Inorganic Chemicals Industry >
Study on preparation process of calcium magnesium acetate snowmelt agent from phosphorous tailings by acetic acid hydrolysis
Received date: 2023-02-22
Online published: 2024-01-18
Using solid waste phosphorus tailings generated from phosphate ore beneficiation as raw materials，in order to recover the valuable elements of calcium and magnesium from the solid waste of phosphate rock，calcium and magnesium acetate was prepared and P2O5 was enriched in the solid waste of phosphate rock.An experimental study on the hydrolysis of phosphate tailings by acetic acid was carried out.The effects of acetic acid dosage，liquid-solid mass ratio，reaction temperature，stirring rate and reaction time on the leaching rate of calcium and magnesium from phosphate tailings were investigated.The results showed that the leaching rate of CaO and MgO could reach 78.26% and 76.32% under the conditions of liquid-solid mass ratio of 14∶1，reaction temperature of 90 ℃，stirring rate of 1 000 r/min and reaction time of 3 h，respectively.The content of P2O5 in phosphate tailings could be increased from 8.82% to 25.91%.Calcium and magnesium acetate were obtained by evaporation and crystallization of acid-hydrolysate after pH adjustment.The characterization and performance tests were carried out.The results showed that its indicators met the requirements of GB/T 23851—2017 “Snowmelt Agent”，and it was an environmentally friendly snowmelt agent with low corrosion，degradability and excellent ice and snow melting performance.
LI Mengyu , TANG Jianwei , LIU Yong , HUA Quanxian , LIU Pengfei , WANG Baoming . Study on preparation process of calcium magnesium acetate snowmelt agent from phosphorous tailings by acetic acid hydrolysis[J]. Inorganic Chemicals Industry, 2024 , 56(1) : 73 -80 . DOI: 10.19964/j.issn.1006-4990.2023-0086
| 1 | 郑建国，于南树，刘永秀，等.磷酸活化磷尾矿制取聚合态钙镁磷肥的工艺条件研究［J］.无机盐工业，2020，52（2）：43-46. |
| ZHENG Jianguo， YU Nanshu， LIU Yongxiu，et al.Study on technological conditions of polymeric calcium magnesium phosphate fertilizer from phosphoric acid activated phosphate tailings［J］.Inorganic Chemicals Industry，2020，52（2）：43-46. | |
| 2 | 张汉泉，许鑫，胡超杰，等.磷化工固体废弃物综合利用技术现状［J］.中国矿业，2021，30（4）：50-55，63. |
| ZHANG Hanquan， XU Xin， HU Chaojie，et al.Current situation of comprehensive utilization technology of solid waste of phosphorus chemical［J］.China Mining Magazine，2021，30（4）：50-55，63. | |
| 3 | 吴发富，王建雄，刘江涛，等.磷矿的分布、特征与开发现状［J］.中国地质，2021，48（1）：82-101. |
| WU Fafu， WANG Jianxiong， LIU Jiangtao，et al.Distribution，geology and development status of phosphate resources［J］.Geology in China，2021，48（1）：82-101. | |
| 4 | 杨成.磷尾矿的综合利用试验研究［D］.武汉：武汉工程大学，2018. |
| YANG Cheng.Study on the comprehensive utilization of phosphate tailings［D］.Wuhan：Wuhan Institute of Technology，2018. | |
