Inorganic Chemicals Industry >
Research progress of preparation and application of nano-sized chromium oxide
Received date: 2023-01-04
Online published: 2023-10-16
Chromium oxide（Cr2O3），as one of the main products of inorganic salt industry，is widely used in chemical industry，metallurgy，machinery and other industries，and plays an important role in the national economy.A large number of studies showed that when the particle size of Cr2O3 was nanoscale，it would have more unique effects（such as small size effect，surface effect，etc.），which provided new ideas for the development and application of new materials.Based on the latest progress of the research and application of nano Cr2O3 both domestically and internationally in recent years，the preparation methods of nano Cr2O3 were reviewed in detail，including gas-phase method（chemical vapor deposition，microwave plasma method，laser vapor deposition），wet-chemical method（precipitation method，microemulsion method，sol-gel method，hydrothermal/solvothermal method，template method） and solid-phase method（solid-state thermal decomposition，high-energy ball milling）.In addition to traditional application scenarios such as pigments，wear and corrosion resistance coatings，gas sensors，the application progress of nano-sized Cr2O3 in emerging fields such as high efficiency catalysis，new energy materials was introduced.Through summarizing and comparing，the suggestion of combination of wet-chemical method andsolid-phase method to achieve large-scale preparation of highly stable nano-sized Cr2O3 was put forward.Moreover，it was pointed out that the transformation of energy structure in China was expected to lead to a new application scenario ofnano-sized Cr2O3 in key materials for energy storage systems under the background of carbon peaking and carbon neutralitygoals.
XU Enhao , WU Kaipeng . Research progress of preparation and application of nano-sized chromium oxide[J]. Inorganic Chemicals Industry, 2023 , 55(10) : 24 -34 . DOI: 10.19964/j.issn.1006-4990.2023-0007
| 1 | PANG Xiaolu， GAO Kewei， LUO Fei，et al.Investigation of microstructure and mechanical properties of multi-layer Cr/Cr2O3 coatings［J］.Thin Solid Films，2009，517（6）：1922-1927. |
| 2 | 杨雄.氧化铬基涂层的制备及其摩擦磨损性能研究［D］.武汉：武汉理工大学，2019. |
| YANG Xiong.The preparation and tribological properties of Cr2O3-based coating［D］.Wuhan：Wuhan University of Technology，2019. | |
| 3 | ?ZGüR M E，ULU A， GüRSES C，et al.The cytotoxicity，DNA fragmentation，and decreasing velocity induced by chromium（Ⅲ） oxide on rainbow trout spermatozoa［J］.Biological Trace Element Research，2023，201（2）：968-983. |
| 4 | SADEGHI N， KHORSHIDI A， GANJALI M.Cr2O3 nanoparticles composited with MWCNTs as an efficient electrocatalyst for the oxygen reduction reaction［J］.Inorganic Chemistry Communications，2021，126：108489. |
| 5 | ZHANG Daixiong， LI Xueming， QIN Bo，et al.Fabrication of chromium（Ⅲ） oxide（Cr2O3） coating by electrophoretic deposition［J］.Journal of the American Ceramic Society，2014，97（11）：3413-3417. |
| 6 | LIANG Shuting， ZHANG Hongling， LUO Minting，et al.Colour performance investigation of a Cr2O3 green pigment prepared via the thermal decomposition of CrOOH［J］.Ceramics International，2014，40（3）：4367-4373. |
| 7 | CAO Jun， XU Yingming， SUI Lili，et al.Highly selective low-temperature triethylamine sensor based on Ag/Cr2O3 mesoporous microspheres［J］.Sensors and Actuators B：Chemical，2015，220：910-918. |
