et al.Synthesis of Bi2MoO6 nanosheets with rich oxygen vacancies by postsynthesis etching treatment for enhanced photocatalytic performance[J].ACS Applied Nano Materials,2018,1(7):3565-3578. |
| [4] | FAISAL M, AHMED J, ALGETHAMI J S,et al.Facile synthesis of palladium nanoparticles/polypyrrole-carbon black/Bi2O3 ternary na-nocomposite for efficient photocatalytic degradation of colorless and colored pollutants under visible light[J].Arabian Journal of Chemistry,2023,16(12):105349. |
| [5] | MANDAL A, BHATTACHARYA G, KARGUPTA K.Enhanced yield of methanol using rGO-Bi2S3/CuO heterojunction photocatalyst for CO2 reduction[J].Journal of Materials Research,2024,39(13):1935-1950. |
| [6] | MENG Qingqiang, CAO Chihao, WANG Jing,et al.Atomically thin Bi2MoO6 nanosheets for efficient visible-light photocatalytic nitrogen fixation via O-vacancy tailored exposure of Mo sites[J].ACS Applied Nano Materials,2024,7(13):15808-15818. |
| [7] | ARORA I, GARG S, CHAWLA H,et al.Visible light active bismuth chromate/curcuma longa heterostructure for enhancing photocatalytic activity[J].Reaction Kinetics,Mechanisms and Catalysis,2024,137(6):2919-2931. |
| [8] | JIMENEZ-RELINQUE E, DAPPOZZE F, BERHAULT G,et al.Bismuth oxyhalide as efficient photocatalyst for water,air treatment and bacteria inactivation under UV and visible light[J].Journal of Photochemistry and Photobiology A:Chemistry,2024,452:115554. |
| [9] | PAN Chengsi, BIAN Gaoming, ZHANG Yaning,et al.Efficient and stable H2O2 production from H2O and O2 on BiPO4 photocatalyst[J].Applied Catalysis B:Environmental,2022,316:121675. |
| [10] | LENG Weiqi, JIANG Xuefei, HE Sheng,et al.Advanced BiVO4-deoxygenated lignocellulosic photocatalyst for effective degradation of organic and heavy metal pollutants in aqueous system[J].International Journal of Biological Macromolecules,2024,283:137948. |
| [11] | CUI Kuixin, QIAN Hui, HE Yuehui,et al.Novel chiral wire-like Bi nanoparticle assembly:In-situ studies on structural evolution from(BiO)2CO3 nanowires under electron-beam irradiation[J].Materials Today Chemistry,2024,42:102394. |
| [12] | QI Shuyan, GUAN Ling, ZHANG Ruiyan,et al.Mn doping enhances the photocatalytic performance of Bi2Fe4O9 photocataly- st[J].Optical Materials,2023,142:114112. |
| [13] | ZHOU Yangen, ZHANG Yongfan, LIN Mousheng,et al.Monolayered Bi2WO6 nanosheets mimicking heterojunction interface with open surfaces for photocatalysis[J].Nature Communications,2015,6:8340. |
| [14] | CHEN Fang, MA Tianyi, ZHANG Tierui,et al.Atomic-level charge separation strategies in semiconductor-based photocatalysts[J].Advanced Materials,2021,33(10):2005256. |
| [15] | OSTERLOH F E.Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting[J].Chemical Society Reviews,2013,42(6):2294-2320. |
| [16] | GOU Zhenqiong, DAI Jinhang, BAI Jinwu.Synthesis of mesoporous Bi2WO6 flower-like spheres with photocatalysis properties under visible light[J].International Journal of Electrochemical Science,2020,15(11):10684-10693. |
| [17] | YANG Wu, ZHOU Fanghe, SUN Ningchao,et al.Constructing a 3D Bi2WO6/ZnIn2S4 direct Z-scheme heterostructure for improved photocatalytic CO2 reduction performance[J].Journal of Colloid and Interface Science,2024,662:695-706. |
| [18] | ELAOUNI A, OUARDI M EL, BAQAIS A,et al.Bismuth tungstate Bi2WO6:A review on structural,photophysical and photocatalytic properties[J].RSC Advances,2023,13(26):17476-17494. |
| [19] | ZHAO Gang, LIU Suwen, LU Qifang,et al.Fabrication of electrospun Bi2WO6 microbelts with enhanced visible photocatalytic degradation activity[J].Journal of Alloys and Compounds,2013,578:12-16. |
| [20] | WANG Xinjun, CHANG Linling, WANG Jinrui,et al.Facile hydrothermal synthesis of Bi2WO6 microdiscs with enhanced photocatalytic activity[J].Applied Surface Science,2013,270:685- 689. |
| [21] | LIU Ying, WANG Weimin, FU Zhengyi,et al.Nest-like structures of Sr doped Bi2WO6:Synthesis and enhanced photocataly-tic properties[J].Materials Science and Engineering:B,2011,176(16):1264-1270. |
| [22] | 马亮,张思远,路淼,等.可见光响应TiO2光催化降解钾肥浮选药剂[J].盐湖研究,2023,31(2):25-35. |
| MA Liang, ZHANG Siyuan, LU Miao,et al.Degradation of potassium fertilizer flotation agents by TiO2 with visible-light respon-se[J].Journal of Salt Lake Research,2023,31(2):25-35. | |
| [23] | 马亮,刘伟朝,宋忠梅,等.氧缺陷型光催化剂构建、失活及其稳定性研究进展[J].应用化工,2024,53(9):2165-2171. |
| MA Liang, LIU Weichao, SONG Zhongmei,et al.Research progress on the construction,deactivation and stability of oxygen deficient photocatalysts[J].Applied Chemical Industry,2024,53(9):2165-2171. | |
