Reviews and Special Topics

Research progress of lithium resource extraction technology

  • CHEN Haixia ,
  • YAN Hong ,
  • SUN Yunlong ,
  • MA Guoqiang
Expand
  • Zhejiang Research Institute of Chemical Industry,Hangzhou 310023,China

Received date: 2023-05-31

  Online published: 2024-01-18

Abstract

Lithium is considered as one of the most important energy metals in the 21st century.Under the common goal of global carbon reduction,the rapid development of new energy industry has promoted the continuous growth of lithium consumption in the past three years,and triggered a research boom on lithium extraction technology at home and abroad.According to the occurrence state of lithium resources,the technology of extracting lithium from mineral and brine was summarized,and the advantages and disadvantages of various methods were systematically summarized and compared.The main methods of extracting lithium from mineral mainly included limestone roasting,sulfuric acid,sulfate roasting,pressure boiling,chlorination roasting and direct acid leaching.The technologies that had received widespread attention in extracting lithium from brine mainly included precipitation,adsorption,solvent extraction,membrane separation and electrochemistry.The high price of lithium carbonate was fallen,and the international situation of lithium salt acquisition became increasingly severe.It was imperative to continuously develop and improve the lithium extraction technology,enhance the self-sufficiency of lithium resources,and achieve cost reduction and efficiency improvement of lithium extraction technology.

Cite this article

CHEN Haixia , YAN Hong , SUN Yunlong , MA Guoqiang . Research progress of lithium resource extraction technology[J]. Inorganic Chemicals Industry, 2024 , 56(1) : 9 -22 . DOI: 10.19964/j.issn.1006-4990.2023-0299

References

1 MENG Fei, MCNEICE J, ZADEH S S,et al.Review of lithium production and recovery from minerals,brines,and lithium-ion batteries[J].Mineral Processing and Extractive Metallurgy Review202142(2):123-141.
2 LIU Yubo, MA Baozhong, LV Yingwei,et al.Thorough extraction of lithium and rubidium from lepidolite via thermal activation and acid leaching[J].Minerals Engineering2022178:107407.
3 乜贞,伍倩,丁涛,等.中国盐湖卤水提锂产业化技术研究进展[J].无机盐工业202254(10):1-12.
  NIE Zhen, WU Qian, DING Tao,et al.Research progress on industrialization technology of lithium extraction from salt lake brine in China[J].Inorganic Chemicals Industry202254(10):1-12.
4 林钰青,张以任,邱宇隆,等.膜技术在盐湖提锂中的进展和展望[J].无机盐工业202355(1):33-45.
  LIN Yuqing, ZHANG Yiren, QIU Yulong,et al.Progress and prospect of membrane technology in lithium extraction from salt lake brine[J].Inorganic Chemicals Industry202355(1):33-45.
5 KELLY J C, WANG M, DAI Qiang,et al.Energy,greenhouse gas,and water life cycle analysis of lithium carbonate and lithium hydroxide monohydrate from brine and ore resources and their use in lithium ion battery cathodes and lithium ion batteries[J].Resources,Conservation and Recycling2021174:105762.
6 CARELLA E, HERNáNDEZ T.Ceramics for fusion reactors:The role of the lithium orthosilicate as breeder[J].Physica B:Condensed Matter2012407(22):4431-4435.
7 HANNAN M A, LIPU M S H, HUSSAIN A,et al.A review of lithium-ion battery state of charge estimation and management system in electric vehicle applications:Challenges and recommendations[J].Renewable and Sustainable Energy Reviews201778:834-854.
8 DEMBINSKA-KRAJEWSKA D, RYBAKOWSKI J K.Psychotropic drugs and personality changes:A case of lithium[J].Pharmacological Reports201567(6):1204-1207.
9 LI D, GUO J W, WANG X S,et al.Effects of crystal size on the mechanical properties of a lithium disilicate glass-ceramic[J].Materials Science and Engineering:A2016669:332-339.
10 FIKRY R M, EL-ADLY R A, ISMAIL N A,et al.Some azine and azole derivatives as antioxidant additives for lithium lubricating grease[J].Egyptian Journal of Petroleum201322(1):61-71.