| 5 | ABDEL-HAKEEM M， EL-HABAAK G.The potential production of rock-based fertilizer and soil conditioner from phosphate mine wastes：A case study from Abu-Tartur Plateau in the Western Desert of Egypt［J］.Journal of Cleaner Production，2021，329：129761. |
| 6 | ARROUG L， ELAATMANI M， ZEGZOUTI A，et al.Low-grade phosphate tailings beneficiation via organic acid leaching：Process optimization and kinetic studies［J］.Minerals，2021，11（5）：492. |
| 7 | 颜鑫，魏义兰.含钙镁废渣综合利用的现状及展望［J］.无机盐工业，2022，54（1）：7-11. |
| YAN Xin， WEI Yilan.Present situation and prospect of comprehensive utilization of waste residue containing calcium and magnesium［J］.Inorganic Chemicals Industry，2022，54（1）：7-11. | |
| 8 | 周雪娜，关洪亮，何东升，等.磷尾矿综合利用研究进展［J］.广州化工，2021，49（5）：24-27. |
| ZHOU Xuena， GUAN Hongliang， HE Dongsheng，et al.Research progress on comprehensive utilization by phosphate tailings［J］.Guangzhou Chemical Industry，2021，49（5）：24-27. | |
| 9 | 黄洋，叶义成，胡南燕，等.磷尾矿材料化综合利用途径研究进展［J］.材料导报，2021，35（S2）：279-284，293. |
| HUANG Yang， YE Yicheng， HU Nanyan，et al.Research progress in materialized utilization of phosphate tailings［J］.Materials Reports，2021，35（S2）：279-284，293. | |
| 10 | 苗俊艳，王艳语，许秀成.中低品位磷矿及磷尾矿的综合利用现状［J］.硫磷设计与粉体工程，2019（6）：11-13，27，4. |
| MIAO Junyan， WANG Yanyu， XU Xiucheng.Current utilization of medium-and low-grade phosphate ore and tailing［J］.Sulphur Phosphorus & Bulk Materials Handling Related Engineering，2019（6）：11-13，27，4. | |
| 11 | 周佳琦，陈葵，武斌，等.磷尾矿煅烧及酸浸过程动力学研究［J］.无机盐工业，2022，54（1）：77-82，108. |
| ZHOU Jiaqi， CHEN Kui， WU Bin，et al.Study on kinetics of phosphate tailings calcination and acid leaching process［J］.Inorganic Chemicals Industry，2022，54（1）：77-82，108. | |
| 12 | 王东东.赤泥质缓蚀型融雪剂的制备及其性能研究［D］.哈尔滨：黑龙江大学，2019. |
| WANG Dongdong.Study on preparation and properties of red mud corrosion-inhibiting snowmelt agent［D］.Harbin：Heilongjiang University，2019. | |
| 13 | 夏伟.膜萃取稀醋酸废水生产醋酸钙镁盐的研究［D］.大连：大连理工大学，2008. |
| XIA Wei.Study on producing calcium magnesium acetate from acetic acid wastewater via membrane extraction［D］.Dalian：Dalian University of Technology，2008. | |
| 14 | 薛玉婷，孙衍忠，周斌.环保型融雪剂新工艺及产品性能研究［J］.化工管理，2020（27）：61-62. |
| 15 | 韩爱霞，吕海棠，王兆谦，等.乳清两步发酵法制取环保型融雪剂醋酸钙镁盐［J］.无机盐工业，2012，44（2）：48-50. |
| HAN Aixia， Haitang Lü， WANG Zhaoqian，et al.Production of environment friendly deicer calcium magnesium acetate by two-stage fermentation process from cheese whey［J］.Inorganic Che- | |
| Industry micals，2012，44（2）：48-50. | |
| 16 | 王腾，郭德栋，周小鹏，等.道路融雪剂融冰能力试验方法的改进研究［J］.中外公路，2020，40（2）：195-198. |
| WANG Teng， GUO Dedong， ZHOU Xiaopeng，et al.Research on test method improvement for deicing ability of road snow-melting agent［J］.Journal of China & Foreign Highway，2020，40（2）：195-198. | |
| 17 | 景金华，何冰.道路融雪剂性能评价方法对比研究［J］.市政技术，2022，40（7）：51-56. |
| JING Jinhua， HE Bing.Comparative study on evaluation methods for snowmelt agent performance［J］.Journal of Municipal Technology，2022，40（7）：51-56. |
/
| 〈 |
|
〉 |