| [24] | GAO Weihong, LI Geng, WANG Qiuwen,et al.Ultrathin porous Bi2WO6 with rich oxygen vacancies for promoted adsorption-photocatalytic tetracycline degradation[J].Chemical Engineering Jo- urnal,2023,464:142694. |
| [25] | WANG Shengyao, XIONG Zhongliang, YANG Nan,et al.Iodine-doping-assisted tunable introduction of oxygen vacancies on bismuth tungstate photocatalysts for highly efficient molecular oxygen activation and pentachlorophenol mineralization[J].Chinese Journal of Catalysis,2020,41(10):1544-1553. |
| [26] | XIONG Jie, ZENG Hongyan, YANG Zhuolin,et al.Engineering oxygen vacancies in Bi2WO6 by introducing heteroatoms for enhancing photo-oxidation/reduction activities[J].Ceramics International,2023,49(22):35927-35938. |
| [27] | TAYYEBI A, SOLTANI T, HONG H,et al.Improved photocatalytic and photoelectrochemical performance of monoclinic bismuth vanadate by surface defect states(Bi1- x VO4)[J].Journal of Colloid and Interface Science,2018,514:565-575. |
| [28] | ANKE B, ROHLOFF M, WILLINGER M G,et al.Improved photoelectrochemical performance of bismuth vanadate by partial O/F-substitution[J].Solid State Sciences,2017,63:1-8. |
| [29] | WANG Yinghui, HU Jingcong, GE Teng,et al.Gradient cationic vacancies enabling inner-to-outer tandem homojunctions:Strong local internal electric field and reformed basic sites boosting CO2 photoreduction[J].Advanced Materials,2023,35(31):2302538. |
| [30] | BIAN Yuan, ZENG Weixuan, HE Meng,et al.Boosting charge transfer via molybdenum doping and electric-field effect in bismuth tungstate:Density function theory calculation and potential applications[J].Journal of Colloid and Interface Science,2019,534:20-30. |
| [31] | ZHANG Liwu, MAN Yi, ZHU Yongfa.Effects of Mo replacement on the structure and visible-light-induced photocatalytic performances of Bi2WO6 photocatalyst[J].ACS Catalysis,2011,1(8):841-848. |
| [32] | 王泽普,付念,于涵,等.铟掺杂钨位增强钨酸铋氧空位光催化效率[J].物理学报,2019,68(21):263-269. |
| WANG Zepu, FU Nian, YU Han,et al.Enhancing oxygen vacancy photocatalytic efficiency of bismuth tungstate using in-doped W site[J].Acta Physica Sinica,2019,68(21):263-269. | |
| [33] | YU Hongguang, CHU Chenglin.Enhanced visible-light-driven photocatalytic activities for assembled hierarchical Bi2WO6 microspheres by fluorine substitution[J].IOP Conference Series:Materials Science and Engineering,2018,284(1):012002. |
| [34] | LI Chunmei, CHEN Gang, SUN Jingxue,et al.Doping effect of phosphate in Bi2WO6 and universal improved photocatalytic activity for removing various pollutants in water[J].Applied Catalysis B:Environmental,2016,188:39-47. |
| [35] | DING Xing, ZHAO Kun, ZHANG Lizhi.Enhanced photocatalytic removal of sodium pentachlorophenate with self-doped Bi2WO6 under visible light by generating more superoxide ions[J].Environmental Science & Technology,2014,48(10):5823-5831. |
| [36] | WANG Fangzhi, LI Wenjun, GU Shaonan,et al.Samarium and nitrogen Co-doped Bi2WO6 photocatalysts:Synergistic effect of Sm3+/Sm2+ redox centers and N-doped level for enhancing visible-light photocatalytic activity[J].Chemistry:A European Journal,2016,22(36):12859-12867. |
| [37] | PENG Diyang, ZENG Hongyan, XIONG Jie,et al.Tuning oxygen vacancy in Bi2WO6 by heteroatom doping for enhanced photooxidation-reduction properties[J].Journal of Colloid and Interface Science,2023,629:133-146. |
| [38] | Kang DA, MAO Xiqiang, MA Yuqian,et al.Fabricating BiOBr/Bi2WO6 S-scheme heterojunction with interface modification strategy for efficient photocatalytic degradation of gaseous tolue-ne[J].Materials Today Communications,2024,40:109612. |
| [39] | AL-ANAZI A, AL-HAJJI L A, ISMAIL A A,et al.Enhanced Hg(Ⅱ) reduction activity over two-dimensional n-n heterojunction MoS2/Bi2WO6 nanocomposites under visible light illumination[J].Optical Materials,2024,157:116327. |
| [40] | LIU Lizhong, WANG Zhongliao, ZHANG Jinfeng,et al.Tunable interfacial charge transfer in a 2D-2D composite for efficient visible-light-driven CO2 conversion[J].Advanced Materials,2023,35(26):2300643. |
| [41] | WEN Shengwu, ZHANG Weiyun, YANG Jinlong,et al.Ternary Bi2WO6/TiO2-Pt heterojunction sonosensitizers for boosting sonodynamic therapy[J].ACS Nano,2024,18(34):23672-23683. |
| [42] | ZHU Shengbao, XU Tongguang, FU Hongbo,et al.Synergetic effect of Bi2WO6 photocatalyst with C60 and enhanced photoactivity under visible irradiation[J].Environmental Science & Technology,2007,41(17):6234-6239. |
/
| 〈 |
|
〉 |