11 KAVANAGH L, KEOHANE J, GARCIA CABELLOS G,et al.Global lithium sources:Industrial use and future in the electric vehicle industry:A review[J].Resources20187(3):57.
12 CHOUBEY P K, KIM M S, SRIVASTAVA R R,et al.Advance review on the exploitation of the prominent energy-storage element:Lithium.Part I:From mineral and brine resources[J].Minerals Engineering201689:119-137.
13 SWAIN B.Recovery and recycling of lithium:A review[J].Separation and Purification Technology2017172:388-403.
14 GOTO M, OKUMURA K, NAKAGAWA S,et al.Nuclear and thermal feasibility of lithium-loaded high temperature gas-cooled reactor for tritium production for fusion reactors[J].Fusion Engineering and Design2018136:357-361.
15 YOUSSEF A, ANWAR R, BASHTER I,et al.Neutron yield as a measure of achievement nuclear fusion using a mixture of deuterium and tritium isotopes[J].Physica Scripta202297(8):085601.
16 STEFANELLI E, PUCCINI M, PESETTI A,et al.Lithium orthosilicate as nuclear fusion breeder material:Optimization of the drip casting production technology[J].Nuclear Materials and Energy202230:101131.
17 KESLER S E, GRUBER P W, MEDINA P A,et al.Global lithium resources:Relative importance of pegmatite,brine and other deposits[J].Ore Geology Reviews201248:55-69.
18 邢凯,朱清,任军平,等.全球锂资源特征及市场发展态势分析[J].地质通报202342(8):1402-1421.
  XING Kai, ZHU Qing, REN Junping,et al.Analysis of global lithi-um resources characteristics and market development trend[J].Geological Bulletin of China202342(8):1402-1421.
19 GAO Tianming, FAN Na, CHEN Wu,et al.Lithium extraction from hard rock lithium ores(spodumene,lepidolite,zinnwaldite,petalite):Technology,resources,environment and cost[J].China Geology20236(1):137-153.
20 PEIRó L T, MéNDEZ G V, AYRES R U.Lithium:Sources,production,uses,and recovery outlook[J].Journal of Operations Management201365(8):986-996.
21 WANG Jiajia, YUE Xiyan, WANG Peifen,et al.Electrochemical technologies for lithium recovery from liquid resources:A revi-ew[J].Renewable and Sustainable Energy Reviews2022154:111813.
22 XU Longhua, TIAN Jia, WU Houqin,et al.Anisotropic surface chemistry properties and adsorption behavior of silicate mineral crystals[J].Advances in Colloid and Interface Science2018256:340-351.
23 SALAKJANI N K, SINGH P, NIKOLOSKI A N.Production of lithium:A literature review part 1:Pretreatment of spodumene[J].Mineral Processing and Extractive Metallurgy Review202041(5):335-348.
24 AYLMORE M G, MERIGOT K, RICKARD W D A,et al.Assessment of a spodumene ore by advanced analytical and mass spectrometry techniques to determine its amenability to processing for the extraction of lithium[J].Minerals Engineering2018119:137-148.
25 MOON K S, FUERSTENAU D W.Surface crystal chemistry in selective flotation of spodumene(LiAl[SiO32) from other aluminosilicates[J].International Journal of Mineral Processing200372(1/2/3/4):11-24.
26 KUAI Yuqing, YAO Wengui, MA Hongwen,et al.Recovery lithium and potassium from lepidolite via potash calcination-leaching process[J].Minerals Engineering2021160:106643.
27 MESHRAM P, PANDEY B D, MANKHAND T R.Extraction of lithium from primary and secondary sources by pre-treatment,leaching and separation:A comprehensive review[J].Hydrometallurgy2014150:192-208.
28 ZELIKMAN A N, KREIN O E, SAMSONOV G V.Metallurgy of rare metals[M].Washington,DC:NASA and National Science Foundation,1966:458.
29 林高逵.江西锂云母-石灰石烧结工艺的改进研究[J].稀有金属与硬质合金199927(2):46-48,14.
  LIN Gaokui.Improvement on sintering of Jiangxi limica and limestone[J].Rare Metals and Cemented Carbides199927(2):46-48,14.
