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Study on lithium dendrite suppression in solid state batteries for new energy vehicles
Received date: 2022-03-15
Online published: 2022-12-19
Solid-state batteries possess higher energy density and better safety than commercial lithium-ion batteries.However，solid electrolytes are still suffered from lithium dendrite growth.The current large-scale industrialized polyvinyl oxide（PEO）-based electrolyte was used as the research object.By combining PEO with garnet type electrolyte with high Young′s modulus，the effective inhibition of Li dendrite growth in PEO based composite electrolyte was realized.The ionic conductivity of the electrolyte membrane was increased from 9.8×10-6 S/cm to 3.8×10-4 S/cm，and the critical current density of the Li/Li symmetric battery was increased from 0.4 mA/cm2 to 1.6 mA/cm2.Meanwhile，the assembled pouch cell based on Li metal anode and conventional graphite anode could obtain the energy density of 334.5 W·h/kg and 218.2 W·h/kg，respectively.Additionally，the capacity retention rate of Li cobalate/composite electrolyte/graphite pouch cell was 92.3% after 1 000 cycles，which met the demand of new energy vehicle.
Pan LI , Yiyi ZHU . Study on lithium dendrite suppression in solid state batteries for new energy vehicles[J]. Inorganic Chemicals Industry, 2022 , 54(12) : 44 -50 . DOI: 10.19964/j.issn.1006-4990.2022-0118
| 1 | XU Kang. Electrolytes and interphases in Li-ion batteries and beyond[J]. Chemical Reviews, 2014, 114(23)：11503-11618. |
| 2 | WINTER M, BARNETT B, XU Kang. Before Li ion batteries[J]. Chemical Reviews, 2018, 118(23)：11433-11456. |
| 3 | CHEN Kai, SHEN Yang, ZHANG Yibo, et al. High capacity and cyclic performance in a three-dimensional composite electrode filled with inorganic solid electrolyte[J]. Journal of Power Sources, 2014, 249: 306-310. |
| 4 | 白小洁, 曹德富, 王君慧, 等. 半固态储能电池的研究进展[J]. 无机盐工业, 2022, 54(2)：6-15. |
| 4 | BAI Xiaojie, CAO Defu, WANG Junhui, et al. Research progress on semi-solid energy storage batteries[J]. Inorganic Chemicals Industry, 2022, 54(2)：6-15. |
| 5 | CHEN Rusong, LI Qinghao, YU Xiqian, et al. Approaching practically accessible solid-state batteries：Stability issues related to solid electrolytes and interfaces[J]. Chemical Reviews, 2020, 120(14)：6820-6877. |
| 6 | HAN Fudong, WESTOVER A S, YUE Jie, et al. High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes[J]. Nature Energy, 2019, 4(3)：187-196. |
| 7 | LI Xiaona, LIANG Jianwen, LUO Jing, et al. Air-stable Li3InCl6 electrolyte with high voltage compatibility for all-solid-state batteries[J]. Energy & Environmental Science, 2019, 12(9)：2665-2671. |
| 8 | SHI Kai, WAN Zipei, YANG Lu, et al. In situ construction of an ultra-stable conductive composite interface for high-voltage all-solid-state lithium metal batteries[J]. Angewandte Chemie：International Ed.in English, 2020, 59(29)：11784-11788. |
| 9 | IIO K, HAYASHI A, MORIMOTO H, et al. Mechanochemical synthesis of high lithium ion conducting materials in the system Li3N-SiS2 [J]. Chemistry of Materials, 2002, 14: 2444-2449. |
| 10 | JENA A, MEESALA Y, HU Shufen, et al. Ameliorating interfacial ionic transportation in all-solid-state Li-ion batteries with interlayer modifications[J]. ACS Energy Letters, 2018, 3(11)：2775-2795. |
| 11 | HAN Fudong, ZHU Yizhou, HE Xingfeng, et al. Electrochemical stability of Li10GeP2S12 and Li7La3Zr2O12 solid electrolytes[J]. Advanced Energy Materials, 2016, 6(8).Doi：10.1002/aenm.201501590 . |
| 12 | XU Biyi, LI Wenlong, DUAN Huanan, et al. Li3PO4-added garnet-type Li6.5La3Zr1.5Ta0.5O12 for Li-dendrite suppression[J]. Journal of Power Sources, 2017, 354: 68-73. |
| 13 | KOSHIKAWA H, MATSUDA S, KAMIYA K, et al. Dynamic changes in charge-transfer resistance at Li metal/Li7La3Zr2O12 interfaces during electrochemical Li dissolution/deposition cycl-es[J]. Journal of Power Sources, 2018, 376: 147-151. |
| 14 | ZHANG Zhizhen, SHAO Yuanjun, LOTSCH B, et al. New horizons for inorganic solid state ion conductors[J]. Energy & Environmental Science, 2018, 11(8)：1945-1976. |
| 15 | BACHMAN J C, MUY S, GRIMAUD A, et al. Inorganic solid-state electrolytes for lithium batteries：Mechanisms and properties governing ion conduction[J]. Chemical Reviews, 2016, 116(1)：140-162. |
| 16 | LUO Wei, GONG Yunhui, ZHU Yizhou, et al. Reducing interfacial resistance between garnet-structured solid-state electrolyte and Li-metal anode by a germanium layer[J]. Advanced Materials, 2017, 29(22).Doi：10.1002/adma.201606042 . |
| 17 | HUANG W L, ZHAO N, BI Z J, et al. Can we find solution to eliminate Li penetration through solid garnet electrolytes？[J]. Materials Today Nano, 2020, 10.Doi：10.1016/j.mtnano.2020.100075 . |
| 18 | HUO Hanyu, LI Xiaona, SUN Yipeng, et al. Li2CO3 effects：New insights into polymer/garnet electrolytes for dendrite-free solid lithium batteries[J]. Nano Energy, 2020, 73.Doi：10.1016/j.nanoen.2020.104836 . |
| 19 | SCHWIETERT T K, ARSZELEWSKA V A, WANG Chao, et al. Clarifying the relationship between redox activity and electrochemical stability in solid electrolytes[J]. Nature Materials, 2020, 19(4)：428-435. |
| 20 | HITZ E M, XIE Hua, LIN Yi, et al. Ion-conducting，electron-bloc-king layer for high-performance solid electrolytes[J]. Small Structures, 2021, 2(8).Doi：10.1002/sstr.202100014 . |
| 21 | TSAI C L, RODDATIS V, CHANDRAN C V, et al. Li7La3Zr2O12 interface modification for Li dendrite prevention[J]. ACS Applied Materials & Interfaces, 2016, 8(16)：10617-10626. |
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