Inorganic Chemicals Industry >
Study on preparation and electrochemical properties of nano-sized LiNi0.05Mn1.95O4 cathode materials
Received date: 2023-06-08
Online published: 2024-04-18
To effectively suppress Jahn-Teller effect of spinel lithium manganate and improve the problem of rapid capacity decay during high-rate charge discharge cycles，the LiNi0.05Mn1.95O4 samples were successfully prepared by using a molten salt combustion method and different calcination temperatures.The experiment results demonstrated that the crystal structure of LiMn2O4 did not change under Ni-doping and different calcination temperatures.With the rise of calcination temperature，the crystallinity and particle size of the samples were increased continuously.Besides，the particle sizes were gradually increased from nanoscales to submicron scales.The optimal calcination temperature of 650 ℃ delivered excellent electrochemical performance.The initial discharge specific capacity at 5C and the capacity retention rate after 500 cycles were 100.8 mA·h/g and 80.0%，respectively.At a higher rate of 10C，the capacity of 500 cycles only attenuated by 7.5%.The dynamic performance test results indicated that it had a large lithium-ion diffusion coefficient of 3.26×10-16 cm2/s and a smaller apparent activation energy of 25.67 kJ/mol.Ni doping and different calcination temperatures inhibited the Jahn-Teller effect of LiMn2O4 materials，thereby promoted the rate performance and cycle life of LiMn2O4 materials.
QIAN Zhihui , ZHU Qin , MA Jiao , GUO Yujiao , XIANG Mingwu , GUO Junming . Study on preparation and electrochemical properties of nano-sized LiNi0.05Mn1.95O4 cathode materials[J]. Inorganic Chemicals Industry, 2024 , 56(4) : 50 -56 . DOI: 10.19964/j.issn.1006-4990.2023-0313
| 1 | LI Jiexiang， YANG Min， ZHANG Xiaoming， et al. First-principles study of the effect of Ni-doped on the spinel-type Mn-based cathode discharge［J］. ACS Applied Materials & Interfaces， 2023， 15（6）：8208-8216. |
| 2 | 徐前进， 徐金钢， 田朋， 等. 氧化铝包覆锂离子电池正极材料的研究进展［J］. 无机盐工业， 2023， 55（1）：46-55，117. |
| XU Qianjin， XU Jingang， TIAN Peng， et al. Research progress of alumina coated cathode materials for lithium-ion batteries［J］. Inorganic Chemicals Industry， 2023， 55（1）：46-55，117. | |
| 3 | JAUMAUX P， LIU Qi， ZHOU Dong， et al. Deep-eutectic-solvent-based self-healing polymer electrolyte for safe and long-life lithi-um-metal batteries［J］. Angewandte Chemie（International Ed.in English）， 2020， 59（23）：9134-9142. |
| 4 | SONG Jin， WANG Hangchao， ZUO Yuxuan， et al. Building better full manganese-based cathode materials for next-generation lithium-ion batteries［J］. Electrochemical Energy Reviews， 2023， 6（1）：20. |
| 5 | NWACHUKWU I M， NWANYA A C， EKWEALOR A B C， et al. Recent progress in Mn and Fe-rich cathode materials used in Li-ion batteries［J］. Journal of Energy Storage， 2022， 54：105248. |
| 6 | XIE Taoxiong， REN Pengwen， YU Linyu， et al. Optimization of Al3+ doping on the microstructure and electrochemical performance of spinel LiMn2O4 ① ［J］. Chinese Journal of Structural Chemistry， 2022， 41（2）：168-175. |
| 7 | YI Hongming， LIANG Ying， QIAN Yunlong， et al. Low-cost Mn-based cathode materials for lithium-ion batteries［J］. Batteries， 2023， 9（5）：246. |
