Inorganic Chemicals Industry >
Research progress of application of silica sol in synthesis of molecular sieve catalyst
Received date: 2022-07-13
Online published: 2022-12-19
Silica sol has been invented for more than 100 years，which was widely used in synthesis of molecular sieve and preparation of catalysts.The market，preparation methods and properties of silica sol were briefly reviewed.The application of silica sol in preparation of molecular sieve catalysts was mainly introduced，including the application of silica sol in silicon source，binder and preparation of small crystalline molecular sieve.Based on the research progress at home and abroad，the role and advantages of catalyst using silica sol as silicon source，binder and carrier in the synthesis of molecular sieve and preparation of catalyst were discussed in detail.According with the application status of silica sol，some problems in the preparation of molecular sieve catalysts were proposed：poor wear resistance of silica based catalyst prepared with silica sol as binder；poor dispersion of active components of catalyst prepared with silica sol as carrier；poor quality stability of silica sol products.It was pointed out that how to solve the above problems and improve the application of silica sol in the preparation of molecular sieve catalyst more effectively would be the focus of the future research.Finally，the development prospect of silica sol was discussed，and it was pointed out that on the basis of controllable synthesis of silica sol，the controllable synthesis and application development of molecular sieve and its catalyst would have a broader prospect.
Key words： silica sol; molecular sieve catalyst; silicon source; binder
Qinghong MAN , He HUANG , Yuqi ZHAO , Xiangming WANG . Research progress of application of silica sol in synthesis of molecular sieve catalyst[J]. Inorganic Chemicals Industry, 2022 , 54(12) : 28 -33 . DOI: 10.19964/j.issn.1006-4990.2022-0422
| 1 | 赵旭, 史凯, 任轶轩, 等. 铝改性硅溶胶合成ZSM-5分子筛方法的研究[J]. 现代化工, 2022, 42(6)：149-152. |
| 1 | ZHAO Xu, SHI Kai, REN Yixuan, et al. Research on synthesis method of ZSM-5 molecular sieve from aluminum modified silica sol[J]. Modern Chemical Industry, 2022, 42(6)：149-152. |
| 2 | 赵蕾. 电子级硅溶胶的制备工艺研究[D].武汉：武汉工程大学, 2017. |
| 2 | ZHAO Lei. Study on preparation technology of electronic grade silicasol[D].Wuhan：Wuhan Institute of Technology, 2017. |
| 3 | 解志益, 周涵, 李庆超, 等. 纳米硅溶胶的制备及在水泥基材料中的应用研究进展[J]. 材料导报, 2020, 34(S2)：1160- 1163. |
| 3 | XIE Zhiyi, ZHOU Han, LI Qingchao, et al. Preparation，application of colloidal nano-silica and its research progress in cement-based materials[J]. Materials Reports, 2020, 34(S2)：1160-1163. |
| 4 | 田振琨. PMS改性硅溶胶的制备及其在涂料中的应用研究[D].南宁：广西大学, 2020. |
| 4 | TIAN Zhenkun. Study on preparation of PMS modified silica sol and its application in coatings[D].Nanning：Guangxi University, 2020. |
| 5 | 桑宇, 邢爱华. 硅源对纳米级ZSM-5分子筛结构及其对甲醇转化制丙烯与丁烯反应催化性能的影响[J]. 工业催化, 2016, 24(11)：41-51. |
| 5 | SANG Yu, XING Aihua. Effects of silicon sources on structure and catalytic performance of nano-ZSM-5 zeolite for methanol to propylene and butylene[J]. Industrial Catalysis, 2016, 24(11)：41- 51. |
| 6 | 李鹏, 李峰, 刘宇键, 等. 含磷模板剂和不同硅源对多级孔ZSM-5分子筛结构和催化性能的影响[J]. 石油炼制与化工, 2018, 49(8)：21-27. |
| 6 | LI Peng, LI Feng, LIU Yujian, et al. Effects of phosphorus template and silicon sources on structure and catalytic performance of hierarchical ZSM-5 zeolite[J]. Petroleum Processing and Petrochemicals, 2018, 49(8)：21-27. |
