Research & Development

Study on spinning molding and performance of Ti-based lithium ion sieve powder and PVDF resin

  • HU Yue ,
  • MO Hengliang ,
  • LI Tianyu ,
  • PENG Wenjuan ,
  • SUN Guangdong ,
  • XIAO Hongkang ,
  • CHEN Yili ,
  • LI Suoding ,
  • TANG Yang
Expand
  • 1.Beijing Origin Water Membrane Technology Co.,Ltd.,Beijing 101400,China
    2.Urban-Rural Water Environment Technology Research and Developments Center of China Jiaotong Group,Beijing 100029,China
    3.Beijing University of Chemical Technology,Beijing 100029,China

Received date: 2022-12-16

  Online published: 2023-11-16

Abstract

In order to realize the granulation molding of titanium-based lithium ion sieve(H2TiO3-LIS) powder and large-scale application in lithium extraction from salt lakes,H2TiO3-LIS powder was formed by spinning.The optimal formula and process conditions were determined,the amount of PVDF was accounted for 20% of the total mass of PVDF and H2TiO3-LIS powder,the amount of PVP-K60 was accounted for 80% of the mass of PVDF,the temperature of the solidification bath was 80 ℃,the length of the air section was 20 cm,and the length of the shredding was 3 mm.The granulated adsorbent was used in the lithium extraction test of Golmud Salt Lake brine.The results showed that the mass adsorption capacity of the H2TiO3-LIS particle adsorbent for Li+ was 9.3 mg/g and the volume adsorption capacity was 3.6 g/L,and the operation stability was good.After 30 cycles,the adsorption capacity was 92.5% of the initial adsorption capacity.

Cite this article

HU Yue , MO Hengliang , LI Tianyu , PENG Wenjuan , SUN Guangdong , XIAO Hongkang , CHEN Yili , LI Suoding , TANG Yang . Study on spinning molding and performance of Ti-based lithium ion sieve powder and PVDF resin[J]. Inorganic Chemicals Industry, 2023 , 55(11) : 58 -63 . DOI: 10.19964/j.issn.1006-4990.2022-0739

References

1 LIU Gui, ZHAO Zhongwei, GHAHREMAN A.Novel approaches for lithium extraction from salt-lake brines:A review[J].Hydrometallurgy2019187:81-100.
2 程梦茹,王舒,宫飞祥 等.锰系锂离子筛的制备及成型方式研究进展[J/OL].盐湖研究:1-12[2023-08-18].http://kns.cnki.net/kcms/detail/63.1026.p.20220719.1528.015.html.
  CHENG Mengru, WANG Shu, GONG Feixiang,et al.Research progress on preparation and formating method of manganese series lithium ion sieve[J/OL].Journal of Salt Lake Research:1-12[2023-08-18].http://kns.cnki.net/kcms/detail/63.1026.p.20220719.1528.015.html.
3 SUN Ying, WANG Qi, WANG Yunhao,et al.Recent advances in magnesium/lithium separation and lithium extraction technologies from salt lake brine[J].Separation and Purification Technology2021256:117807.
4 李燕茹,袁建军,朱亮,等.盐湖卤水碳酸锂提取工艺过程研究[J].无机盐工业201345(7):12-14.
  LI Yanru, YUAN Jianjun, ZHU Liang,et al.Research on extraction process of lithium carbonate from salt lake brine[J].Inorganic Chemicals Industry201345(7):12-14.
5 乜贞,伍倩,丁涛,等.中国盐湖卤水提锂产业化技术研究进展[J].无机盐工业202254(10):1-12.
  NIE Zhen, WU Qian, DING Tao,et al.Research progress on industrialization technology of lithium extraction from salt lake brine in China[J].Inorganic Chemicals Industry202254(10):1-12.
6 罗清平,郭朋成,李存增,等.我国锂资源分布及提取工艺研究现状[J].湿法冶金201231(2):67-70.
  LUO Qingping, GUO Pengcheng, LI Cunzeng,et al.Distribution of lithium resources and research status on lithium extraction technology[J].Hydrometallurgy of China201231(2):67-70.
7 周苏禹.LTO型锂离子筛的改性与成型[D].上海:上海师范大学,2022.
  ZHOU Suyu.Modification and molding of LTO lithium ion scre-en[D].Shanghai:Shanghai Normal University,2022.
8 陈旺,蒋磊,潘巧珍,等.钛系锂离子筛的制备及其吸附性能研究[J].无机盐工业202153(10):47-51.
  CHEN Wang, JIANG Lei, PAN Qiaozhen,et al.Research on preparation and adsorption performance of titanium lithium ion sieve[J].Inorganic Chemicals Industry202153(10):47-51.
9 YAN Qunxuan, LI Xinhai, WANG Zhixing,et al.Extraction of lithium from lepidolite by sulfation roasting and water leaching[J].International Journal of Mineral Processing2012110/111:1-5.
10 王涛,孟庆祥,许海涛,等.纳米纤维锂离子筛吸附剂的制备及表征[J].无机盐工业201648(3):29-33.
  WANG Tao, MENG Qingxiang, XU Haitao,et al.Preparation and characterization of lithium ion sieve nanofibrous adsorbents[J].Inorganic Chemicals Industry201648(3):29-33.
11 史丹丹,许乃才.锰氧化物锂离子筛盐湖卤水提锂研究进展[J].无机盐工业201547(11):11-14,19.
  SHI Dandan, XU Naicai.Progress in extracting lithium from salt lake brine by lithium ionic sieve of manganese oxides[J].Inorganic Chemicals Industry201547(11):11-14,19.
12 张瑞,钟静,林森,等.盐湖铝系提锂吸附剂成型条件的影响研究[J].化工学报202172(12):6291-6297.
  ZHANG Rui, ZHONG Jing, LIN Sen,et al.Study on the influence of granulation conditions on Li/Al-LDHs for lithium recovery from low grade brine[J].CIESC Journal202172(12):6291-6297.
13 陈琳琳,李小为,蒋磊,等.钛系颗粒状吸附剂用于盐湖卤水中锂的吸附研究[J].当代化工研究2021(21):4-7.
  CHEN Linlin, LI Xiaowei, JIANG Lei,et al.Study on adsorption of lithium from salt lake brine by titanium-based granulated adsorbent[J].Modern Chemical Research2021(21):4-7.
14 孙建科,陈进,易大伟.离子筛型锂吸附剂的成型及研究进展[J].化工新型材料202250(2):293-297.
  SUN Jianke, CHEN Jin, YI Dawei.Research progress on molding of ionic sieve type Li adsorbent[J].New Chemical Materials202250(2):293-297.
Outlines

/