Inorganic Chemicals Industry >
Research progress on preparation of calcium sulfate whisker from industrial by⁃product gypsum under atmospheric pressure
Received date: 2024-07-08
Online published: 2024-08-14
With the rapid development of China's industry,industrial by⁃product gypsum(phosphogypsum,flue gas desulfurization gypsum,titanium gypsum,etc.) emissions are growing,a large amount of industrial by⁃product gypsum accumulation will cause serious environmental problems,such as groundwater pollution,soil pollution and so on.Calcium sulfate whisker is often added to other materials as a filler in the industry to enhance performance and other functions,make full use of industrial by⁃product gypsum to prepare high added value calcium sulfate whisker,which can not only protect the environment,but also expand its application range and increase economic benefits.Due to the influence of production technology and equipment,the preparation of calcium sulfate whisker by industrial by⁃product gypsum under normal pressure has not been realized on a large scale.The methods of preparing calcium sulfate whisker from industrial by⁃product gypsum under atmospheric pressure were described and compared,the regulation mechanism of different types of crystal modifier on crystal morphology was described, the influence of impurities in industrial by⁃product gypsum on the crystallization process was introduced.The shortcomings of the current preparation methods of calcium sulfate whisker was summarized,and the future preparation process of calcium sulfate whisker was prospected.
RAO Jiahuan , WEI Jiazhan , DENG Lian , JING Daiyan . Research progress on preparation of calcium sulfate whisker from industrial by⁃product gypsum under atmospheric pressure[J]. Inorganic Chemicals Industry, 2025 , 57(5) : 46 -54 . DOI: 10.19964/j.issn.1006-4990.2024-0392
1 | DU Jingwei, TIAN Lin, QI Manfu,et al.Revealing maleic acid role in the preparation of α-hemihydrate gypsum from titanium gypsum through experiments and DFT calculations[J].Science of the Total Environment,2023,897:166405. |
2 | GUAN Baohong, YANG Li, FU Hailu,et al. α-calcium sulfate hemihydrate preparation from FGD gypsum in recycling mixed salt solutions[J].Chemical Engineering Journal,2011,174(1):296-303. |
3 | MIN Junjie, HUANG Jian, HU Hailong,et al.Effect of mixed cation acetate electrolyte on synthesis of α-hemihydrate gypsum from phosphogypsum[J].Journal of the American Ceramic Society,2024,107(1):107-120. |
4 | WANG Wei, XIA Baolin, SUO Xinyan,et al.Facile preparation of α-calcium sulfate hemihydrate whisker from by?product gypsum in chloride?free salt solution system[J].Journal of Environmental Chemical Engineering,2023,11(5):110385. |
5 | 苏一鑫.脱硫石膏制备纳米硫酸钙及其应用[D].天津:河北工业大学,2022. |
SU Yixin.Eparation of nanometer calcium sulfate from desulfurized gypsum and its application[D].Tianjin:Hebei University of Technology,2022. | |
6 | MAICHIN P, JITSANGIAM P, NONGNUANG T,et al.Stabilized high clay content lateritic soil using cement-FGD gypsum mixtures for road subbase applications[J].Materials,2021,14(8):1858. |
