Inorganic Chemicals Industry >
Research on boron nitride modified film for cathode interface of metallic lithium battery
Received date: 2023-09-04
Online published: 2024-04-18
The application of metallic lithium cathodes can significantly improve the energy density of existing lithium-ion batteries，due to their ultra-high specific capacity（3 860 mA·h/g） and ultra-low reduction potential（-3.04 V）.However，the continuous side reactions between metallic lithium and electrolyte lead to severe polarization of the battery，the increasing of inactive lithium，as well as the fast capacity decay.In this study，in order to improve the cycling performance of the Li metal batteries，the boron nitride film was used as the artificial solid electrolyte interphase（SEI） on the surface of metallic lithium to inhibit the side reaction between the boron nitride film and the electrolyte，so as to achieve the long cycle of metallic lithium battery.Boron nitride film could be uniformly deposited on the surface of metallic lithium by a simple and easy spraying deposition method，and the optimal deposition time by electrochemical impedance spectroscopy was investigated.The boron nitride SEI film possessed the character of ionic conducting and electron blocking，which successfully suppressed the polarization increasing.Compared with the unmodified lithium metal，the area specific resistance of the cathode interface was decreased from 4.6 Ω/cm2 to 1.2 Ω/cm2 after boron nitride modification.The initial coulombic efficiency of the assembled lithium manganate/metallic lithium battery was increased from 89.2% to 96.6%.The capacity retention was increased from 86.3% to 94.6% after 300 cycles at 1C.
ZHOU Haitao , WEN Chengqin , ZHENG Ling , SUN Jie . Research on boron nitride modified film for cathode interface of metallic lithium battery[J]. Inorganic Chemicals Industry, 2024 , 56(4) : 85 -89 . DOI: 10.19964/j.issn.1006-4990.2023-0438
| 1 | IMANISHI N， YAMAMOTO O. Perspectives and challenges of rechargeable lithium-air batteries［J］. Materials Today Advances， 2019， 4：100031. |
| 2 | XIE Zhengkun， WU Zhijun， AN Xiaowei， et al. Anode-free rechargeable lithium metal batteries：Progress and prospects［J］. Energy Storage Materials， 2020， 32：386-401. |
| 3 | ZHANG Zhizhen， SHAO Yuanjun， LOTSCH B， et al. New horizons for inorganic solid state ion conductors［J］. Energy & Environmental Science， 2018， 11（8）：1945-1976. |
| 4 | XIA Qiuying， NI Mingzhu， CHEN Minghua， et al. Low-temperature synthesized self-supported single-crystalline LiCoO2 nanoflake arrays as advanced 3D cathodes for flexible lithium-ion batteries［J］. Journal of Materials Chemistry A， 2019， 7（11）：6187-6196. |
| 5 | FANG Guozhao， ZHU Chuyu， CHEN Minghui， et al. Suppressing manganese dissolution in potassium manganate with rich oxygen defects engaged high-energy-density and durable aqueous zinc-ion battery［J］. Advanced Functional Materials， 2019， 29（15）：1808375. |
| 6 | 康乐， 景茂祥， 李东红， 等. 铝酸锂纳米棒改性固态电解质的制备及电化学性能研究［J］. 无机盐工业， 2023， 55（8）：65-70. |
| KANG Le， JING Maoxiang， LI Donghong， et al. Study on preparation and electrochemical performance of lithium aluminate nanorods modified solid electrolyte［J］. Inorganic Chemicals Industry， 2023， 55（8）：65-70. | |
| 7 | LIU Ting， ZHANG Yibo， ZHANG Xue， et al. Enhanced electrochemical performance of bulk type oxide ceramic lithium batteries enabled by interface modification［J］. Journal of Materials Chemistry A， 2018， 6（11）：4649-4657. |
| 8 | WINTER M， BARNETT B， XU Kang. Before Li ion batteries［J］. Chemical Reviews， 2018， 118（23）：11433-11456. |
| 9 | XU Kang. Electrolytes and interphases in Li-ion batteries and beyond［J］. Chemical Reviews， 2014， 114（23）：11503-11618. |
| 10 | KRAVCHYK K V， OKUR F， KOVALENKO M V. Break-even analysis of all-solid-state batteries with Li-garnet solid electrolytes［J］. ACS Energy Letters， 2021， 6（6）：2202-2207. |
| 11 | CHONG Jin， ZHANG Jingping， XIE Haiming， et al. High performance LiNi0.5Mn1.5O4 cathode material with a bi-functional coating for lithium ion batteries［J］. RSC Advances， 2016， 6（23）：19245-19251. |
| 12 | HAN Fudong， ZHU Yizhou， HE Xingfeng， et al. Electrochemical stability of Li10GeP2S12 and Li7La3Zr2O12 solid electrolytes［J］. Advanced Energy Materials， 2016， 6（8）：1501590. |
| 13 | GAO Aolei， SUN Zhenhua， LI Shaopeng， et al. The mechanism of manganese dissolution on Li1.6Mn1.6O4 ion sieves with HCl［J］. Dalton Transactions， 2018， 47（11）：3864-3871. |
| 14 | JENSEN K M ?， CHRISTENSEN M， GUNNLAUGSSON H P， et al. Defects in hydrothermally synthesized LiFePO4 and LiFe1- x Mn x PO4 cathode materials［J］. Chemistry of Materials， 2013， 25（11）：2282-2290. |
| 15 | CHEN Shaojie， NIE Zhiwei， TIAN Feifei， et al. The influence of surface chemistry on critical current density for garnet electroly-te［J］. Advanced Functional Materials， 2022， 32（23）：2113318. |
| 16 | JENA A， MEESALA Y， HU Shufen， et al. Ameliorating interfacial ionic transportation in all-solid-state Li-ion batteries with interlayer modifications［J］. ACS Energy Letters， 2018， 3（11）：2775-2795. |
/
| 〈 |
|
〉 |