Inorganic Chemicals Industry >

2024 , Vol. 56 >Issue 11: 95 - 104

DOI: https://doi.org/10.19964/j.issn.1006-4990.2024-0190

Reviews and Special Topics

Advances in encapsulated catalysts for propane dehydrogenation

  • WANG Yansu ,
  • FENG Qing ,
  • LIU Guozhu ,
  • YU Haibin ,
  • SUN Yanmin ,
  • NAN Jun
Expand
  • 1.Institute of Chemical Engineering，Tianjin University，Tianjin 300350，China
    2.CNOOC Tianjin;Chemical Research and Design Institute Co. ，Ltd. ，Tianjin 300131，China

Received date: 2024-04-03

  Online published: 2024-04-28

Fold

Abstract

Propane dehydrogenation（PDH） to propylene is an important technological pathway for increasing the production of the vital chemical propylene.The PDH reaction，being a structure-insensitive process，requires only a single metal or metal-oxygen site for C—H activation to occur.However，the competing C—C activation reaction requires aggregation state metal or oxide sites to take place.Therefore，the development strategy of PDH catalysts often involves constructing sub-nanometer dehydrogenation active centers through confinement effects or strong metal-support interactions.In recent years，utilizing the confinement effect of zeolite channels to construct stable sub-nanometer-sized active sites has become a research hotspot in PDH field.The metal species encapsulated in zeolites were firstly systematically classified，synthesis strategies were introduced，and qualitative and quantitative methods for characterizing the entry of metal species into the micropores of zeolites were discussed.Then，the latest synthetic research progress of zeolite-encapsulated metal catalysts was summarized，including precious and non-precious metal catalysts for propane dehydrogenation reaction.Meanwhile，catalytic mechanisms and structure-function relationships were also discussed.Finally，the limitations and future development directions of zeolite-encapsulated metal catalysts in the propane dehydrogenation process were proposed to provide new insights for the preparation of metal-loaded zeolite propane dehydrogenation catalysts.

Key words： propane dehydrogenation; zeolite; encapsulation; confinement effect; noble metal; non-noble metal

Cite this article

WANG Yansu , FENG Qing , LIU Guozhu , YU Haibin , SUN Yanmin , NAN Jun . Advances in encapsulated catalysts for propane dehydrogenation[J]. Inorganic Chemicals Industry, 2024 , 56(11) : 95 -104 . DOI: 10.19964/j.issn.1006-4990.2024-0190

