Inorganic Chemicals Industry >
Research progress on preparation technology of two?dimensional perovskite materials
Received date: 2021-11-16
Online published: 2022-09-22
Perovskite is widely used in the field of optoelectronic devices such as solar cells and photodetectors because of its excellent physical and chemical properties，such as tunable structure，low defect density，high carrier mobility and adjustable band gap.Because the dimension and thickness of two?dimensional perovskite materials are reduced，the quantum confinement effect is caused，which enhances the electron hole interaction and increases the exciton binding energy.Therefore，compared with bulk materials，two?dimensional perovskite materials show better photoelectric properties and enhanced stability，and quickly become a research hotspot in the field of two?dimensional materials.Combined with the research status at home and abroad in recent years，the preparation methods of two?dimensional perovskite materials such as stripping method，liquid phase method and gas phase method were reviewed，the advantages and disadvantages of each method were analyzed，and their future development was prospected.It was pointed out that the research of two?dimensional perovskite materials was needed to focus on the following two aspects:1）developing a simple and feasible preparation method for large?scale production of two?dimensional perovskite materials with large size，high quality，environmental friendliness and high stability was still the focus of research in this field.Among the three preparation methods，gas phase method was very likely to achieve large?scale production of two?dimensional perovskite materials with high quality，However，the urgent problems to be solved were to reduce the equipment cost and improve the process conditions to improve the growth rate of two?dimensional perovskite materials；2）Two dimensional perovskite materials had shown good application prospects in the fields of solar cells，photodetectors，LEDs and other optoelectronic devices，but the basic research on the working principle of optoelectronic devices and how to accurately control the morphology and luminous properties of materials were still needed to be further discussed，which was also the focus of attention in the future.
Key words： perovskite; two?dimensional materials; solar cells; optoelectronic devices
Miao DU , Xiao ZHENG , Mingyue HU , Yuan MA , Qingqing DU , Yuena DUAN . Research progress on preparation technology of two?dimensional perovskite materials[J]. Inorganic Chemicals Industry, 2022 , 54(9) : 14 -20 . DOI: 10.11962/1006-4990.2021-0692
| [1] | MA Shuang， CAI Molang， CHENG Tai， et al.Two?dimensional organic?inorganic hybrid perovskite:From material properties to device applications[J].Science China Materials，2018，61（10）:1257-1277. |
| [2] | WANG Jun， LI Junze， TAN Qinghai， et al.Controllable synthesis of two?dimensional ruddlesden?popper?type perovskite heterostructures[J].The Journal of Physical Chemistry Letters，2017，8（24）:6211-6219. |
| [3] | LING Xufeng， ZHU Hongwei， XU Weidong， et al.Combined precursor engineering and grain anchoring leading to MA-free，phase?pure，and stable α-formamidinium lead iodide perovskites for efficient solar cells[J].Angewandte Chemie，2021，133（52）:27505-27512. |
| [4] | ZHANG Xuliang， HUANG Hehe， LING Xufeng， et al.Homojunction perovskite quantum dot solar cells with over 1 μm-thick photoactive layer[J].Advanced Materials，2022，34（2）.Doi:10.1002/adma.202105977. |
| [5] | 杜淼，张光荣.石墨烯的制备及其应用研究进展[J].无机盐工业，2019，51（3）:12-15. |
| [5] | DU Miao， ZHANG Guangrong.Progress in preparation and application of graphene[J].Inorganic Chemicals Industry，2019，51（3）:12-15. |
