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Research progress of PEO based organic/inorganic composite solid electrolyte
Received date: 2024-05-07
Online published: 2024-06-13
Lithium-ion battery is considered as the most convenient and effective energy storage equipment due to its high energy density and long cycle life.In order to improve the stability and safety of lithium-ion batteries，solid-state electrolytes have been widely studied.However，pure polymer electrolytes have the drawbacks of lower ionic conductivity，narrow operating voltage window，which hindered their applications in all-solid-state lithium-ion batteries.PEO-based composite electrolytes are the most promising class of electrolyte systems due to their advantages of easy processing，low cost，and good interfacial contact.Based on this，composite solid electrolytes were introduced basicly and the ionic conduction mechanism of PEO-based electrolytes was discussed，and then the relevant research results in recent years according to the different geometries of inorganic fillers，such as nanoparticles，nanowires/nanotubes，two-dimensional lamellar materials，and 3D skeleton structures were reviewed.The effects of inorganic fillers with different geometries on the performance of electrolytes，especially ionic conductivity，and the cycling performance of the full battery were elaborated.Finally，the key issues and development of composite solid-state electrolytes were summarized.
MA Jingyuan , LI Yan , ZHOU Hanjie , LI Jiangang . Research progress of PEO based organic/inorganic composite solid electrolyte[J]. Inorganic Chemicals Industry, 2025 , 57(3) : 1 -8 . DOI: 10.19964/j.issn.1006-4990.2024-0249
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