| 8 | LI Yongtao， LIU Yuzhou， SHI Chenyong，et al.Carbon/Cr2O3 nanocrystal composites as an anode with improved lithium storage performance［J］.International Journal of Electrochemical Science，2022，17（3）：220311. |
| 9 | LIN H T， HUANG J L， LO W T，et al.Investigation on carbonizing behaviors of nanometer-sized Cr2O3 particles dispersed on alumina particles by metalorganic chemical vapor deposition in fluidized bed［J］.Journal of Materials Research，2005，20（8）：2154-2160. |
| 10 | HAFEEZ M， SIDDIQUE SALEEMI A， REHMAN S UR，et al.CVD growth of layered Cr2O3 hexagonal flakes for optoelectronic applications［J］.Applied Surface Science，2021，536：147713. |
| 11 | CHEVALIER S， BONNET G， LARPIN J P.Metal-organic chemical vapor deposition of Cr2O3 and Nd2O3 coatings.Oxide growth kinetics and characterization［J］.Applied Surface Science，2000，167（3/4）：125-133. |
| 12 | 李帅，何迪，刘晓鹏，等.一种氧化铬薄膜的制备方法：中国，103805960A［P］.2014-05-21. |
| 13 | VOLLATH D， SZABó D V， WILLIS J O.Magnetic properties of nanocrystalline Cr2O3 synthesized in a microwave plasma［J］.Materials Letters，1996，29（4/5/6）：271-279. |
| 14 | NADEEM K， KAMRAN M， JAVED A，et al.Role of surface spins on magnetization of Cr2O3 coated γ-Fe2O3 nanoparticles［J］.Solid State Sciences，2018，83：43-48. |
| 15 | BALAKRISHNAN G， KUPPUSAMI P， SAIRAM T N，et al.Influence of background gas atmosphere on formation of Cr2O3 thin films prepared by pulsed laser deposition［J］.Surface Engineering，2009，25（3）：223-227. |
| 16 | SI P Z， WANG X L， XIAO X F，et al.Structure and magnetic properties of Cr2O3/CrO2 nanoparticles prepared by reactive laser ablation and oxidation under high pressure of oxygen［J］.Journal of Magnetics，2015，20（3）：211-214. |
| 17 | VILA M， RUBIO-ZUAZO J， LUCAS I，et al.Ferromagnetic epitaxial Cr2O3 thin films grown on oxide substrates by pulsed laser deposition［J］.Applied Surface Science，2020，534：147638. |
| 18 | ZHANG Wenxia， LIANG Yan， LUO Jianwei，et al.Morphological effects of ordered Cr2O3 nanorods and Cr2O3 nanoparticles on fluorination of 2-chloro-1，1，1-trifluoroethane［J］.Journal of Materials Science，2016，51（13）：6488-6496. |
| 19 | ABBAS S M， AHMAD N， RANA U ALI，et al.High rate capability and long cycle stability of Cr2O3 anode with CNTs for lithium ion batteries［J］.Electrochimica Acta，2016，212：260-269. |
| 20 | ABECASSIS-WOLFOVICH M， ROTTER H， LANDAU M V，et al.Texture and nanostructure of chromia aerogels prepared by urea-assisted homogeneous precipitation and low-temperature supercritical drying［J］.Journal of Non-Crystalline Solids，2003，318（1/2）：95-111. |
| 21 | 邓彤彤，彭振山.超细氧化铬制备方法的研究进展［J］.无机盐工业，2003，35（4）：5-7. |
| DENG Tongtong， PENG Zhenshan.Preparation technique of ultra-fine chromium oxide powder［J］.Inorganic Chemicals Industry，2003，35（4）：5-7. | |
| 22 | BAI Guangmei， DAI Hongxing， LIU Yuxi，et al.Preparation and catalytic performance of cylinder-and cake-like Cr2O3 for toluene combustion［J］.Catalysis Communications，2013，36：43-47. |
| 23 | 滕飞，宁桂玲，魏国，等.微乳纳米反应器制备单分散性球形氧化铬超细粉的研究［J］.中国粉体技术，2000，6（S1）：267-269. |
| TENG Fei， NING Guiling， WEI Guo，et al.Preparation of mono-dispersed spherical superfine Cr2O3 powder in microemulson system［J］.China Powder Science and Technology，2000，6（S1）：267-269. | |
| 24 | 王孝华.纳米氧化铬制备方法研究进展［J］.无机盐工业，2009，41（12）：5-7，35. |
| WANG Xiaohua.Research progress on preparation of nano-sized chromic oxide［J］.Inorganic Chemicals Industry，2009，41（12）：5-7，35. | |
| 25 | ALMONTASSER A， PARVEEN A.Preparation and characterization of chromium oxide nanoparticles［C］//AIP Conference Proceedings.3RD International Conference on Condensed Matter and Applied Physics（ICC-2019）.Bikaner，India：AIP Publishing，2020. |