| 8 | XU Wangqiong， BAI Hongli， LI Qiling， et al. Preparation and electrochemical performance of nano-LiNi0.05Mn1.95O4 cathode materials by a low-temperature molten-salt combustion method［J］. International Journal of Electrochemical Science， 2017， 12（10）：9758-9773. |
| 9 | WANG Faxing， XIAO Shiying， SHI Yan， et al. Spinel LiNi x Mn2- x O4 as cathode material for aqueous rechargeable lithium batteries［J］. Electrochimica Acta， 2013， 93：301-306. |
| 10 | ZHU Jinyu， LIU Qing， XIANG Mingwu， et al. Facile synthesis of truncated octahedron LiNi0.10Mn1.90O4 for high-performance Li-ion batteries［J］. Ceramics International， 2020， 46（10）：14516-14522. |
| 11 | XU Wangqiong， LI Qiling， SUI Fengrui， et al. Unveiling the role of Ni doping in the electrochemical performance improvement of the LiMn2O4 cathodes［J］. Applied Surface Science， 2023， 624：157142. |
| 12 | BAI Hongli， XU Wangqiong， GUO Junming， et al. High rate cyclability of nickle-doped LiNi0.1Mn1.9O4 cathode materials prepared by a facile molten-salt combustion method for lithium-ion batteries［J］. Journal of Materials Science：Materials in Electronics， 2018， 29（17）：14668-14678. |
| 13 | 于月， 白红丽， 刘晓芳， 等. 液相无焰燃烧合成LiNi x Mn2- x O4（x≤0.10）及电化学性能研究［J］. 电池工业， 2018， 22（2）：62-69. |
| YU Yue， BAI Hongli， LIU Xiaofang， et al. Study on the synthesis of LiNi x Mn2- x O4（x≤0.10） and electrochemical properties via a liquid flameless combustion method［J］. Chinese Battery Industry， 2018， 22（2）：62-69. | |
| 14 | KUNJUZWA N， KEBEDE M A， OZOEMENA K I， et al. Stable nickel-substituted spinel cathode material（LiMn1.9Ni0.1O4） for lithium-ion batteries obtained by using a low temperature aqueous reduction technique［J］. RSC Advances， 2016， 6（113）：111882-111888. |
| 15 | 梁其梅， 郭昱娇， 郭俊明， 等. 亚微米去顶角八面体LiNi0.08Mn1.92O4正极材料制备及高温电化学性能［J］. 化学学报， 2021， 79（12）：1526-1533. |
| LIANG Qimei， GUO Yujiao， GUO Junming， et al. Preparation and high temperature electrochemical performance of LiNi0.08Mn1.92O4 cathode material of submicron truncated octahedron［J］. Acta Chimica Sinica， 2021， 79（12）：1526-1533. | |
| 16 | 李萌， 刘红雷， 郭俊明， 等. Li-Ni共掺尖晶石型LiMn2O4单晶多面体材料的制备及电化学性能［J］. 复合材料学报， 2021， 38（10）：3402-3411. |
| LI Meng， LIU Honglei， GUO Junming， et al. Preparation and electrochemical properties of Li-Ni co-doping spinel LiMn2O4 single crystal polyhedron material［J］. Acta Materiae Compositae Sinica， 2021， 38（10）：3402-3411. | |
| 17 | 朱志红， 朱永芳. 硅掺杂锰酸锂的自蔓延燃烧制备及其性能研究［J］. 无机盐工业， 2023， 55（5）：66-70. |
| ZHU Zhihong， ZHU Yongfang. Study on preparation and properties of silicon doped lithium manganate by self-propagating combustion［J］. Inorganic Chemicals Industry， 2023， 55（5）：66-70. | |
| 18 | BHUVANESWARI S， VARADARAJU U V， GOPALAN R， et al. Structural stability and superior electrochemical performance of Sc-doped LiMn2O4 spinel as cathode for lithium ion batteries［J］. Electrochimica Acta， 2019， 301：342-351. |
| 19 | LLUSCO A， GRAGEDA M， USHAK S. Kinetic and thermodynamic studies on synthesis of Mg-doped LiMn2O4 nanoparticl- es［J］. Nanomaterials， 2020， 10（7）：1409. |
| 20 | WANG Jing， KOENIG G M. Comparison of lithium diffusion coefficient measurements in tellurium electrodes via different electrochemical techniques［J］. Journal of the Electrochemical Society， 2023， 170（5）： 050534. |
/
| 〈 |
|
〉 |