Environment·Health·Safety

Titanium white by-product ferrous sulfate photofenton oxidation degradation of methyl orange in wastewater

  • Yirui Shu ,
  • Pan Zhang ,
  • Wei Wang ,
  • Hengli Xiang ,
  • Genkuan Ren ,
  • Dehua Xu ,
  • Zhiye Zhang ,
  • Xiushan Yang
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  • 1. School of Chemical Engineering,Sichuan University,Chengdu 610065,China
    2. Engineering Research Center of Comprehensive Utilization and Clean Processing of Phosphorus Resources,Ministry of Education
    3. Yibin University

Received date: 2020-09-19

  Online published: 2021-03-11

Abstract

Using ferrous sulfate(by-product of tianium white) as iron source and catalyst of photogenic Fenton,the oxidative decomposition of methyl orange by ferrous sulfate-H2O2 system under ultraviolet light was studied.The effect of temperature, concentration of H2O2,wavelength of ultraviolet light,concentration of ferrous sulfate and concentration of Fe2+ on the decolorization rate of methyl orange was investigated.It is demonstrated that the decolorization rate of methyl orange is the fastest which reaches 100% under the conditions of 35 ℃,6.4 mmol/L of hydrogen peroxide,1.0 mmol/L of ferrous sulfate(about 1.0 mmol/L of Fe2+) and 395 nm of ultraviolet light.The decolorization effect of the ferrous sulfate on methyl orange was better than that of pure heptahydrate ferrous sulfate.The work has expanded a new strategy for the effective utilization of the by-product of tianium white,which can be used to treat methyl orange by catalytic degradation

Cite this article

Yirui Shu , Pan Zhang , Wei Wang , Hengli Xiang , Genkuan Ren , Dehua Xu , Zhiye Zhang , Xiushan Yang . Titanium white by-product ferrous sulfate photofenton oxidation degradation of methyl orange in wastewater[J]. Inorganic Chemicals Industry, 2021 , 53(3) : 68 -72 . DOI: 10.11962/1006-4990.2020-0190

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