| [6] | DU Juan， SHI Junjie.2D Ca3Sn2S7 chalcogenide perovskite:A graphene?like semiconductor with direct bandgap 0.5 eV and ultrahigh carrier mobility 6.7×104 cm2·V-1·s-1 [J].Advanced Materials，2019，31（51）.Doi:10.1002/adma.201905643. |
| [7] | GRAPE E S， FLORES J G， HIDALGO T， et al.A robust and biocompatible bismuth ellagate MOF synthesized under green ambient conditions[J].Journal of the American Chemical Society，2020，142（39）:16795-16804. |
| [8] | JI Dianxiang， CAI Songhua， PAUDEL T R， et al.Freestanding crystalline oxide perovskites down to the monolayer limit[J].Nature，2019，570（7759）:87-90. |
| [9] | QUAN Lina， YUAN Mingjian， COMIN R， et al.Ligand?stabilized reduced?dimensionality perovskites[J].Journal of the American Chemical Society，2016，138（8）:2649-2655. |
| [10] | TSAI H， NIE Wanyi， BLANCON J C， et al.High?efficiency two?dimensional Ruddlesden-Popper perovskite solar cells[J].Nature，2016，536（7616）:312-316. |
| [11] | ZHOU Jiachen， CHU Yingli， HUANG Jia.Photodetectors based on two?dimensional layer?structured hybrid lead iodide perovskite |
| [11] | semiconductors[J].ACS Applied Materials & Interfaces，2016，8（39）:25660-25666. |
| [12] | LU Yingbo， GUAN Chengbo， SUN Hui， et al.Investigation on enhanced moisture resistance of two?dimensional layered hybrid organic?inorganic perovskites（C4H9NH3）2PbI4 [J].The Journal of Physical Chemistry C，2018，122（22）:11862-11869. |
| [13] | LEKINA Y， SHEN Zexiang.Excitonic states and structural stability in two?dimensional hybrid organic?inorganic perovskites[J].Journal of Science:Advanced Materials and Devices，2019，4（2）:189-200. |
| [14] | WANG Xi， LING Yichuan， CHIU Y C， et al.Dynamic electronic junctions in organic?inorganic hybrid perovskites[J].Nano Letters，2017，17（8）:4831-4839. |
| [15] | HA S T， LIU Xinfeng， ZHANG Qing， et al.Synthesis of organic?inorganic lead halide perovskite nanoplatelets:Towards high?performance perovskite solar cells and optoelectronic devices[J].Advanced Optical Materials，2014，2（9）:838-844. |
| [16] | SPINA M， LEHMANN M， NáFRáDI B， et al.Microengineered CH3NH3PbI3 nanowire/graphene phototransistor for low?intensity light detection at room temperature[J].Small，2015，11（37）:4824-4828. |
| [17] | CHANG Pohan， LIU Shangyi， LAN Yubing， et al.Ultrahigh responsivity and detectivity graphene?perovskite hybrid phototransistors by sequential vapor deposition[J].Scientific Reports，2017，7.Doi:10.1038/srep46281. |
| [18] | CHENG H C， WANG Gongming， LI Dehui， et al.Van der waals heterojunction devices based on organohalide perovskites and two?dimensional materials[J].Nano Letters，2016，16（1）:367-373. |
| [19] | MA Renzhi， SASAKI T.Two?dimensional oxide and hydroxide nanosheets:Controllable high?quality exfoliation，molecular assembly，and exploration of functionality[J].Accounts of Chemical Research，2015，48（1）:136-143. |
| [20] | HINTERMAYR V A， RICHTER A F， EHRAT F， et al.Tuning the optical properties of perovskite nanoplatelets through composition and thickness by ligand?assisted exfoliation[J].Advanced Materials，2016，28（43）:9478-9485. |
| [21] | TONG Yu， EHRAT F， VANDERLINDEN W， et al.Dilution-induced formation of hybrid perovskite nanoplatelets[J].ACS Nano，2016，10（12）:10936-10944. |
| [22] | HU Yuchao， GUO Liejin.Rapid preparation of perovskite lead niobate nanosheets by ultrasonic?assisted exfoliation for enhanced |
| [22] | visible?light?driven photocatalytic hydrogen production[J].ChemCatChem，2015，7（4）:584-587. |
| [23] | LIANG Yin， SHANG Qiuyu， WEI Qi， et al.Lasing from mechanically exfoliated 2D homologous Ruddlesden?Popper perovskite engineered by inorganic layer thickness[J].Advanced Materials，2019，31（39）.Doi:10.1002/adma.201903030. |
| [24] | XIE Meilin， LIU Huan， CHUN Fengjun， et al.Aqueous phase exfoliating quasi-2D CsPbBr3 nanosheets with ultrahigh intrinsic water stability[J].Small，2019，15（34）.Doi:10.1002/smll.201901994. |