References

1 CHEN Sai， CHANG Xin， SUN Guodong，et al.Propane dehydrogenation：Catalyst development，new chemistry，and emerging technologies［J］.Chemical Society Reviews，2021，50（5）：3315-3354.
2 XU Zhikang， XU Rui， YUE Yuanyuan，et al.Bimetallic Pt-Sn nanocluster from the hydrogenolysis of a well-defined surface compound consisting of ［（AlO）Pt（COD）Me］ and ［（AlO）SnPh3］ fragments for propane dehydrogenation［J］.Journal of Catalysis，2019，374：391-400.
3 SHI Lei， DENG Gaoming， LI Wencui，et al.Al2O3 nanosheets rich in pentacoordinate Al（3+） ions stabilize Pt-Sn clusters for propane dehydrogenation［J］.Angewandte Chemie，2015，54（47）：13994-13998.
4 SUN Qiming， WANG Ning， FAN Qiyuan，et al.Frontispiece：Subnanometer bimetallic platinum-zinc clusters in zeolites for propane dehydrogenation［J］.Angewandte Chemie International Edition，2020，59（44）：e202084461.
5 DENG Lidan， SHISHIDO T， TERAMURA K，et al.Effect of reduction method on the activity of Pt-Sn/SiO2 for dehydrogenation of propane［J］.Catalysis Today，2014，232：33-39.
6 QU Ziqiang， SUN Qiming.Advances in zeolite-supported metal cat-alysts for propane dehydrogenation［J］.Inorganic Chemistry Frontiers，2022，9（13）：3095-3115.
7 ZHANG Bofeng， SONG Mingxia， XU Mingrui，et al.Recent advances in metal-zeolite catalysts for direct propane dehydrogenation［J］.Energy & Fuels，2023，37（24）：19419-19432.
8 SUN Qiming， WANG Ning， YU Jihong.Advances in catalytic applications of zeolite-supported metal catalysts［J］.Advanced Materials，2021，33（51）：e2104442.
9 WANG Yansu， HU Zhongpan， LV Xianwei，et al.Ultrasmall PtZn bimetallic nanoclusters encapsulated in silicalite-1 zeolite with superior performance for propane dehydrogenation［J］.Journal of Catalysis，2020，385：61-69.
10 解则安，吕聪敏，初晓，等.微孔分子筛限域Pt基丙烷脱氢催化剂制备的研究进展［J］.沈阳师范大学学报（自然科学版），2022，40（2）：115-120.
  XIE Zean， Congmin Lü， CHU Xiao，et al.Synthesis research progress of microporous molecular zeolites confined Pt-based catalysts for direct dehydrogenation of propane［J］.Journal of Shenyang Normal University（Natural Science Edition），2022， 40（2）：115-120.
11 LIU Meng， MIAO Caixia， WU Zhijie.Recent advances in the synthesis，characterization，and catalytic consequence of metal species confined within zeolite for hydrogen-related reactions［J］.Industrial Chemistry & Materials，2024，2（1）：57-84.
12 ZHANG Qiang， GAO Shiqin， YU Jihong.Metal sites in zeolites：Synthesis，characterization，and catalysis［J］.Chemical Reviews，2023，123（9）：6039-6106.
13 ZHANG Wei， WANG Haizhi， JIANG Jiawei，et al.Size dependence of Pt catalysts for propane dehydrogenation：From atomically dispersed to nanoparticles［J］.ACS Catalysis，2020，10（21）：12932-12942.
14 王延苏，刘国柱，于海斌.非贵金属催化剂用于丙烷脱氢的研究进展［J］.无机盐工业，2023，55（12）：1-11.
  WANG Yansu， LIU Guozhu， YU Haibin.Research progress of non-precious metal catalysts for propane dehydrogenation［J］.Inorganic Chemicals Industry，2023，55（12）：1-11.
15 ZHU Jun， YANG Minglei， YU Yingda，et al.Size-dependent reaction mechanism and kinetics for propane dehydrogenation over Pt catalysts［J］.ACS Catalysis，2015，5（11）：6310-6319.
16 WANG Ning， SUN Qiming， BAI Risheng，et al. In situ confinement of ultrasmall Pd clusters within nanosized silicalite-1 zeolite for highly efficient catalysis of hydrogen generation［J］.Journal of the American Chemical Society，2016，138（24）：7484-7487.
17 MOLINER M， GABAY J E， KLIEWER C E，et al.Reversible transformation of Pt nanoparticles into single atoms inside high-silica chabazite zeolite［J］.Journal of the American Chemical Society，2016，138（48）：15743-15750.
18 ZHANG Jian， WANG Liang， SHAO Yi，et al.A Pd@Zeolite catalyst for nitroarene hydrogenation with high product selectivity by sterically controlled adsorption in the zeolite micropores［J］.Angewandte Chemie，2017，56（33）：9747-9751.
19 LI Shiwen， BUREL L， AQUINO C，et al.Ultimate size control of encapsulated gold nanoparticles［J］.Chemical Communications，2013，49（76）：8507-8509.
20 LIU Lichen， DíAZ U， ARENAL R，et al.Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D［J］.Nature Materials，2017，16（1）：132-138.