7 | ZHAI Weiwei, DAI Yuxia, ZHAO Wenliang,et al.Simultaneous immobilization of the cadmium,lead and arsenic in paddy soils amended with titanium gypsum[J].Environmental Pollution,2020,258:113790. |
8 | YANG Yuhong, KOU Lidong, CHEN Huan,et al.Synthesis of magnetic adsorbents from titanium gypsum and biomass wastes for enhanced phosphate removal[J].Bioresource Technology,2023,371:128609. |
9 | GOU Mifeng, ZHAO Mengke, ZHOU Longfei,et al.Hydration and mechanical properties of FGD gypsum?cement?mineral powder composites[J].Journal of Building Engineering,2023,69:106288. |
10 | 王艾文.磷石膏常压无氯盐溶液法制备硫酸钙晶须[D].绵阳:西南科技大学,2021. |
WANG Aiwen.Eparation of calcium sulfate whiskers from phosphogypsum by chloride?free solution method at atmospheric pressure[D].Mianyang:Southwest University of Science and Technology,2021. | |
11 | 王宇斌.硫酸钙晶须晶型稳定化研究[D].沈阳:东北大学,2008. |
WANG Yubin.Study on crystal stability of calcium sulfate whiskers[D].Shenyang:Northeastern University,2008. | |
12 | ZIA-UL-HAQ M, WU Jian, PENG Zonglin,et al.Mechanical properties and thermal stability of modified calcium sulfate whisker?reinforced polydimethylsiloxane/ethylene?vinyl acetate copolymer composites[J].Iranian Polymer Journal,2023,32(10):1335-1346. |
13 | CHEN Xuemei, GAO Jianming, WU Ye,et al.Preparation of CSHW with flue gas desulfurization gypsum[J].Materials,2022,15(7):2691. |
14 | FAN Taotao, WANG Xiushan.Influence of calcium sulfate whisker on the high temperature performance of asphalt binder[J].Petroleum Science and Technology,2020,38(4):303-308. |
15 | QI Yuanhao, WU Jinxiu, QIN Sicheng,et al.Characterization and mechanism of natural rubber composites reinforced by modified calcium sulfate whisker[J].Journal of Applied Polymer Science,2023,140(27):e53911. |
16 | YANG Jinian, NIE Shibin, ZHU Jinbo.Fabrication and characterization of poly(lactic acid) biocomposites reinforced by calcium sulfate whisker[J].Journal of Polymers and the Environment,2018,26(8):3458-3469. |
17 | SUDHAN RAJ J, CHRISTY T V, DARIUS GNANARAJ S,et al.Influence of calcium sulfate whiskers on the tribological characteristics of automotive brake friction materials[J].Engineering Science and Technology,an International Journal,2020,23(2):445-451. |
18 | CAO Kai, LIU Ganggui, LI Hui,et al.Mechanical properties and microstructure of calcium sulfate whisker?reinforced cement?based composites[J].Materials,2022,15(3):947. |
19 | FREYER D, VOIGT W.Crystallization and phase stability of CaSO4 and CaSO4-based salts[J].Monatshefte Für Chemie/Che? mical Monthly,2003,134(5):693-719. |
20 | DR H W, DR M B.How much water does calcined gypsum contain?[J].Angewandte Chemie International Edition,2009,48(19):3520-3524. |
21 | DUAN Zhengyang, LI Jianxi, LI Tianguo,et al.Influence of crystal modifier on the preparation of α-hemihydrate gypsum from phosphogypsum[J].Construction and Building Materials,2017,133:323-329. |
22 | 蒋光明. α半水石膏亚稳定特性及其在醇水溶液中的结晶规律及颗粒特性[D].杭州:浙江大学,2015. |
JIANG Guangming.Tastable characteristics of α-hemihydrate gypsum and its crystallization law and particle characteristics in alcohol aqueous solution[D].Hangzhou:Zhejiang University,2015. | |