30 YELATONTSEV D, MUKHACHEV A.Processing of lithium ores:Industrial technologies and case studies:A review[J].Hydrometallurgy2021201:105578.
31 RIOYO J, TUSET S, GRAU R.Lithium extraction from spodumene by the traditional sulfuric acid process:A review[J].Mineral Processing and Extractive Metallurgy Review202243(1):97-106.
32 ZHANG Yuqing, MA Baozhong, LV Yingwei,et al.An effective method for directly extracting lithium from α-spodumene by activated roasting and sulfuric acid leaching[J].Journal of Industrial and Engineering Chemistry2023122:540-550.
33 DESSEMOND C, SOUCY G, HARVEY J P,et al.Phase transitions in the α-γ-β spodumene thermodynamic system and impact of γ-spodumene on the efficiency of lithium extraction by acid leaching[J].Minerals202010(6):519.
34 SALAKJANI N K, SINGH P, NIKOLOSKI A N.Mineralogical transformations of spodumene concentrate from Greenbushes,Western Australia.Part 1:Conventional heating[J].Minerals Engineering201698:71-79.
35 ABDULLAH A A, OSKIERSKI H C, ALTARAWNEH M,et al.Phase transformation mechanism of spodumene during its calcination[J].Minerals Engineering2019140:105883.
36 KOTSUPALO N P, MENZHERES L T, RYABTSEV A D,et al.Mechanical activation of α-spodumene for further processing into lithium compounds[J].Theoretical Foundations of Chemical Engineering201044(4):503-507.
37 SALAKJANI N K, SINGH P, NIKOLOSKI A N.Acid roasting of spodumene:Microwave vs.conventional heating[J].Minerals Engineering2019138:161-167.
38 SALAKJANI N K, NIKOLOSKI A N, SINGH P.Mineralogical transformations of spodumene concentrate from Greenbushes,Western Australia.Part 2:Microwave heating[J].Minerals Engineering2017100:191-199.
39 LIU Jinlian, YIN Zhoulan, LI Xinhai,et al.Recovery of valuable metals from lepidolite by atmosphere leaching and kinetics on dissolution of lithium[J].Transactions of Nonferrous Metals Society of China201929(3):641-649.
40 VIECELI N, NOGUEIRA C A, PEREIRA M F C,et al.Optimization of lithium extraction from lepidolite by roasting using sodium and calcium sulfates[J].Mineral Processing and Extractive Metallurgy Review201738(1):62-72.
41 LUONG V T, KANG Dongjun, AN J W,et al.Factors affecting the extraction of lithium from lepidolite[J].Hydrometallurgy2013134-135:54-61.
42 SETOUDEH N, NOSRATI A, WELHAM N J.Lithium recovery from mechanically activated mixtures of lepidolite and sodium sulfate[J].Mineral Processing and Extractive Metallurgy2021130(4):354-361.
43 LUONG V T, KANG Dongjun, AN J W,et al.Iron sulphate roasting for extraction of lithium from lepidolite[J].Hydrometallurgy2014141:8-16.
44 ZHANG Xiufeng, CHEN Zhichao, ROHANI S,et al.Simultaneous extraction of lithium,rubidium,cesium and potassium from lepidolite via roasting with iron(Ⅱ) sulfate followed by water leaching[J].Hydrometallurgy2022208:105820.
45 YAN Qunxuan, LI Xinhai, WANG Zhixing,et al.Extraction of lithium from lepidolite by sulfation roasting and water leaching[J].International Journal of Mineral Processing2012110-111:1-5.
46 KONG Xiangzhong, YE Hua, QIN Yu.Factors of extracting lithium from lepidolite by sulfate roasting and dilute sulphuric acid leaching[J].Applied Mechanics and Materials2014522-524:1467-1470.
47 KUANG Ge, LIU Yu, LI Huan,et al.Extraction of lithium from β-spodumene using sodium sulfate solution[J].Hydrometallurgy2018177:49-56.
48 ALHADAD M F, OSKIERSKI H C, CHISCHI J,et al.Lithium extraction from β-spodumene:A comparison of keatite and analcime processes[J].Hydrometallurgy2023215:105985.
49 YAN Qunxuan, LI Xinhai, YIN Zhoulan,et al.A novel process for extracting lithium from lepidolite[J].Hydrometallurgy2012121-124:54-59.
