Inorganic Chemicals Industry >
A gas chromatographic analysis method for acetic acid content in phosphoric acid and acetic acid mixed system
Received date: 2022-07-19
Online published: 2023-05-15
A method using gas chromatography with propionic acid as an internal standard was proposed to solve the problems of low accuracy and cumbersome operation in the analysis of acetic acid content in the phosphoric acid and acetic acid mixed system.The accuracy and applicability of this method were verified through recovery experiments，precision experiments，comparison tests with literature methods，and experiments on the interference of phosphoric acid concentration.The experimental results showed that the recoveries of blank standard of acetic acid was 97.67%~104.55%，and the recoveries of sample standard of acetic acid was 97.72%~104.35%，and the precision of multiple test results was 1.26%.Compared with the literature methods，this method had high accuracy.In addition，for phosphoric acid concentrations at the range of 0~70%，the analytical results of acetic acid were not affected by the phosphoric acid content.Therefore，this chromatographic analysis method could accurately，rapidly，and easily determine the content of acetic acid in the phosphoric acid and acetic acid mixed system.This method was of great importance for the analysis of acetic acid content in related industries.
LI Jiaqiang , LI Jun , JIN Yang , CHEN Ming . A gas chromatographic analysis method for acetic acid content in phosphoric acid and acetic acid mixed system[J]. Inorganic Chemicals Industry, 2023 , 55(5) : 115 -120 . DOI: 10.19964/j.issn.1006-4990.2022-0440
| 1 | SHIN C H， KIM J Y， KIM J Y，et al.A solvent extraction approach to recover acetic acid from mixed waste acids produced during semiconductor wafer process[J].Journal of Hazardous Materials，2009，162（2/3）：1278-1284. |
| 2 | 周兆梅.一种铝合金化学抛光液及其抛光方法：中国，110219004A[P].2019-09-10. |
| ZHOU Zhaomei.A chemical polishing liquid for aluminum alloy and its polishing method：CN110219004A[P].2019-09-10. | |
| 3 | 吴赵敏，杨林，王辛龙，等.动态离子交换法处理电子行业蚀刻含铝废酸工艺研究[J].无机盐工业，2021，53（2）：61-65，70. |
| WU Zhaomin， YANG Lin， WANG Xinlong，et al.Study on process of dynamic ion-exchange for etching waste acid containing aluminum in electronic industry[J].Inorganic Chemicals Industry，2021， 53（2）：61-65，70. | |
| 4 | JUYANA A.A study on nanostructured of anodised aluminium template synthesised by the mixture of phosphoric acid and acetic acid[J].Universiti Malaysia Perlis，2010. |
| 5 | 谢国庆，朱琦，翟金国，等.三种方法联合测试硝酸-氢氟酸-醋酸混酸组成[J].广州化学，2018，43（5）：52-55. |
| XIE Guoqing， ZHU Qi， ZHAI Jinguo，et al.Determination of nitric acid-hydrofluoric acid-acetic acid in mixed acid by spectrophotography-precipitation method-potentiometry[J].Guangzhou Chemistry，2018，43（5）：52-55. | |
| 6 | 陈旗.混酸（硝酸、磷酸、冰醋酸）的电位滴定分析[J].浙江化工，2008，39（1）：28-30，25. |
| CHEN Qi.Potentiometric titration analysis of electrolyte of mixed acid[J].Zhejiang Chemical Industry，2008，39（1）：28-30，25. | |