21 WANG Yansu， SUO Yujun， LV Xianwei，et al.Enhanced performances of bimetallic Ga-Pt nanoclusters confined within silicalite-1 zeolite in propane dehydrogenation［J］.Journal of Colloid and Interface Science，2021，593：304-314.
22 WEI Xueer， CHENG Jiawei， LI Yubing，et al.Bimetallic clusters confined inside silicalite-1 for stable propane dehydrogenati- on［J］.Nano Research，2023，16（8）：10881-10889.
23 ZHU Jie， OSUGA R， ISHIKAWA R，et al.Ultrafast encapsulation of metal nanoclusters into MFI zeolite in the course of its crystallization：Catalytic application for propane dehydrogenation［J］.Angewandte Chemie，2020，59（44）：19669-19674.
24 RYOO R， KIM J，JO C，et al.Rare-earth-platinum alloy nanoparticles in mesoporous zeolite for catalysis［J］.Nature，2020， 585（7824）：221-224.
25 LIU Lichen， LOPEZ-HARO M， LOPES C W，et al.Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis［J］.Nature Materials，2019，18（8）：866-873.
26 QI Liang， BABUCCI M， ZHANG Yanfei，et al.Propane dehydrogenation catalyzed by isolated Pt atoms in ≡SiOZn-OH nests in dealuminated zeolite beta［J］.Journal of the American Chemical Society，2021，143（50）：21364-21378.
27 MA Yue， SONG Shaojia， LIU Changcheng，et al.Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation［J］.Nature Catalysis，2023，6：506-518.
28 ZENG Lei， CHENG Kang， SUN Fanfei，et al.Stable anchoring of single rhodium atoms by indium in zeolite alkane dehydrogenation catalysts［J］.Science，2024，383（6686）：998-1004.
29 HU Zhongpan， QIN Gangqiang， HAN Jingfeng，et al.Atomic insight into the local structure and microenvironment of isolated co-motifs in MFI zeolite frameworks for propane dehydrogenation［J］.Journal of the American Chemical Society，2022，144（27）：12127-12137.
30 QU Ziqiang， HE Guangyuan， ZHANG Tianjun，et al.Tricoordinated single-atom cobalt in zeolite boosting propane dehydrogenation［J］.Journal of the American Chemical Society，2024， 146（13）：8939-8948.
31 XIE Linjun， WANG Rui， CHAI Yuchao，et al.Propane dehydrogenation catalyzed by in situ partially reduced zinc cations confined in zeolites［J］.Journal of Energy Chemistry，2021，63：262-269.
32 SONG Shaojia， YANG Kun， ZHANG Peng，et al.Silicalite-1 stabilizes Zn-hydride species for efficient propane dehydrogenati- on［J］.ACS Catalysis，2022，12（10）：5997-6006.
33 CHAI Yicong， CHEN Shunhua， CHEN Yang，et al.Dual-atom catalyst with N-colligated Zn1Co1 species as dominant active sites for propane dehydrogenation［J］.Journal of the American Chemical Society，2024，146（1）：263-273.
34 YUE Yuanyuan， FU Jing， WANG Chuanming，et al.Propane dehydrogenation catalyzed by single Lewis acid site in Sn-Beta zeolite［J］.Journal of Catalysis，2021，395：155-167.
35 HU Bo， SCHWEITZER N M， ZHANG Guanghui，et al.Isolated FeII on silica as a selective propane dehydrogenation catalyst［J］.ACS Catalysis，2015，5（6）：3494-3503.
36 YUN J H， LOBO R F.Catalytic dehydrogenation of propane over iron-silicate zeolites［J］.Journal of Catalysis，2014，312：263- 270.
37 XU Guangyue， ZHANG Xiang， DONG Zhuoya，et al.Ferric single-site catalyst confined in a zeolite framework for propane dehydrogenation［J］.Angewandte Chemie，2023，62（44）：e202305915.
38 SEARLES K， SIDDIQI G， SAFONOVA O V，et al.Silica-supported isolated gallium sites as highly active，selective and stable propane dehydrogenation catalysts［J］.Chemical Science，2017，8（4）：2661-2666.
39 PHADKE N M， MANSOOR E， BONDIL M，et al.Mechanism and kinetics of propane dehydrogenation and cracking over Ga/H-MFI prepared via vapor-phase exchange of H-MFI with GaCl3 ［J］.Journal of the American Chemical Society，2019，141（4）：1614-1627.
40 NI Lingli， KHARE R， BERMEJO-DEVAL R，et al.Highly active and selective sites for propane dehydrogenation in zeolite Ga-BEA［J］.Journal of the American Chemical Society，2022，144（27）：12347-12356.
41 YUAN Yong， LEE J S， LOBO R F.Ga+-chabazite zeolite：A highly selective catalyst for nonoxidative propane dehydrogenati-on［J］.Journal of the American Chemical Society，2022，144（33）：15079-15092.
Options
Outlines

/

〈 〉



Copyright © 2021 Editorial Office of Inorganic Chemicals Industry

Add:No.3 Road Dingzigu,Hongqiao District,Tianjin,China

E-mail：book@wjygy.com.cn 违法和不良信息举报电话: 022-26689297