Inorganic Chemicals Industry >
Research progress of preparation technology of black phosphorus
Received date: 2024-06-11
Online published: 2024-07-11
In recent years，as a conceptually new two-dimensional layered material，black phosphorus（BP） has good development potential in semiconductor，electrochemistry，solar cells，photocatalysis，flame retardant，biomedicine and other fields owing to its unique structure and excellent physicochemical properties，such as large specific surface area，high anisotropy，wide light absorption，high carrier mobility.Due to the high cost of black phosphorus，further advancement and application of this material have been hindered，thereby making the research on its synthesis processes become a focus topic.The preparation processes of black phosphorus were reviewed.Firstly，the physicochemical properties of black phosphorus and its application fields were introduced.Subsequently，various synthesis methods were outlined，encompassing high-pressure methods，mechanical ball milling，solvothermal synthesis，bismuth melting process，mercury reflux method，and chemical vapor transport（CVT） method，etc.Particular emphasis was placed on the optimization procedures and mechanism related to CVT.The advantages and disadvantages of each preparation technique were summarized and the future development direction was prospected.
LI Yongxiang , LIU Chenxi , LI Yundong , MA Hang , MEI Lianping , DANG Hui , SUN Zhi , WAN Banglong . Research progress of preparation technology of black phosphorus[J]. Inorganic Chemicals Industry, 2025 , 57(3) : 18 -29 . DOI: 10.19964/j.issn.1006-4990.2024-0319
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