| 7 | 张亚春. 绿色、低成本合成ZSM-5沸石分子筛的研究[D].太原：山西大学, 2019. |
| 7 | ZHANG Yachun. Study on synthesis of ZSM-5 zeolite with low-cost by green mehods[D].Taiyuan：Shanxi University, 2019. |
| 8 | AGLIULLIN M R, KOLYAGIN Y G, SEREBRENNIKOV D V, et al. Acid properties and morphology of SAPO-11 molecular sieve controled by silica source[J]. Microporous and Mesoporous Materials, 2022, 338.Doi：10.1016/j.micromeso.2022.111962 . |
| 9 | 孙莉. ZSM-34分子筛的快速合成、表征及后处理研究[D].东营：中国石油大学（华东）, 2016. |
| 9 | SUN Li. Synthesis，characterization and post treatment of ZSM-34 zeolite with short synthesis period[D].Dongying：China University of Petroleum（Huadong）, 2016. |
| 10 | MOHAMED R M, ALY H M, EL-SHAHAT M F, et al. Effect of the silica sources on the crystallinity of nanosized ZSM-5 zeolite[J]. Microporous and Mesoporous Materials, 2005, 79(1/2/3)：7-12. |
| 11 | 姚芃旭. TS-1合成中Na+对催化性能的影响及失活催化剂再生的研究[D].天津：天津大学, 2014. |
| 11 | YAO Pengxu. Effect of Na+ in synthesis of titanium silicalite-1on its catalytic performance in cyclohexanone ammoximation and regeneration of deactivated catalyst[D].Tianjin：Tianjin University, 2014. |
| 12 | 王艳梅. 用廉价原料合成钛硅分子筛TS-1的研究[D].大连：大连理工大学, 2010. |
| 12 | WANG Yanmei. Synthesis of titanium silicalite-1 with cheap materials[D].Dalian：Dalian University of Technology, 2010. |
| 13 | 杨丽静, 田辉平, 龙军, 等. 硅溶胶胶凝过程的分形特征[J]. 石油学报：石油加工, 2010, 26(6)：841-845. |
| 13 | YANG Lijing, TIAN Huiping, LONG Jun, et al. Fractal of silica Sol during Sol-Gel process[J]. Acta Petrolei Sinica：Petroleum Processing Section, 2010, 26(6)：841-845. |
| 14 | ZHOU Jian, TENG Jiawei, REN Liping, et al. Full-crystalline hierarchical monolithic ZSM-5 zeolites as superiorly active and long-lived practical catalysts in methanol-to-hydrocarbons reaction[J]. Journal of Catalysis, 2016, 340: 166-176. |
| 15 | 刘丽杰, 胡云峰, 舒静. 高硅铝比小晶粒分子筛的合成及应用进展[J]. 工业催化, 2014, 22(6)：405-411. |
| 15 | LIU Lijie, HU Yunfeng, SHU Jing. Progress in synthesis and application of nanosized zeolites with high silica-alumina ratio[J]. Industrial Catalysis, 2014, 22(6)：405-411. |
| 16 | 张伟, 任立军, 王亮. 硅溶胶合成小晶粒ZSM-5分子筛的研究[J]. 石油化工应用, 2013, 32(10)：88-92. |
| 16 | ZHANG Wei, REN Lijun, WANG Liang. Study on the synthesis of small grain ZSM-5 molecular sieve with silica sol[J]. Petrochemical Industry Application, 2013, 32(10)：88-92. |
| 17 | 韩京京. ZSM-22的形貌尺寸控制合成及其制生物航煤性能[D].大连：大连理工大学, 2021. |
| 17 | HAN Jingjing. Controllable synthesis of ZSM-22 with different sizes and morphologies and their performance on production of bio-jet fuel[D].Dalian：Dalian University of Technology, 2021. |
| 18 | 董衡. 粒径可控的小晶粒NaY分子筛的合成、表征及其催化性能研究[D].北京：北京工业大学, 2016. |
| 18 | DONG Heng. Synthesis，characterization and catalytic performance of the NaY molecular sieves with the controllable small particle size[D].Beijing：Beijing University of Technology, 2016. |
| 19 | 李阳. 硅溶胶在催化裂化催化剂中的应用研究[D].大连：大连理工大学, 2019. |
| 19 | LI Yang. Application study of silica Sol in catalytic cracking catalyst[D].Dalian：Dalian University of Technology, 2019. |
| 20 | 武鹏, 张魁, 王鹏, 等. 硅溶胶粒径对沉淀铁催化剂费托合成性能的影响[J]. 石油化工, 2016, 45(4)：398-401. |
| 20 | WU Peng, ZHANG Kui, WANG Peng, et al. Effects of particle size of silica Sol on properties of precipitated iron catalysts for Fischer-Tropsch synthesis[J]. Petrochemical Technology, 2016, 45(4)：398-401. |
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