Inorganic Chemicals Industry >

2023 , Vol. 55 >Issue 9: 57 - 65

DOI: https://doi.org/10.19964/j.issn.1006-4990.2022-0652

Research & Development

Experimental study on carbon dioxide sequestration by wet carbonation of calcium silicate minerals

  • CHANG Chengbing ,
  • LIU Shengyu ,
  • ZHANG Lei ,
  • YANG Zhichao ,
  • GUO Jianying ,
  • LI Bao
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  • 1.College of Mining Engineering，Taiyuan University of Technology，Taiyuan 030024，China
    2.Shanxi -Zheda Institute of Advanced Materials and Chemical Engineering，Taiyuan 030032，China
    3.Key Laboratory of In situ Property-improving Mining of Ministry of Education，Taiyuan University of Technology，Taiyuan 030024 China

Received date: 2022-11-03

  Online published: 2023-09-19

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Abstract

Wet carbonation of calcium silicate minerals for CO2 sequestration is a promising carbonsequestration technology.To compare the carbon sequestration effects of different calcium silicate minerals，the effects of temperature，pressure，liquid-solid ratio（mL/g），particle size and mineral additives（NaHCO3 and NaCl） on CO2 sequestration by wet carbonation of wollastonite and anorthite were investigated.The results showed that the carbonation products of wollastonite and anorthite were calcite and aragonite，respectively，and the results of the thermogravimetric experiment indicated that the thermostability of calcite was higher than that of aragonite.The carbonation conversion of wollastonite was higher than that of anorthite under all test conditions，and the carbonation conversion of the two minerals was increased with increasing pressure，decreasing particle size，and the addition of NaHCO3 and NaCl.The maximum carbonation conversions of 83.62% and 16.20% were obtained for wollastonite and anorthite，respectively，with significant differences.The results of Gibbs free energy of dissolution（ΔGr ） showed that，in the range of 120~210 ℃，the ΔGr of wollastonite was always lower than that of anorthite，indicating that the rate of dissolution and the spontaneously occurring extent of dissolution reaction of wollastonite were both greater than that of anorthite.It was a key factor affecting the activity of the carbonation reaction for calcium silicate minerals.

Key words： wollastonite; anorthite; wet carbonation; sequestered CO2; carbon sequestration technology

Cite this article

CHANG Chengbing , LIU Shengyu , ZHANG Lei , YANG Zhichao , GUO Jianying , LI Bao . Experimental study on carbon dioxide sequestration by wet carbonation of calcium silicate minerals[J]. Inorganic Chemicals Industry, 2023 , 55(9) : 57 -65 . DOI: 10.19964/j.issn.1006-4990.2022-0652