| 26 | ALMONTASSER A， PARVEEN A， HASHIM M，et al.Structural，optical，and antibacterial properties of pure and doped（Ni，Co，and Fe） Cr2O3 nanoparticles：A comparative study［J］.Applied Nanoscience，2021，11（2）：583-604. |
| 27 | PEI Zhenzhao， XU Hongbin， ZHANG Yi.Preparation of Cr2O3 nanoparticles via C2H5OH hydrothermal reduction［J］.Journal of Alloys and Compounds，2009，468（1/2）：L5-L8. |
| 28 | SHAFI I， LIU Yuanyue， ZENG Gaojie，et al.Cr2O3/rGO nanocomposite with excellent electrochemical capacitive properties［J］.SN Applied Sciences，2020，2（11）：1836. |
| 29 | ANANDAN K， RAJENDRAN V.Studies on structural，morphological，magnetic and optical properties of chromium sesquioxi-de（Cr2O3） nanoparticles：Synthesized via facile solvothermal process by different solvents［J］.Materials Science in Semiconductor Processing，2014，19：136-144. |
| 30 | 李波，张波，梁建，等.一种纳米三氧化二铬及其制备方法：中国，114715939A［P］.2022-07-08. |
| 31 | LI L， ZHU Z H， WANG S B，et al.Chromium oxide catalysts for CO x -free hydrogen generation via catalytic ammonia decomposition［J］.Journal of Molecular Catalysis A：Chemical，2009，304（1/2）：71-76. |
| 32 | KIM J H， KARNG S W， OH I H，et al.Ortho-para hydrogen conversion characteristics of amorphous and mesoporous Cr2O3 powders at a temperature of 77 K［J］.International Journal of Hydrogen Energy，2015，40（41）：14147-14153. |
| 33 | 奚亚男，胡淑锦.一种纳米氧化铬的生物模板制备方法及其在气敏传感中的应用：中国，112429775A［P］.2021-03-02. |
| 34 | 刘玉欣，石凤娟，吕耀辉，等.纳米或多孔氧化铬粒子制备的研究进展［J］.无机盐工业，2019，51（10）：1-6. |
| LIU Yuxin， SHI Fengjuan， Yaohui Lü，et al.Progress in preparation of nano-sized or porous chromium oxide particles［J］.Inorganic Chemicals Industry，2019，51（10）：1-6. | |
| 35 | GHOLAMI S， ALAVI S M， REZAEI M.Synthesis of Cr2O3-Al2O3 powders with various Cr2O3/Al2O3 molar ratios and their applications as support for the preparation of nickel catalysts in CO2 methanation reaction［J］.International Journal of Hydrogen Energy，2021，46（7）：5311-5322. |
| 36 | 宁延生.无机盐工艺学［M］.北京：化学工业出版社，2013：758-761. |
| 37 | 梁建，田森，冯海涛，等.一种球状纳米三氧化二铬的制备方法：中国，110697776B［P］.2022-03-15. |
| 38 | 徐国钻，刘如铁，羊求民，等.制备高纯度纳米氧化铬的方法及高纯度纳米氧化铬：中国，111908506A［P］.2020-11-10. |
| 39 | TSUZUKI T， MCCORMICK P G.Synthesis of Cr2O3 nanoparticles by mechanochemical processing［J］.Acta Materialia，2000， 48（11）：2795-2801. |
| 40 | SABYASACHI S， MAJUMDAR S， GIRI S.Nanocrystallite interface effect and exchange bias phenomenology in Cr2O3 and NiO nanoparticles［J］.Solid State Communications，2011，151（21）：1515-1519. |
| 41 | KAFI-AHMADI L， KHADEMINIA S， POURSATTAR MARJANI A，et al.Microwave-assisted preparation of polysubstituted imidazoles using zingiber extract synthesized green Cr2O3 nanoparticl- es［J］.Scientific Reports，2022，12：19942. |
| 42 | CHEN Xi， CHEN Xi， CAI Songcai，et al.Catalytic combustion of toluene over mesoporous Cr2O3-supported platinum catalysts prepared by in situ pyrolysis of MOFs［J］.Chemical Engineering Journal，2018，334：768-779. |
| 43 | WU Zhixing， DENG Jiguang， XIE Shaohua，et al.Mesoporous Cr2O3-supported Au-Pd nanoparticles：High-performance catalysts for the oxidation of toluene［J］.Microporous and Mesoporous Materials，2016，224：311-322. |
| 44 | LIN Jianliang， SPROUL W D.Structure and properties of Cr2O3 coatings deposited using DCMS，PDCMS，and DOMS［J］.Surface and Coatings Technology，2015，276：70-76. |
