Inorganic Chemicals Industry >
Study on new process for beneficiation phosphate of low-grade phosphate rock leaching via lactic acid
Received date: 2023-04-26
Online published: 2024-03-14
The P2O5 content in the low-grade rare earth-containing phosphate ore in Guizhou Zhijin is 15.47%.This ore is mainly composed by fluorine apatite,colloidal phosphate site,dolomite,quartz,etc.It is difficult to separate P2O5 from this kind of ore effectively by using traditional method.In order to solve this problem,low molecular weight lactic acid was used as leaching agent to selectively dissolve the carbonate components in the ore,and the useful component was retained because it was insoluble in lactic acid,and the purpose of enriching P2O5 was achieved after filtering the filtrate.The effects of lactic acid concentration,reaction time,reaction temperature,liquid-solid ratio,ore particle size on the enrichment effect of P2O5 were investigated in details.The results showed that under the conditions of lactic acid concentration of 9%,reaction temperature of 50 °C,reaction time of 3 h,liquid-solid ratio (V/m,mL/g)of 30∶1,ore particle size of 0.075~<0.09 mm,the P2O5 content in phosphate ore was 33.99%,which was met the market standard.The process of using lactic acid to selectively leach carbonate gangue components in phosphate ore to enrich P2O5 had the characteristics of high enrichment rate,simple,economic and energy saving,which could effectively improve the comprehensive utilization rate of rare earth phosphate ore resources,and showed good application prospects.
WANG Jianrui , ZHANG Song , ZHANG Jie . Study on new process for beneficiation phosphate of low-grade phosphate rock leaching via lactic acid[J]. Inorganic Chemicals Industry, 2024 , 56(3) : 56 -63 . DOI: 10.19964/j.issn.1006-4990.2023-0237
| 1 | 王建蕊,张杰,莫樊,等.选择性浸出中低品位磷块岩实验研究[J].无机盐工业,2016,48(5):13-15. |
| WANG Jianrui, ZHANG Jie, MO Fan,et al.Study of selective leaching of low-grade phosphate rock in acid[J].Inorganic Chemicals Industry,2016,48(5):13-15. | |
| 2 | WANG Jianrui, ZHANG Jie.Study on the selective leaching of low-grade phosphate ore for beneficiation of phosphorus and rare earths using citric acid as leaching agent[J].Russian Journal of Applied Chemistry,2016,89(7):1196-1205. |
| 3 | 金会心.织金新华磷矿稀土赋存状态及其在浮选、酸解过程中的行为研究[D].昆明:昆明理工大学,2008. |
| JIN Huixin.Study on the occurrence state of rare earth in Zhijin Xinhua phosphate rock and its behavior in flotation and acidoly-sis[D].Kunming:Kunming University of Science and Technology,2008. | |
| 4 | 谢娟,刘松林,陶绍程,等.高镁磷尾矿碳化法制备碱式碳酸镁研究[J].无机盐工业,2021,53(12):135-139. |
| XIE Juan, LIU Songlin, TAO Shaocheng,et al.Study on preparation of magnesium carbonate hydroxide by carbonization method from high-Mg phosphate tailings[J].Inorganic Chemicals Industry,2021,53(12):135-139. | |
| 5 | EI-MIDANI A.Separating dolomite from phosphate rock by reactive flotation:Fundamental and application[D].Thesis University of Florida,2004. |
| 6 | 郑东钥,唐盛伟,吕莉.盐酸分解高硅混合型胶磷矿工艺研究[J].无机盐工业,2021,53(2):81-83,104. |
| ZHENG Dongyao, TANG Shengwei, Li Lü.Study on process of hydrochloric acid leaching high silicon mixed phosphate ore[J].Inorganic Chemicals Industry,2021,53(2):81-83,104. | |
| 7 | FREDD C N, SCOTT FOGLER H.The kinetics of calcite dissolution in acetic acid solutions[J].Chemical Engineering Science,1998,53(22):3863-3874. |