23 | 孙祥斌.基于磷石膏二水硫酸钙制备结构形貌可控半水硫酸钙的研究[D].合肥:合肥工业大学,2020. |
SUN Xiangbin.Udy on preparation of calcium sulfate hemihydrate with controllable structure and morphology based on phosphogypsum dihydrate[D].Hefei:Hefei University of Technology,2020. | |
24 | 牛小超,吴锦绣,柳召刚,等.硫酸钙晶须的研究进展[J].应用化工,2022,51(4):1174-1180,1201. |
NIU Xiaochao, WU Jinxiu, LIU Zhaogang,et al.Research progress of calcium sulfate whiskers[J].Applied Chemical Industry,2022,51(4):1174-1180,1201. | |
25 | YANG Baojun, DONG Yinzhe, WANG Bainian,et al.A mild alcohol?salt route to synthesize α-hemihydrate gypsum microrods from flue gas desulfurization gypsum in large scale[J].Materials Research Express,2019,6(4):045507. |
26 | 杨凤玲,乔国鑫,杨普,等.脱硫石膏制备α-半水石膏研究进展及应用[J].无机盐工业,2024,56(2):11-20,29. |
YANG Fengling, QIAO Guoxin, YANG Pu,et al.Research progress and application of α-hemihydrate gypsum preparation from desulfurization gypsum[J].Inorganic Chemicals Industry,2024,56(2):11-20,29. | |
27 | 郭静静,路瑞玲,薛甜,等.硫酸钙晶须的调控与应用研究进展[J].工业催化,2022,30(10):1-8. |
GUO Jingjing, LU Ruiling, XUE Tian,et al.Research progress on the regulation and application of calcium sulfate whiskers[J].Industrial Catalysis,2022,30(10):1-8. | |
28 | 徐伟.稀土石膏常压酸化法制备硫酸钙晶须及其改性的研究[D].包头:内蒙古科技大学,2020. |
XU Wei.Udy on preparation and modification of calcium sulfate whisker by atmospheric acidification of rare earth gypsum[D].Baotou:Inner Mongolia University of Science & Technology,2020. | |
29 | 谢晴,蒋美雪,彭同江,等.磷石膏常压酸化法制备无水硫酸钙晶须的实验研究[J].人工晶体学报,2019,48(6):1060-1066,1071. |
XIE Qing, JIANG Meixue, PENG Tongjiang,et al.Experimental study on preparation of anhydrous calcium sulfate whisker by phosphogypsum at atmospheric acidification method[J].Journal of Synthetic Crystals,2019,48(6):1060-1066,1071. | |
30 | 李前均,谢燕,陈前林,等.常压酸化法制备硫酸钙晶须工艺研究[J].无机盐工业,2017,49(6):59-62. |
LI Qianjun, XIE Yan, CHEN Qianlin,et al.Study on preparation of calcium sulphate wiskers by atmospheric acidification[J].Inorganic Chemicals Industry,2017,49(6):59-62. | |
31 | SUN Hongjuan, TAN Daoyong, PENG Tongjiang,et al.Preparation of calcium sulfate whisker by atmospheric acidification method from flue gas desulfurization gypsum[J].Procedia Environmental Sciences,2016,31:621-626. |
32 | 黄建时.醇水体系中脱硫石膏制备α-半水石膏晶须及重金属铅(Pb)迁移分配规律[D].杭州:中国计量大学,2019. |
HUANG Jianshi.Nthesis of α-hemihydrate whiskers from FGD gypsum and the fate of heavy metal(Pb) during the conversion process in alcohol?water systems[D].Hangzhou:China Jiliang University,2019. | |
33 | 何响,阳勇.磷石膏制备硫酸钙晶须的研究现状[J].磷肥与复肥,2023,38(5):29-32. |
HE Xiang, YANG Yong.Research status of preparation of calcium sulfate whisker from phosphogypsum[J].Phosphate & Compound Fertilizer,2023,38(5):29-32. | |
34 | 屈吉艳,陈高祥,刘芮村,等.盐溶液法制备半水石膏的工艺研究及探讨[J].矿产综合利用,2024,45(3):1-12.QU Jiyan, CHEN Gaoxiang, LIU Ruicun,et al.Research and discussion on the process of preparing semi?aqueous gypsum by salt solution method[J].Multipurpose Utilization of Mineral Resour?ces,2024,45(3):1-12. |
35 | 周佳佳,迟慧芳,夏宝林.脱硫石膏作水泥缓凝剂的若干问题分析[J].水泥技术,2024(3):86-88. |
ZHOU Jiajia, CHI Huifang, XIA Baolin.Analysis of several issues on desulfurized gypsum as cement retarder[J].Cement Technology,2024(3):86-88. | |