50 CHEN Ya, TIAN Qianqiu, CHEN Baizhen,et al.Preparation of lithium carbonate from spodumene by a sodium carbonate autoclave process[J].Hydrometallurgy2011109(1/2):43-46.
51 SONG Yunfeng, ZHAO Tianyu, HE Lihua,et al.A promising approach for directly extracting lithium from α-spodumene by alkaline digestion and precipitation as phosphate[J].Hydrometallurgy2019189:105141.
52 XING Peng, WANG Chengyan, ZENG Lei,et al.Lithium extraction and hydroxysodalite zeolite synthesis by hydrothermal conversion of α-spodumene[J].ACS Sustainable Chemistry & Engineering20197(10):9498-9505.
53 GAIDOUMI A EL, BENABDALLAH A C, BALI B EL,et al.Synthesis and characterization of zeolite HS using natural pyrophyllite as new clay source[J].Arabian Journal for Science and Engineering201843(1):191-197.
54 KUNDU D, DEY B, NASKAR M K,et al.Emulsion-derived urchin-shaped hydroxy sodalite particles[J].Materials Letters201064(14):1630-1633.
55 LV Yingwei, XING Peng, MA Baozhong,et al.Efficient extraction of lithium and rubidium from polylithionite via alkaline leaching combined with solvent extraction and precipitation[J].ACS Sustainable Chemistry & Engineering20208(38):14462-14470.
56 MULWANDA J, SENANAYAKE G, OSKIERSKI H,et al.Leaching of lepidolite and recovery of lithium hydroxide from purified alkaline pressure leach liquor by phosphate precipitation and lime addition[J].Hydrometallurgy2021201:105538.
57 YANG Hui, MA Baozhong, LV Yingwei,et al.Novel technology for synergistic extraction of Li and Rb from a complex lithium concentrate[J].ACS Sustainable Chemistry & Engineering202210(36):12030-12040.
58 李良彬,刘明,彭爱平,等.锂云母提锂工艺及工业化应注意的问题[J].世界有色金属2014(8):37-39.
59 LIU Yubo, LV Yingwei, MA Baozhong,et al.An environmentally friendly improved chlorination roasting process for lepidolite with reduced chlorinating agent dosage and chlorinated waste gas emission[J].Separation and Purification Technology2023310:123173.
60 BARBOSA L I, VALENTE G, OROSCO R P,et al.Lithium extraction from β-spodumene through chlorination with chlorine gas[J].Minerals Engineering201456:29-34.
61 BARBOSA L I, GONZáLEZ J A, DEL CARMEN RUIZ M.Extraction of lithium from β-spodumene using chlorination roasting with calcium chloride[J].Thermochimica Acta2015605:63- 67.
62 YAN Qunxuan, LI Xinhai, WANG Zhixing,et al.Extraction of lithium from lepidolite using chlorination roasting-water leaching process[J].Transactions of Nonferrous Metals Society of China201222(7):1753-1759.
63 ZHANG Xiufeng, ALDAHRI T, TAN Xiumin,et al.Efficient co-extraction of lithium,rubidium,cesium and potassium from lepidolite by process intensification of chlorination roasting[J].Chemical Engineering and Processing:Process Intensification2020147:107777.
64 GUO Hui, LV Menghua, KUANG Ge,et al.Stepwise heat treatment for fluorine removal on selective leachability of Li from lepidolite using HF/H2SO4 as lixiviant[J].Separation and Purification Technology2021259:118194.
65 ROSALES G D, DEL CARMEN RUIZ M, RODRIGUEZ M H.Novel process for the extraction of lithium from β-spodumene by leaching with HF[J].Hydrometallurgy2014147-148:1-6.
66 GUO Hui, KUANG Ge, WANG Haidong,et al.Investigation of enhanced leaching of lithium from α-spodumene using hydrofluoric and sulfuric acid[J].Minerals20177(11):205.
67 GUO Hui, LV Menghua, KUANG Ge,et al.Enhanced lithium extraction from α-spodumene with fluorine-based chemical method:A stepwise heat treatment for fluorine removal[J].Minerals Engineering2021174:107246.