| [25] | WANG Xudong， MIAO Naihua， LIAO Jinfeng， et al.The top?down synthesis of single?layered Cs4CuSb2Cl12 halide perovskite nanocrystals for photoelectrochemical application[J].Nanoscale，2019，11（12）:5180-5187. |
| [26] | XING Jun， YAN Fei， ZHAO Yawen， et al.High?efficiency light?emitting diodes of organometal halide perovskite amorphous nano? particles[J].ACS Nano，2016，10（7）:6623-6630. |
| [27] | AUDEBERT P， CLAVIER G， ALAIN-RIZZO V， et al.Synthesis of new perovskite luminescent nanoparticles in the visible ran?ge[J].Chemistry of Materials，2009，21（2）:210-214. |
| [28] | CHEN Zhihui， ZHANG Qi， ZHU Menglong， et al.Synthesis of two-dimensional perovskite by inverse temperature crystallization and studies of exciton states by two?photon excitation spectroscopy[J].Advanced Functional Materials，2020，30（31）.Doi:10.1002/adfm.202002661. |
| [29] | BAI Yu， ZHANG Haixin， ZHANG Mingjing， et al.Liquid?phase growth and optoelectronic properties of two?dimensional hybrid perovskites CH3NH3PbX3（X=Cl，Br，I）[J].Nanoscale，2020，12（2）:1100-1108. |
| [30] | KUNDU K， ACHARYYA P， MAJI K， et al.Synthesis and localized photoluminescence blinking of lead?free 2D nanostructures of Cs3Bi2I6Cl3 perovskite[J].Angewandte Chemie International Edition，2020，59（31）:13093-13100. |
| [31] | SHI Enzheng， YUAN Biao， SHIRING S B， et al.Two?dimensional halide perovskite lateral epitaxial heterostructures[J].Nature，2020，580（7805）:614-620. |
| [32] | SHAO Zhipeng， WANG Zaiwei， LI Zhipeng， et al.A scalable methylamine gas healing strategy for high?efficiency inorganic pero?vskite solar cells[J].Angewandte Chemie，2019，131（17）:5643-5647. |
| [33] | SCHMITT T， BOURELLE S，TYE N，et al.Control of crystal symmetry breaking with halogen?substituted benzylammonium in layered hybrid metal?halide perovskites[J].Journal of the American Chemical Society，2020，142（11）:5060-5067. |
| [34] | TONG Guoqing， LI Huan， LI Danting， et al.Dual?phase CsPbBr3-CsPb2Br5 perovskite thin films via vapor deposition for high?performance rigid and flexible photodetectors[J].Small，2018，14（7）.Doi:10.1002/smll.201702523. |
| [35] | HU Xuelu， ZHOU Hong， JIANG Zhenyu， et al.Direct vapor growth of perovskite CsPbBr3 nanoplate electroluminescence devices[J].ACS Nano，2017，11（10）:9869-9876. |
| [36] | WANG Renyan， MUHAMMAD Y， XU Xiang， et al.Facilitating all?inorganic halide perovskites fabrication in confined?space deposition[J].Small Methods，2020，4（7）.Doi:10.1002/smtd.202000102. |
| [37] | ZHU Xuejie， XU Zhuo， ZUO Shengnan， et al.Vapor?fumigation for record efficiency two?dimensional perovskite solar cells with superior stability[J].Energy & Environmental Science，2018，11（12）:3349-3357. |
| [38] | LIANG Jia， FANG Qiyi， WANG Hua， et al.Perovskite?derivative valleytronics[J].Advanced Materials，2020，32（48）.Doi:10.1002/adma.202004111. |
| [39] | CHEN Xiaogang， SONG Xianjiang， ZHANG Zhixu， et al.Two?dimensional layered perovskite ferroelectric with giant piezoelectric voltage coefficient[J].Journal of the American Chemical Society，2020，142（2）:1077-1082. |
| [40] | KIM D， JUNG H J， PARK I J， et al.Efficient，stable silicon tandem cells enabled by anion?engineered wide?bandgap perovskit? es[J].Science，2020，368（6487）:155-160. |
| [41] | JEONG G，KOO D， SEO J， et al.Suppressed interdiffusion and degradation in flexible and transparent metal electrode?based pe? |
| [41] | rovskite solar cells with a graphene interlayer[J].Nano Letters，2020，20（5）:3718-3727. |
| [42] | RICCIARDULLI A G， YANG Sheng， SMET J H， et al.Emerging perovskite monolayers[J].Nature Materials，2021，20（10）:1325-1336. |
| [43] | YIN Zixi， LENG Jing， WANG Shiping， et al.Auger?assisted electron transfer between adjacent quantum wells in two?dimensional layered perovskites[J].Journal of the American Chemical Society，2021，143（12）:4725-4731. |
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