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Study on pilot catalytic performance of the modified catalyst for alkylation of toluene with methanol to p-xylene
Received date: 2020-09-11
Online published: 2021-03-11
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A composite-modified nano ZSM-5 zeolite catalyst was prepared through multi-step impregnation with the precur-sor of SiO2,MgO,P2O5 and Pt.The catalytic performance for alkylation of toluene with methanol was investigated in a six-stage fixed bed reactor,which is filled with more than 720 g of the catalyst.The result shows that the conversion rate of toluene was controllably adjusted in the range of 22%~30% by adjusting the amount-of-substance ratio of toluene to methanol,as well as the selectivity to xylene in liquid products of alkylation and selectivity to p-xylene in xylene（o-xylene,m-xylene and p-xylene） both simultaneously stabilized above 95%.The life of the catalyst reaches 1 300 h in alkylation reaction and the catalytic activity decreased after 1 200 h.The fresh and deactivated catalysts were characterized by XRD,TG-DTG and N2 adsorption-desorption.It is indicated that the generated coke blocked the pores of ZSM-5 zeolite or deposited on the active sites of catalyst,leading to the catalytic deactivation.The catalytic activity of deactivated catalyst almost can be restored after in-situ regeneration.
Li Xiaoguo , Li Yongheng , Hou Zhanggui , Han Guodong , Xiao Jiawang , Gao Jinping , Chang Yang . Study on pilot catalytic performance of the modified catalyst for alkylation of toluene with methanol to p-xylene[J]. Inorganic Chemicals Industry, 2021 , 53(3) : 97 -101 . DOI: 10.11962/1006-4990.2020-0419
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