68 GUO Hui, YU Haizhao, ZHOU Anan,et al.Kinetics of leaching lithium from α-spodumene in enhanced acid treatment using HF/H2SO4 as medium[J].Transactions of Nonferrous Metals Society of China201929(2):407-415.
69 WANG Haidong, ZHOU Anan, GUO Hui,et al.Kinetics of leaching lithium from lepidolite using mixture of hydrofluoric and sulfuric acid[J].Journal of Central South University202027(1):27-36.
70 GUO Hui, KUANG Ge, LI Huan,et al.Enhanced lithium leaching from lepidolite in continuous tubular reactor using H2SO4+H2SiF6 as lixiviant[J].Transactions of Nonferrous Metals Society of China202131(7):2165-2173.
71 张亮,杨卉芃,柳林,等.全球提锂技术进展[J].矿产保护与利用202040(5):24-31.
  ZHANG Liang, YANG Huipeng, LIU Lin,et al.Global technology trends of lithium extraction[J].Conservation and Utilization of Mineral Resources202040(5):24-31.
72 CATOVIC E.Process for extracting and recovering lithium values from lithium bearing materials:US,10883157[P].2021-01-05.
73 ZHU Rong, WANG Shixin, SRINIVASAKANNAN C,et al.Lithium extraction from salt lake brines with high magnesium/lithium ratio:A review[J].Environmental Chemistry Letters202321(3):1611-1626.
74 VERA M L, TORRES W R, GALLI C I,et al.Environmental impact of direct lithium extraction from brines[J].Nature Reviews Earth & Environment20234(3):149-165.
75 PAN Yanan, YU Jianguo, LIN Sen.A rational strategy for synchronous extraction of lithium and boron from salt lake brines[J].Chemical Engineering Science2023276:118757.
76 XU Ping, HONG Jun, QIAN Xiaoming,et al.Materials for lithium recovery from salt lake brine[J].Journal of Materials Science202156(1):16-63.
77 ZHANG Ye, HU Yuehua, WANG Li,et al.Systematic review of lithium extraction from salt-lake brines via precipitation approaches[J].Minerals Engineering2019139:105868.
78 WANG Huaiyou, ZHONG Yuan, DU Baoqiang,et al.Recovery of both magnesium and lithium from high Mg/Li ratio brines using a novel process[J].Hydrometallurgy2018175:102-108.
79 LIU Jinlian, YIN Zhoulan, LI Xinhai,et al.A novel process for the selective precipitation of valuable metals from lepidolite[J].Minerals Engineering2019135:29-36.
80 XIAO Chao, XIAO Liansheng, GAO Congjie,et al.Thermodynamic study on removal of magnesium from lithium chloride solutions using phosphate precipitation method[J].Separation and Purification Technology2015156:582-587.
81 HE Lihua, XU Wenhua, SONG Yunfeng,et al.Selective removal of magnesium from a lithium-concentrated anolyte by magnesium ammonium phosphate precipitation[J].Separation and Purification Technology2017187:214-220.
82 ZHANG Ye, HU Yuehua, SUN Ning,et al.A novel precipitant for separating lithium from magnesium in high Mg/Li ratio brine[J].Hydrometallurgy2019187:125-133.
83 LAI Xianrong, XIONG Pan, ZHONG Hui.Extraction of lithium from brines with high Mg/Li ratio by the crystallization-precipita-tion method[J].Hydrometallurgy2020192:105252.
84 张丽芬,张大义,欧阳红勇,等.高镁锂比盐湖卤水镁锂分离工艺[J].矿冶工程201636(4):83-87.
  ZHANG Lifen, ZHANG Dayi, OUYANG Hongyong,et al.Technique for separating magnesium and lithium from salt lake brine with high Mg/Li ratio[J].Mining and Metallurgical Engineering201636(4):83-87.
85 REICH R, SLUNITSCHEK K, DANISI R M,et al.Lithium extraction techniques and the application potential of different sorbents for lithium recovery from brines[J].Mineral Processing and Extractive Metallurgy Review202344(4):261-280.
86 PARANTHAMAN M P, LI Ling, LUO Jiaqi,et al.Recovery of lithium from geothermal brine with lithium-aluminum layered double hydroxide chloride sorbents[J].Environmental Science & Technology201751(22):13481-13486.