36 | XIA Baolin, SHI Ruohan, WANG Wei,et al.Preparation of α hemihydrate gypsum whiskers from phosphogypsum using atmospheric pressure nitrate solution[J].Construction and Building Materials,2024,412:134888. |
37 | 何花.磷石膏基醇—水热法制备大长径比改性硫酸钙晶须研究[D].绵阳:西南科技大学,2014. |
HE Hua.Study on phosphogypsum?based modified calcium sulfate whiskers with large aspect ratio by glycerol?hydrothermal method[D].Mianyang:Southwest University of Science and Technology,2014. | |
38 | 吴传龙.常压醇水法α-半水石膏的形貌调控及性能研究[D].绵阳:西南科技大学,2016. |
WU Chuanlong.Study on morphology control and performance of α-hemihydrate gypsum by the glycerol water method at atmospheric pressure[D].Mianyang:Southwest University of Science and Technology,2016. | |
39 | FU Hailu, LI Mengfan, HUANG Jianshi,et al.Insights into the role of Na+ on the transformation of gypsum into α-hemihydrate whiskers in alcohol?water systems[J].ACS Omega,2022,7(18):15570-15579. |
40 | LI Xianbo, HE Yuqi.Preparation of α-hemihydrate gypsum from phosphogypsum in glycerol and Na2SO4 mixed solutions under atmospheric pressure[J].Journal of Crystal Growth,2021,568:126184. |
41 | 杨彪,杨颖,黄宏彬,等.微波加热性能优化研究现状[J].昆明理工大学学报(自然科学版),2024,49(4):138-153. |
YANG Biao, YANG Ying, HUANG Hongbin,et al.Research status of microwave heating performance optimization[J].Journal of Kunming University of Science and Technology(Natural Science),2024,49(4):138-153. | |
42 | 李德星,郭荣鑫,林志伟,等.常压微波醇水法制备α半水硫酸钙晶须的研究[J].非金属矿,2022,45(1):46-50,55. |
LI Dexing, GUO Rongxin, LIN Zhiwei,et al.Study on preparation of α-calcium sulfate hemihydrate whiskers by atmospheric microwave glycerol water method[J].Non?Metallic Mines,2022,45(1):46-50,55. | |
43 | 卢佳艳.微波辅助微乳液法制备脱水相硫酸钙[D].湘潭:湘潭大学,2021. |
LU Jiayan.Preparation of dehydrated calcium sulfate by microwave?assisted microemulsion method[D].Xiangtan:Xiangtan University,2021. | |
44 | 李德星.常压微波辐照醇水体系中磷石膏制备半水硫酸钙晶须的研究[D].昆明:昆明理工大学,2022. |
LI Dexing.Preparation of hemihydrate calcium sulfate whiskers from phosphogypsum under atmospheric pressure microwave irradiation in glycerol water system[D].Kunming:Kunming University of Science and Technology,2022. | |
45 | 张绍奇.磷石膏微波醇水体系中制备半水硫酸钙晶须的基础研究[D].昆明:昆明理工大学,2021. |
ZHANG Shaoqi.Basic research on preparation of calcium sulfate hemihydrate whiskers in phosphogypsum microwave alcohol water system[D].Kunming:Kunming University of Science and Technology,2021. | |
46 | LI Liang, ZHU Yingjie, MA Mingguo.Microwave?assisted preparation of calcium sulfate nanowires[J].Materials Letters,2008,62(30):4552-4554. |
47 | 冯焱,张绍奇,林志伟,等.微波辐照下丁二酸对磷石膏制备半水石膏的影响[J].硅酸盐通报,2020,39(11):3535-3541,3556. |
FENG Yan, ZHANG Shaoqi, LIN Zhiwei,et al.Effect of succinic acid on preparation of hemihydrate gypsum from phosphogypsum under microwave irradiation[J].Bulletin of the Chinese Ceramic Society,2020,39(11):3535-3541,3556. | |
48 | FENG Yan, GUO Rongxin, LIN Zhiwei.Effect of aluminum sulfate and succinic acid on the growth law of α-calcium sulfate hemihydrate under microwave irradiation[J].Advances in Materials Science and Engineering,2021,2021(1):6630638. |
