Inorganic Chemicals Industry >
Study on preparation of nickel-iron-manganate sodium layered oxides and their properties
Received date: 2023-03-01
Online published: 2024-02-06
The O3-type NaNi0.4Fe0.2Mn0.4O2 cathode material has the characteristics of high specific capacity and excellent high/low-temperature performance，which is a kind of sodium-ion cathode material with practical application value.A series of cathode materials were prepared by co-precipitation method，and the effects of pH on the characteristics and performance of the materials were investigated.With the help of scanning electron microscope（SEM），X-ray diffractometer（XRD），constant current intermittent titration technique（GITT） and other electrochemical testing techniques，the morphology，lattice parameter，cycling performance，multiplicity performance，sodium-ion diffusion coefficient，and pseudocapacitance contribution of the NaNi0.4Fe0.2Mn0.4O2 materials were analyzed，and the samples were found to have a decreasing particle size with the increase of pH.It was found that the particle size of the samples decreased with the increase of pH，and excessive high pH would cause a sharp decrease in the particle size of the samples，and the optimal synthesis pH was 11.The electrochemical test results of the NaNi0.4Fe0.2Mn0.4O2 material at the optimized pH showed that the discharge specific capacity of NaNi0.4Fe0.2Mn0.4O2 material at 30 ℃ with a current density of 0.2C was 142.3 mA·h/g，which exhibited excellent electrochemical performance.
WANG Yizhou , HU Xiaomei , WANG Yongxiang , ZHANG Weimin . Study on preparation of nickel-iron-manganate sodium layered oxides and their properties[J]. Inorganic Chemicals Industry, 2024 , 56(2) : 57 -64 . DOI: 10.19964/j.issn.1006-4990.2023-0104
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