| 8 | 韩增辉,周琼波,谢建新,等.磷精矿脱除湿法稀磷酸中硫酸根的实验研究[J].无机盐工业,2021,53(7):83-85,104. |
| HAN Zenghui, ZHOU Qiongbo, XIE Jianxin,et al.Experimental research on sulfate removal from wet-process phosphoric acid using phosphate concentrate[J].Inorganic Chemicals Industry,2021,53(7):83-85,104. | |
| 9 | LA?IN O, D?NMEZ B, DEMIR F.Dissolution kinetics of natural magnesite in acetic acid solutions[J].International Journal of Mineral Processing,2005,75(1/2):91-99. |
| 10 | 李靖,张覃,李龙江,等.采用浮选柱从中低品位磷矿石中富磷降镁初步试验研究[J].矿业研究与开发,2017,37(7):79-83. |
| LI Jing, ZHANG Qin, LI Longjiang,et al.Study on the phosphorus enrichment and magnesium reduction from middle-low grade phosphate ores by flotation column[J].Mining Research and Development,2017,37(7):79-83. | |
| 11 | 黄筱迪,刘志红,李显波.贵州某中低品位磷矿石浮选试验研究[J].化工矿物与加工,2016,45(10):4-7. |
| HUANG Xiaodi, LIU Zhihong, LI Xianbo.Experimental study on flotation of a mid-low grade phosphate ore in Guizhou[J].Industrial Minerals & Processing,2016,45(10):4-7. | |
| 12 | 丁蕾蕾,郜华萍,万欣,等.干法煅烧改性中低品位磷矿石[J].非金属矿,2020,43(1):59-63. |
| DING Leilei, GAO Huaping, WAN Xin,et al.Modified medium-low grade phosphate ores by dry calcination[J].Non-Metallic Mines,2020,43(1):59-63. | |
| 13 | 王辛龙,许德华,钟艳君,等.中国磷化工行业60年发展历程及未来发展趋势[J].无机盐工业,2020,52(10):9-17. |
| WANG Xinlong, XU Dehua, ZHONG Yanjun,et al.Future trend and development course of phosphorus chemical industry for sixty years in China[J].Inorganic Chemicals Industry,2020,52(10):9-17. | |
| 14 | 徐昌伟,高宏亮.磷矿浮选废水治理的现状及发展趋势[J].环境技术,2004,22(4):25-28. |
| XU Changwei, GAO Hongliang.Treating situation and developing ternd of phosphorite floatation wastewater[J].Environmental Te- | |
| chnology,2004,22(4):25-28. | |
| 15 | JEPPSSON L, FREDHOLM D, MATTIASSON B.Acetic acid and phosphatic fossils:A warning[J].Journal of Paleontology,1985,59(4):952-956. |
| 16 | ZAFAR Z I, ASHRAF M.Selective leaching kinetics of calcareous phosphate rock in lactic acid[J].Chemical Engineering Journal,2007,131(1/2/3):41-48. |
| 17 | 张耀滔,李军,陈明,等.碱法回收湿法磷酸萃余渣中五氧化二磷的研究[J].无机盐工业,2021,53(7):86-91. |
| ZHANG Yaotao, LI Jun, CHEN Ming,et al.Study on the recovery of phosphorus pentoxide from wet-process phosphoric acid extraction residue by alkaline process[J].Inorganic Chemicals Industry,2021,53(7):86-91. | |
| 18 | 丁蕾蕾.利用黄磷尾气热解中低品位磷矿石中碳酸盐技术研究[D].昆明:昆明理工大学,2020. |
| DING Leilei.Technology of pyrolyzing carbonate in medium-low grade phosphate ores with yellow phosphorus off-gas[D].Kunming:Kunming University of Science and Technology,2020. | |
| 19 | 梁成波,解田,杨林,等.磷酸分解磷矿过程中金属元素的浸出规律研究[J].无机盐工业,2021,53(11):49-54. |
| LIANG Chengbo, XIE Tian, YANG Lin,et al.Study on leaching law of metal elements in process of decomposing phosphate rock by phosphoric acid[J].Inorganic Chemicals Industry,2021,53(11):49-54. | |
| 20 | 尹伟,黄进,解田,等.磷酸高效分解磷矿实验研究[J].无机盐工业,2020,52(9):34-36. |
| YIN Wei, HUANG Jin, XIE Tian,et al.Experimental study on high efficiency decomposition of phosphate rock by phosphoric acid[J].Inorganic Chemicals Industry,2020,52(9):34-36. | |
| 21 | 聂登攀,刘安荣,王在谦,等.含稀土中低品位磷矿石盐酸酸解工艺研究[J].化工矿物与加工,2015,44(7):7-9. |
| NIE Dengpan, LIU Anrong, WANG Zaiqian,et al.Study on dissolution of rare earth bearing middle-low grade phosphate ore by hydrochloric acid hydrolysis process[J].Industrial Minerals & Processing,2015,44(7):7-9. |
/
| 〈 |
|
〉 |