| 7 | 徐蕊，张维维，巫景铭，等.铝蚀刻液混酸浓度的电位滴定方法：中国，102778532A[P].2012-11-14. |
| XU Rui， ZHANG Weiwei， WU Jingming，et al.Potentiometric titration method of mixed acid concentration of aluminum etching solution：CN102778532A[P].2012-11-14. | |
| 8 | 张笑旻.离子色谱法测定混合酸中的组分及含量[C]//第十二届全国离子色谱学术报告会.福建厦门：中国仪器仪表学会分析仪器分会，2008：197-199. |
| ZHANG Xiaomin.Determination of components and contents in mixed acids by ion chromatography[C]//Proceedings of the 12th National Conference on Ion Chromatography.Xiamen：Analytical Instrument Branch of China Instrument and Control Society，2008：197-199. | |
| 9 | VANATTA L E， COLEMAN D E， WOODRUFF A.Determination of chloride and sulfate in semiconductor-grade etchants comprised of acetic acid，nitric acid and phosphoric acid[J].Journal of Chromatography A，2003，997（1/2）：269-278. |
| 10 | 马蕙，仪宏，王丽丽.气相色谱法测定发酵液中丙酸和乙酸的含量[J].饲料工业，2008，29（9）：48-50. |
| MA Hui， YI Hong， WANG Lili.Determination of propionic acid and acetic acid in fermentation broth by gas chromatography[J].Feed Industry，2008，29（9）：48-50. | |
| 11 | 张月萍，赵磊，赵平.填充柱气相色谱法快速测定发酵废水提取物中丙/乙酸含量[J].分析试验室，2009，28（10）：117- 119. |
| ZHANG Yueping， ZHAO Lei， ZHAO Ping.Fast detection of propionic acid and acetic acid in vitamin B12 fermentation wastewater extracts with gas chromatography[J].Chinese Journal of Analy-Laboratory sis，2009，28（10）：117-119. | |
| 12 | 赵平，赵磊，张月萍.填充柱气相色谱法快速测定发酵废水提取物中丙/乙酸[C]//第五届全国化学工程与生物化工年会.陕西西安：西北大学，2008：1292. |
| ZHAO Ping， ZHAO Lei， ZHANG Yueping.Rapid determination of propyl/acetic acid in fermentation wastewater extracts by pack-ed column gas chromatography[C]//The Fifth National Annual Conference on Chemical Engineering and Biochemistry.Xi'an：Northwest University，2008：1292. | |
| 13 | 蔡元明.毛细柱色谱技术中多种定量方法的比较[C]//第四届全国石油地质实验技术及实验室管理工作交流会.上海：中国石油天然气股份有限公司，2001：140-142. |
| CAI Yuanming.Comparison of various quantitative methods in capillary column chromatography[C]//The 4th National Petroleum Geological Experiment Technology and Laboratory Management Work Exchange Conference.Shanghai：China National Petroleum Corporation，2001：140-142. | |
| 14 | 李灵云，倪开岭，李敏，等.气相色谱法快速测定疏血通注射液中乙酸、丙酸、丁酸的含量[J].天津中医药，2020，37（1）：99-103. |
| LI Lingyun， NI Kailing， LI Min，et al.Rapid determination of acetic acid，propionic acid and butyric acid in Shuxuetong Injection by gas chromatography[J].Tianjin Journal of Traditional Chinese Medicine，2020，37（1）：99-103. | |
| 15 | 刘俊保，赵慧晖，黄世英，等.一种测定丙烯氧化反应液相 |
| 产物中乙酸含量的方法：中国，107345942B[P].2019-09- 03. | |
| LIU Junbao， ZHAO Huihui， HUANG Shiying，et al.A method for determining acetic acid content in liquid phase products of propylene oxidation reaction：CN107345942B[P].2019-09-03. | |
| 16 | 国家质量监督检验检疫总局，中国国家标准化管理委员会. 合格评定 化学分析方法确认和验证指南： [S].北京：中国标准出版社，2017. |
| 17 | WANG Ye， CHEN Fang， MA Xiaodong，et al.Recovery of nitric and acetic acids from etching waste solutions using a synergistic system consisting of N235 and TRPO in cyclohexane[J].Hydrometallurgy，2019，185：23-29. |
| 18 | 中国石油和化学工业协会. 磷矿石和磷精矿中五氧化二磷含量的测定 磷钼酸喹啉重量法和容量法： [S].北京：中国标准出版社，1996. |
/
| 〈 |
|
〉 |