87 ZHONG Jing, LIN Sen, YU Jianguo.Effects of excessive lithium deintercalation on Li+ adsorption performance and structural stability of lithium/aluminum layered double hydroxides[J].Journal of Colloid and Interface Science2020572:107-113.
88 YU T M, CAROLINE REIS MEIRA A, CRISTINA KREUTZ J,et al.Exploring the surface reactivity of the magnetic layered double hydroxide lithium-aluminum:An alternative material for sorption and catalytic purposes[J].Applied Surface Science2019467-468:1195-1203.
89 LU Mengxiang, SHAO Liqiang, YANG Ying,et al.Simultaneous recovery of lithium and boron from brine by the collaborative adsorption of lithium-ion sieves and boron chelating resins[J].Industrial & Engineering Chemistry Research202362(3):1508-1522.
90 BAO Luri, ZHANG Jingze, TANG Weiping,et al.Synthesis and adsorption properties of metal oxide-coated lithium ion-sieve from salt lake brine[J].Desalination2023546:116196.
91 张理元,沈如倩,阳金菊,等.锂离子筛研究进展[J].无机盐工业202254(5):28-37.
  ZHANG Liyuan, SHEN Ruqian, YANG Jinju,et al.Research progress on lithium ion sieves[J].Inorganic Chemicals Industry202254(5):28-37.
92 TIAN Liyan, MA Wei, HAN Mei.Adsorption behavior of Li+ onto nano-lithium ion sieve from hybrid magnesium/lithium manganese oxide[J].Chemical Engineering Journal2010156(1):134-140.
93 LIN Hongyu, YU Xiaoping, LI Mingli,et al.Synthesis of polyporous ion-sieve and its application for selective recovery of lithium from geothermal water[J].ACS Applied Materials & Interfaces201911(29):26364-26372.
94 LIU Minxia, WU Dang, QIN Dongling,et al.Spray-drying assisted layer-structured H2TiO3 ion sieve synthesis and lithium adsorption performance[J].Chinese Journal of Chemical Engineering202245:258-267.
95 MOAZENI M, HAJIPOUR H, ASKARI M,et al.Hydrothermal synthesis and characterization of titanium dioxide nanotubes as novel lithium adsorbents[J].Materials Research Bulletin201561:70-75.
96 WEI Shudan, WEI Yuanfeng, CHEN Tao,et al.Porous lithium ion sieves nanofibers:General synthesis strategy and highly selective recovery of lithium from brine water[J].Chemical Engineering Journal2020379:122407.
97 LI Xiaowei, CHEN Linlin, CHAO Yanhong,et al.Highly selective separation of lithium with hierarchical porous lithium-ion sieve microsphere derived from MXene[J].Desalination2022537:115847.
98 ZHANG Junxiang, CHENG Zeyu, QIN Xinbo,et al.Recent advances in lithium extraction from salt lake brine using coupled and tandem technologies[J].Desalination2023547:116225.
99 康锦,卫丽娜,成怀刚.离子液体用于盐湖卤水萃取提锂的研究进展[J].无机盐工业202254(1):1-6.
  KANG Jin, WEI Lina, CHENG Huaigang.Research progress on application of ionic liquids in extracting lithium from salt lak-es[J].Inorganic Chemicals Industry202254(1):1-6.
100 LI Zheng, BINNEMANS K.Selective removal of magnesium from lithium-rich brine for lithium purification by synergic solvent extraction using β-diketones and Cyanex 923[J].AIChE Journal202066(7):e16246.
101 BUKOWSKY H, UHLEMANN E, GLOE K,et al.The separation of calcium and magnesium from lithium chloride by liquid-liquid extraction with di(2-ethylhexyl) phosphoric acid[J].Hydrometallurgy199228(3):323-329.
102 ZHOU Zhiyong, QIN Wei, LIANG Shengke,et al.Recovery of lithium using tributyl phosphate in methyl isobutyl ketone and FeCl3 [J].Industrial & Engineering Chemistry Research201251(39):12926-12932.
103 XIANG Wei, LIANG Shengke, ZHOU Zhiyong,et al.Extraction of lithium from salt lake brine containing borate anion and high concentration of magnesium[J].Hydrometallurgy2016166:9-15.