49 | 陈勇,李楠,张欢,等.转晶剂对动态水热法制备α-半水石膏的影响[J].广州化工,2023,51(24):40-42. |
CHEN Yong, LI Nan, ZHANG Huan,et al.Effect of crystal transformation agents on preparation of α-semi hydrated gypsum by dynamic hydrothermal method[J].Guangzhou Chemical Industry,2023,51(24):40-42. | |
50 | 王明顺,敖先权,袁兴,等.转晶剂对磷石膏制备无水硫酸钙影响的研究[J].无机盐工业,2024,56(5):101-107. |
WANG Mingshun, AO Xianquan, YUAN Xing,et al.Study on effect of crystallizer on preparation of anhydrous calcium sulfate from phosphogypsum[J].Inorganic Chemicals Industry,2024,56(5):101-107. | |
51 | 方羊.水热法制备半水硫酸钙晶须及其长径比的可控研究[D].合肥:合肥工业大学,2017. |
FANG Yang.Calcium sulfate hemihydrate whiskers prepared by hydrothermal method and the controllability study of aspect ratios[D].Hefei:Hefei University of Technology,2017. | |
52 | GUAN Qingjun, SUN Wei, HU Yuehua,et al.A facile method of transforming FGD gypsum to α-CaSO4·0.5H2O whiskers with cetyltrimethylammonium bromide(CTAB) and KCl in glycerol?water solution[J].Scientific Reports,2017,7(1):7085. |
53 | 董一苇,徐祖顺,杨婷婷,等.化学石膏制备α-半水石膏的研究进展[J].材料导报,2021,35(S2):241-247. |
DONG Yiwei, XU Zushun, YANG Tingting,et al.Research progress on the preparation of α?calcium sulfate hemihydrate from chemical gypsum[J].Materials Reports,2021,35(S2):241-247. | |
54 | HOU Sichao, WANG Jing, WANG Xiaoxue,et al.Effect of Mg2+ on hydrothermal formation of α-CaSO4·0.5H2O whiskers with high aspect ratios[J].Langmuir,2014,30(32):9804-9810. |
55 | GUAN Qingjun, SUN Wei, LIU Runqing,et al.Preparation of α calcium sulfate hemihydrate whiskers with high aspect ratios in presence of a minor amount of CuCl2·2H2O[J].Journal of Central South University,2018,25(3):526-533. |
56 | 范瑞华. α-半水硫酸钙晶体生长形貌调控机制及其在磷石膏高值化中的应用[D].长沙:中南大学,2023. |
FAN Ruihua.Crystal morphology control mechanism of α-hemihydrate and its application on the high value utilization of phosphogypsum[D].Changsha:Central South University,2023. | |
57 | LI Lixia, HAO Haiqing, YUAN Zhitao.Effect of additives on the morphologies of hydrothermal products prepared from semi?dry desulfurization residues[J].Crystals,2018,8(11):417. |
58 | 秦思成,吴锦绣,齐源昊,等.添加剂对无水硫酸钙晶须生长的影响及分子动力学模拟[J].硅酸盐通报,2023,42(7):2551-2562. |
QIN Sicheng, WU Jinxiu, QI Yuanhao,et al.Effects of additives on anhydrous calcium sulfate whisker growth and molecular dynamics simulation[J].Bulletin of the Chinese Ceramic Society,2023,42(7):2551-2562. | |
59 | YANG Lin, CAO Jianxin, LUO Tong.Effect of Mg2+,Al3+,and Fe3+ ions on crystallization of type α hemi?hydrated calcium sulfate under simulated conditions of hemi?hydrate process of phosphoric acid[J].Journal of Crystal Growth,2018,486:30-37. |
60 | WANG Bingqi, YANG Lin, CAO Jianxin.The influence of impurities on the dehydration and conversion process of calcium sulfate dihydrate to α-calcium sulfate hemihydrate in the two?step wet?process phosphoric acid production[J].ACS Sustainable Chemistry & Engineering,2021,9(43):14365-14374. |
61 | FU Hailu, HUANG Jianshi, SHEN Luming,et al.Role and fate of the lead during the conversion of calcium sulfate dihydrate to α hemihydrate whiskers in ethylene glycol?water solutions[J].Chemical Engineering Journal,2019,372:74-81. |
/
〈 |
|
〉 |