Research & Development

Study on preparation process of strontium rich functional salt from Zigong underground brine

  • SU Xin ,
  • LAI Dongmei ,
  • ZHOU Yuan ,
  • ZHU Xiaping
Expand
  • 1.College of Materials and Chemistry and Chemical Engineering,Chengdu University of Technology,Key Laboratory of Mineral Resources Chemistry,Chengdu 610059,China
    2.Sichuan Institute of Product Quality Supervision,Inspection and Testing,Chengdu 610100,China

Received date: 2023-04-25

  Online published: 2024-03-14

Abstract

Underground brine in Zigong contains rich sodium,magnesium,lithium bromide,strontium,etc.It can be used to produce raw salt,magnesium salt,bromine and other industrial products,which is an important liquid mineral resource for the alkali industry and salt industry.In response to the characteristics of rich strontium in underground brine in Zigong and the current status of salt production technology,strontium rich salt was developed.By optimizing oxalic acid as brine purifying agents,calcium and magnesium were removed from brine,and more strontium was retained.The optimized brine purification process was as follows:adding 5.2 mL of oxalic acid with concentration of 0.7 mol/L at a constant rate of 5 mL/min to 100 mL of brine at 45 ℃,adjusting the pH to 8.0,stirring for 30 min,adding 0.3 mL of polyacrylamide with mass concentration of 2 g/L and molecular weight of 8 million,allowing the final solution to stand for 1 h.The strontium content in the table salt(100 g dry basis) prepared by high-temperature evaporation of purified brine obtained by optimizing the process was 37.5 mg,which was 20 times of the strontium content in the currently available table salt.The strontium salts and other index requirements complied with the national standard(GB 2721—2015).The new process realized the comprehensive utilization of strontium in Zigong brine,and also provided citizens with the choice of strontium rich functional salts.

Cite this article

SU Xin , LAI Dongmei , ZHOU Yuan , ZHU Xiaping . Study on preparation process of strontium rich functional salt from Zigong underground brine[J]. Inorganic Chemicals Industry, 2024 , 56(3) : 45 -50 . DOI: 10.19964/j.issn.1006-4990.2023-0235

References

1 韩积斌,许建新,刘久波,等.地下卤水水文地质研究进展[J].盐湖研究201826(4):79-84,90.
  HAN Jibin, XU Jianxin, LIU Jiubo,et al.Advance in hydrogeological study of subsurface brine[J].Journal of Salt Lake Research201826(4):79-84,90.
2 张苏江,张琳,姜爱玲,等.中国盐湖资源开发利用现状与发展建议[J].无机盐工业202254(10):13-21.
  ZHANG Sujiang, ZHANG Lin, JIANG Ailing,et al.Current situation and development suggestions of development and utilization of salt lake resources in China[J].Inorganic Chemicals Industry202254(10):13-21.
3 乜贞,伍倩,丁涛,等.中国盐湖卤水提锂产业化技术研究进展[J].无机盐工业202254(10):1-12.
  NIE Zhen, WU Qian, DING Tao,et al.Research progress on industrialization technology of lithium extraction from salt lake brine in China[J].Inorganic Chemicals Industry202254(10):1-12.
4 徐正震,梁精龙,李慧,等.含锂资源中锂的提取研究现状及展望[J].矿产综合利用2021(5):32-37.
  XU Zhengzhen, LIANG Jinglong, LI Hui,et al.Research status and prospects of lithium extraction from lithium containing resources[J].Multipurpose Utilization of Mineral Resources2021(5):32-37.
5 郑绵平,侯献华.青海盐湖资源综合利用与可持续发展战略[J].科技导报201735(12):11-13.
  ZHENG Mianping, HOU Xianhua.Comprehensive utilization and sustainable development strategy of salt lake resources in Qing-hai[J].Science & Technology Review201735(12):11-13.
6 张晓,纪志永,汪婧,等.电氧化法地下卤水提溴探究及条件优化[J].化工学报202172(4):2123-2131.
  ZHANG Xiao, JI Zhiyong, WANG Jing,et al.Exploration and optimization of extraction process of bromine from underground brine by electrooxidation[J].CIESC Journal202172(4):2123-2131.
7 余疆江,郑绵平,伍倩,等.卤水溴资源开发利用进展[J].现代化工201333(4):47-51.
  YU Jiangjiang, ZHENG Mianping, WU Qian,et al.Development and utilization progress of brine bromine resource[J].Modern Chemical Industry201333(4):47-51.
8 师景双,于艳艳,任雪梅,等.我国食盐行业现状及盐业体制改革分析[J].中国调味品202045(11):195-197,200.
  SHI Jingshuang, YU Yanyan, REN Xuemei,et al.Analysis of the current situation and system reform of salt industry in China[J].China Condiment202045(11):195-197,200.
9 曹琴,周训,张欢,等.四川盆地卧龙河储卤构造地下卤水的水化学特征及成因[J].地质通报201534(5):990-997.
  CAO Qin, ZHOU Xun, ZHANG Huan,et al.Hydrochemical characteristics and genesis of the subsurface brines in the Wolonghe brine-bearing structure of Sichuan Basin[J].Geological Bulletin of China201534(5):990-997.
10 周翊,刘昌辉,易胜利,等.四川盆地自贡地区下-中三叠统卤水富锂成因初探[J].中国井矿盐202253(5):7-11.
  ZHOU Yi, LIU Changhui, YI Shengli,et al.Preliminary study on the origin of lithium enrichment in lower Middle Triassic brine in Zigong area,Sichuan basin[J].China Well and Rock Salt202253(5):7-11.
11 WANG Sibo, SUN Jiateng, GU Lingfeng,et al.Association of urinary strontium with cardiovascular disease among the US adults:A cross-sectional analysis of the national health and nutrition examination survey[J].Biological Trace Element Research2023201(8):3583-3591.
12 DOTTA T C, HAYANN L,DE PADUA ANDRADE ALMEIDA L,et al.Strontium carbonate and strontium-substituted calcium carbonate nanoparticles form protective deposits on dentin surface and enhance human dental pulp stem cells mineralization[J].Journal of Functional Biomaterials202213(4):250.
13 曾宪录,高仕,韩飞,等.锶在骨质疏松治疗中的应用研究进展[J].食品研究与开发202142(16):220-224.
  ZENG Xianlu, GAO Shi, HAN Fei,et al.A review of strontium application in the treatment of osteoporosis[J].Food Research and Development202142(16):220-224.
14 黄胥莱,高亚男,张养东,等.食品中锶功能的研究进展[J].食品科学202344(15):397-406.
  HUANG Xulai, GAO Yanan, ZHANG Yangdong,et al.Research progress of strontium function in food[J].Food Science202344(15):397-406.
15 赵睿,杨晓,朱向东,等.微量元素锶掺杂生物材料在骨修复领域的应用[J].化学进展202133(4):533-542.
  ZHAO Rui, YANG Xiao, ZHU Xiangdong,et al.Application of trace element strontium-doped biomaterials in the field of bone regeneration[J].Progress in Chemistry202133(4):533-542.
16 WU Qianju, HU Longwei, YAN Ran,et al.Strontium-incorporated bioceramic scaffolds for enhanced osteoporosis bone regeneration[J].Bone Research2022(4):816-825.
Outlines

/