104 QIAO Linju, CHEN Hang, YU Jianguo.Recovery of lithium from salt-lake brine by liquid-liquid extraction using TBP-FeCl3 based mixture solvent[J].The Canadian Journal of Chemical Engineering2023101(4):2139-2147.
105 SONG Jianfeng, HUANG Tao, QIU Hongbin,et al.Recovery of lithium from salt lake brine of high Mg/Li ratio using Na[FeCl4?2TBP] as extractant:Thermodynamics,kinetics and process- es[J].Hydrometallurgy2017173:63-70.
106 YU Xiaoping, FAN Xuebing, GUO Yafei,et al.Recovery of lithium from underground brine by multistage centrifugal extraction using tri-isobutyl phosphate[J].Separation and Purification Technology2019211:790-798.
107 HORMATI A, REZAI B, HAMIDIAN SHOORMASTI H,et al.Extraction of lithium ions from salt lake brine using magnetic ionic liquid:Kinetic and equilibrium studies[J].Inorganic Che- mistry Communications2022142:109693.
108 FOO Z H, REHMAN D, BOUMA A T,et al.Lithium concentration from salt-lake brine by donnan-enhanced nanofiltration[J].Environmental Science & Technology202357(15):6320-6330.
109 WANG Wenguang, HONG Guanghui, ZHANG Yanqiu,et al.Designing an energy-efficient multi-stage selective electrodialysis process based on high-performance materials for lithium extraction[J].Journal of Membrane Science2023675:121534.
110 CHILDRESS A E, ELIMELECH M.Relating nanofiltration membrane performance to membrane charge(electrokinetic) characteristics[J].Environmental Science & Technology200034(17):3710-3716.
111 ZHANG Haizhen, XU Zhenliang, DING Hao,et al.Positively charged capillary nanofiltration membrane with high rejection for Mg2+ and Ca2+ and good separation for Mg2+ and Li+ [J].Desalination2017420:158-166.
112 CHEN Yongliang, LIU Fu, WANG Yi,et al.A tight nanofiltration membrane with multi-charged nanofilms for high rejection to concentrated salts[J].Journal of Membrane Science2017537:407-415.
113 GUO Yi, YING Yulong, MAO Yiyin,et al.Polystyrene sulfonate threaded through a metal-organic framework membrane for fast and selective lithium-ion separation[J].Angewandte Chemie International Edition201655(48):15120-15124.
114 SUN Shuying, NIE Xiaoyao, HUANG Jun,et al.Molecular simulation of diffusion behavior of counterions within polyelectrolyte membranes used in electrodialysis[J].Journal of Membrane Science2020595:117528.
115 LIU Gui, ZHAO Zhongwei, HE Lihua.Highly selective lithium recovery from high Mg/Li ratio brines[J].Desalination2020474:114185.
116 PAN Xijuan, DOU Zhihe, MENG Deliang,et al.Electrochemical separation of magnesium from solutions of magnesium and lithium chloride[J].Hydrometallurgy2020191:105166.
117 ZHAO Zhongwei, SI Xiufen, LIU Xuheng,et al.Li extraction from high Mg/Li ratio brine with LiFePO4/FePO4 as electrode materials[J].Hydrometallurgy2013133:75-83.
118 XIONG Jiachun, HE Lihua, LIU Dongfu,et al.Olivine-FePO4 preparation for lithium extraction from brines via electrochemical de-intercalation/Intercalation method[J].Desalination2021520:115326.
119 XU Wenhua, LIU Dongfu, LIU Xuheng,et al.Highly selective and efficient lithium extraction from brines by constructing a novel multiple-crack-porous LiFePO4/FePO4 electrode[J].Desalination2023546:116188.
120 XU Xin, ZHOU You, FENG Zhiwen,et al.A self-supported λ-MnO 2 film electrode used for electrochemical lithium recovery from brines[J].ChemPlusChem201883(6):521-528.
121 MU Yingxin, ZHANG Chengyi, ZHANG Wen,et al.Electrochemical lithium recovery from brine with high Mg2+/Li+ ratio using mesoporous λ-MnO2/LiMn2O4 modified 3D graphite felt electrodes[J].Desalination2021511:115112.
Outlines

/