References

1 郭伟，石涵，袁标.无机固体吸附剂在二氧化碳捕集应用中的研究进展［J］.无机盐工业，2021，53（12）：29-34，42.
  GUO Wei， SHI Han， YUAN Biao.Research progress of inorganic solid adsorbents in carbon dioxide capture［J］.Inorganic Chemicals Industry，2021，53（12）：29-34，42.
2 Yang OU， RONEY C， ALSALAM J，et al.Deep mitigation of CO2 and non-CO2 greenhouse gases toward 1.5 ℃ and 2 ℃ futures［J］.Nature Communications，2021，12（1）：1-9.
3 JEFFRY L， ONG M Y， NOMANBHAY S，et al.Greenhouse gases utilization：A review［J］.Fuel，2021，301：121017.
4 AJAYI T， GOMES J S， BERA A.A review of CO2 storage in geological formations emphasizing modeling，monitoring and capacity estimation approaches［J］.Petroleum Science，2019，16（5）：1028-1063.
5 何民宇，刘维燥，刘清才，等.CO2矿物封存技术研究进展［J］.化工进展，2022，41（4）：1825-1833.
  HE Minyu， LIU Weizao， LIU Qingcai，et al.Research progress in CO2 mineral sequestration technology［J］.Chemical Industry and Engineering Progress，2022，41（4）：1825-1833.
6 蒋剑.钙镁盐直接碳酸化固定CO2实验研究［D］.南京：南京师范大学，2018.
  JIANG Jian.Experimental study on CO2 immobilization by direct carbonation of calcium magnesium salt［D］.Nanjing：Nanjing Normal University，2018.
7 FAGERLUND J， HIGHFIELD J， ZEVENHOVEN R.Kinetics studies on wet and dry gas-solid carbonation of MgO and Mg（OH）2 for CO2 sequestration［J］.RSC Advances，2012，2（27）：10380-10393.
8 WANG Bo， PAN Zihe， CHENG Huaigang，et al.A review of carbon dioxide sequestration by mineral carbonation of industrial byproduct gypsum［J］.Journal of Cleaner Production，2021，302：126930.
9 RAHMANI O， JUNIN R， TYRER M，et al.Mineral carbonation of red gypsum for CO2 sequestration［J］.Energy & Fuels，2014，28（9）：5953-5958.
10 李兰兰，叶坤，郭会荣，等.矿物封存二氧化碳实验研究进展［J］.资源与产业，2013，15（2）：117-123.
  LI Lanlan， YE Kun， GUO Huirong，et al.Test advance in minerals-sealing carbon dioxide［J］.Resources & Industries，2013，15（2）：117-123.
11 REYNES J F， MERCIER G， BLAIS J F，et al.Feasibility of a mineral carbonation technique using iron-silicate mining waste by direct flue gas CO2 capture and cation complexation using 2，2′-bipyridine［J］.Minerals，2021，11（4）：343.
12 张兵兵，王慧敏，曾尚红，等.二氧化碳矿物封存技术现状及展望［J］.化工进展，2012，31（9）：2075-2083.
  ZHANG Bingbing， WANG Huimin， ZENG Shanghong，et al.Current status and outlook of carbon dioxide mineral carbonation technologies［J］.Chemical Industry and Engineering Progress，2012，31（9）：2075-2083.
13 晏恒.中低压条件下非纯CO2液相直接矿物碳酸化的实验研究［D］.武汉：华中科技大学，2015.
  YAN Heng.Experimental study of CO2 sequestration from flue gas by direct on direct aqueous mineral carbonation under low-medium pressure conditions.［D］.Wuhan：Huazhong University of Science and Technology，2015.
14 刘瑞，王志华，徐强，等.钙长石矿物的化学活性及其固碳潜力研究初探［J］.长春工程学院学报（自然科学版），2013，14（4）：64-66，91.
  LIU Rui， WANG Zhihua， XU Qiang，et al.Preliminary studies on anorthite chemical activity and carbon fixation ability［J］.Journal of Changchun Institute of Technology（Natural Sciences Edition），2013，14（4）：64-66，91.
15 OELKERS E H， GISLASON S R， MATTER J.Mineral carbonation of CO2 ［J］.Elements，2008，4（5）：333-337.
16 EIKELAND E， BLICHFELD A B， TYRSTED C，et al.Optimized carbonation of magnesium silicate mineral for CO2 storage［J］.ACS Applied Materials & Interfaces，2015，7（9）：5258-5264.
17 张彬，肖霄，韩芸娇，等.碳酸钙三级红外光谱研究［J］.无机盐工业，2021，53（1）：97-101.
  ZHANG Bin， XIAO Xiao， HAN Yunjiao，et al.Study on third-step infrared spectroscopy of calcium carbonate［J］.Inorganic Chemicals Industry，2021，53（1）：97-101.
18 KARUNADASA K S P， MANORATNE C H， PITAWALA H M T G A，et al.Thermal decomposition of calcium carbonate（calcite polymorph） as examined by in situ high-temperature X-ray powder diffraction［J］.Journal of Physics and Chemistry of Solids，2019，134：21-28.
19 HAN Zuozhen， MENG Ruirui， YAN Huaxiao，et al.Calcium carbonate precipitation by synechocystis sp.PCC6803 at different Mg/Ca molar ratios under the laboratory condition［J］.Carbonates and Evaporites，2017，32（4）：561-575.
20 纪龙.利用粉煤灰矿化封存二氧化碳的研究［D］.北京：中国矿业大学（北京），2018.
  JI Long.Carbon dioxide sequestration by mineralization of coal fly ash［D］.Beijing：China University of Mining & Technology，Beijing，2018.
21 LI Jiajie， JACOBS A D， HITCH M.Direct aqueous carbonation on olivine at a CO2 partial pressure of 6.5 MPa［J］.Energy，2019，173：902-910.
22 SHENG Haoyi， Li Lü， LIANG Bin，et al.Aqueous carbonation of the potassium-depleted residue from potassium feldspar-CaCl2 calcination for CO2 fixation［J］.Environmental Earth Sciences，2015，73（11）：6871-6879.
23 YAN Heng， ZHANG Junying， ZHAO Yongchun，et al.CO2 sequestration by direct aqueous mineral carbonation under low-medium pressure conditions［J］.Journal of Chemical Engineering of Japan，2015，48（11）：937-946.
24 CHEN Zhongying， O'CONNOR W K， GERDEMANN S J.Chemistry of aqueous mineral carbonation for carbon sequestration and explanation of experimental results［J］.Environmental Progress，2006，25（2）：161-166.
25 SANNA A， STEEL L， MAROTO-VALER M M.Carbon dioxide sequestration using NaHSO4 and NaOH：A dissolution and carbonation optimisation study［J］.Journal of Environmental Management，2017，189：84-97.
26 RUAN Fang， KAWANISHI S， SUKENAGA S，et al.Effect of the silicate structure on calcium elution behaviors of calcium-silicate based mineral phases in aqueous solution［J］.ISIJ International，2020，60（3）：419-425.
27 王宗华，张军营，徐俊，等.CO2矿物碳酸化隔离的理论研究［J］.工程热物理学报，2008，29（6）：1063-1068.
  WANG Zonghua， ZHANG Junying， XU Jun，et al.A theoretical study on mineral carbonation for CO2 sequestration［J］.Journal of Engineering Thermophysics，2008，29（6）：1063-1068.
28 STEWART E M， AGUE J J， FERRY J M，et al.Carbonation and decarbonation reactions：Implications for planetary habitability［J］.American Mineralogist，2019，104（10）：1369-1380.
29 李亚楠，苏锐，周志超，等.北山新场BS34钻孔岩样在不同温度下的水岩作用［J］.核化学与放射化学，2022，44（3）：386-392.
  LI Yanan， SU Rui， ZHOU Zhichao，et al.Water-rock interaction of granite from borehole BS34 at different temperatures［J］.Journal of Nuclear and Radiochemistry，2022，44（3）：386-392.
30 SORAI M， SASAKI M.Dissolution kinetics of anorthite in a supercritical CO2-water system［J］.American Mineralogist，2010，95（5/6）：853-862.
31 姚曦智.超临界二氧化碳环境下钙镁矿物碳酸盐化实验研究［D］.南京：南京大学，2017.
  YAO Xizhi.Study of calcium and magnesium mineral carbonation under supercritical CO2 condition［D］.Nanjing：Nanjing University，2017.
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