Environment·Health·Safety

Study on enhanced modification of fly ash with alkali hydrothermal-coupling agent and its surface properties

  • Bo Tan ,
  • Baojian Wu ,
  • Xudong Liu ,
  • Yuxiang Liang ,
  • Meigui Yi
Expand
  • School of Chemical Engineering,Sichuan University,Chengdu 610065,China

Received date: 2020-08-12

  Online published: 2021-05-12

Abstract

The surface of fly ash was modified by alkali solution hydrothermal treatment and grafting with silane coupling agent to improve its interfacial compatibility in polymer matrix.The microstructure,composition and surface properties of fly ash were characterized by scanning electron microscope(SEM),X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),infrared spectroscopy(FT-IR) and contact angle test.When the concentration of NaOH was increased from 0 mol/L to 4.0 mol/L,fly ash presented petal-like architecture and formed Na6(AlSiO46·4H2O,which led to the increase of specific sur-face area from 12.2 m2/g to 46.4 m2/g,and the reactive sites increased,which was beneficial to graft with silane coupling agent and improve the interfacial compatibility with polymer.

Cite this article

Bo Tan , Baojian Wu , Xudong Liu , Yuxiang Liang , Meigui Yi . Study on enhanced modification of fly ash with alkali hydrothermal-coupling agent and its surface properties[J]. Inorganic Chemicals Industry, 2021 , 53(5) : 84 -87 . DOI: 10.11962/1006-4990.2020-0317

References

[1] 刘新杰, 王昊, 刘丽丽. 粉煤灰资源开发利用及产业发展[J]. 无机盐工业, 2018,50(5):12-14.
[2] 王丽萍, 李超. 粉煤灰资源化技术开发与利用研究进展[J]. 矿产保护与利用, 2019,39(4):38-45.
[3] 李佳, 张思奇, 倪文, 李子富, 等. 垃圾焚烧飞灰的固化及综合利用研究进展[J]. 金属矿山, 2019(12):182-187.
[4] Wong Guojing, Fan Xiaohui, Gan Min, et al. Resource utilization of municipal solid waste incineration fly ash in iron ore sintering pro-cess:A novel thermal treatment[J]. Journal of Cleaner Production, 2020,263.Doi: 10.1016/j.jclepro.2020.121400.
[5] 张祥成, 孟永彪. 浅析中国粉煤灰的综合利用现状[J]. 无机盐工业, 2020,52(2):1-5.
[6] 杨明成, 李召朋, 宋卫东, 等. 废旧PE/木粉/粉煤灰复合材料的制备与辐射改性研究[J]. 塑料工业, 2010,38(5):12-14,26.
[7] 王继虎, 徐善中, 唐志君, 等. 粉煤灰/硅橡胶复合材料的性能研究[J]. 高分子通报, 2013(3):78-82.
[8] 朱建军, 谢吉民, 陈敏, 等. 粉煤灰制二氧化硅表面疏水改性机理研究[J]. 非金属矿, 2008(1):7-9.
[9] Xie Jun, Wu Shaopeng, Pang Ling. Influence of surface treated fly ash with coupling agent on asphalt mixture moisture damage[J]. Construction and Building Materials, 2012,30:340-346.
[10] Sengupta S, Maity P, Ray D, et al. Stearic acid as coupling agent in fly ash reinforced recycled polypropylene matrix composites:Struc-tural,mechanical,and thermal characterizations[J]. Journal of APP-lied Polymer Science, 2013,130(3):1996-2004.
[11] Zhang Hongbo, Wei Lubin. Screening of surface medication agents and modification mechanism of fly ash[J]. Journal of China Uni-versity of Mining & Technology, 2007,17(3):342-344.
[12] Alkadasi N A N, Sarwade B D, Hundiwale D G, et al. Studies on the effect of titanate coupling agent(2.0%) on the mechanical proper-ties of flyash-filled polybutadiene rubber[J]. Journal of Applied Polymer Science, 2004,93, 1293-1298.
[13] Norihiro Murayama, Hideki Yamamoto, Junji Shibata. Zeolite syn-journal from coal fly ash by hydrothermal reaction using various al-kali sources[J]. Journal of Chemical Technology and Biotechnolo-gy, 2002,77:280-286.
[14] 柳翱, 巴晓微, 刘颖, 等. BET容量法测定固体比表面积[J]. 长春工业大学学报:自然科学版, 2012,33(2):197-199.
Outlines

/