| 45 | MAO Lin， XIAO Jinkun， SUN Guodong，et al.Microstructure and wear behaviors of Cr2O3-Al2O3 composite coatings deposited by atmospheric plasma spraying［J］.Surface and Coatings Technology，2022，444：128619. |
| 46 | BABU P S，SEN D， JYOTHIRMAYI A，et al.Influence of microstructure on the wear and corrosion behavior of detonation spray-ed Cr2O3-Al2O3 and plasma sprayed Cr2O3 coatings［J］.Ceramics International，2018，44（2）：2351-2357. |
| 47 | ZHANG Hongling， LIANG Shuting， LUO Minting，et al.Preparation and color performance control of Cr2O3 green pigment through thermal decomposition of chromium hydroxide precurs- or［J］.Materials Letters，2014，117：244-247. |
| 48 | XIE Dongjin， LUO Qiuyi， ZHOU Shen，et al.One-step preparation of Cr2O3-based inks with long-term dispersion stability for inkjet applications［J］.Nanoscale Advances，2021，3（21）：6048-6055. |
| 49 | AI Shuhe， ZHENG Huade， YU Jincheng.Preparation and reflectance spectrum modulation of Cr2O3 green pigment by solution combustion synthesis［J］.Materials，2020，13（7）：1540. |
| 50 | LIANG Shuting， ZHANG Hongling， LUO Minting，et al.Preparation of Cr2O3-based pigments with high NIR reflectance via thermal decomposition of CrOOH［J］.Transactions of Nonferrous Metals Society of China，2015，25（8）：2646-2647. |
| 51 | WANG Wei， LI Zhenyu， ZHENG Wei，et al.Cr2O3-sensitized ZnO electrospun nanofibers based ethanol detectors［J］.Sensors and Actuators B：Chemical，2010，143（2）：754-758. |
| 52 | 姜玮，崔彦发，曾庆毫，等.氧化铟/氧化铬异质材料的制备及其高气敏响应性能研究［J］.无机盐工业，2019，51（1）：73-77. |
| JIANG Wei， CUI Yanfa， ZENG Qinghao，et al.Preparation and high gas sensing performance of In2O3/Cr2O3 heterostructure material［J］.Inorganic Chemicals Industry，2019，51（1）：73-77. | |
| 53 | WU Xinyu， WANG Hairong， WANG Jiuhong，et al.VOCs gas sensor based on MOFs derived porous Au@Cr2O3-In2O3 nanorods for breath analysis［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2022，632：127752. |
| 54 | CAI Zhicheng， PARK S.Enhancement mechanisms of ethanol-sensing properties based on Cr2O3 nanoparticle-anchored SnO2 nanowires［J］.Journal of Materials Research and Technology，2020，9（1）：271-281. |
| 55 | ZHANG Deyin， QIN Mingli， HUANG Min，et al.Facile synthesis of amorphous Cr2O3/N-doped carbon nanosheets and its excellent lithium storage property［J］.Journal of the American Ceramic Society，2018，101（7）：3234-3243. |
| 56 | KHAMLICH S， NURU Z Y， BELLO A，et al.Pulsed laser deposited Cr2O3 nanostructured thin film on graphene as anode material for lithium-ion batteries［J］.Journal of Alloys and Compoun- ds，2015，637：219-225. |
| 57 | WANG Buxue， WANG Ziqi， CUI Yuanjing，et al.Cr2O3@TiO2 yolk/shell octahedrons derived from a metal-organic framework for high-performance lithium-ion batteries［J］.Microporous and Mesoporous Materials，2015，203：86-90. |
| 58 | LUO Mei， ORTIZ A L， SHAW L L.Enhancing the electrochemical performance of NaCrO2 through structural defect control［J］.ACS Applied Energy Materials，2020，3（7）：7216-7227. |
| 59 | XI Kaiying， CHU Shufen， ZHANG Xiaoyu，et al.A high-performance layered Cr-Based cathode for sodium-ion batteries［J］.Nano Energy，2020，67：104215. |
| 60 | KO W， CHO M K， KANG J，et al.Exceptionally increased reversible capacity of O3-type NaCrO2 cathode by preventing irreversible phase transition［J］.Energy Storage Materials，2022，46：289-299. |
| 61 | DONG Jia， JIA Jinbiao， SHI Beibei，et al.Cr2O3 interlayer at TiO2/perovskite interface propelling the efficiency improvement of perovskite solar cells［J］.Surfaces and Interfaces，2022，29：101761. |
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