Reviews and Special Topics

Review of basic properties and influence factors related to stability of chlorine dioxide

  • Yuhe Liu ,
  • Mingsong Wu ,
  • Xinshu Wang ,
  • Nannan Huang ,
  • Xiuyan Zhou
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  • 1. School of Resources and Civil Engineering,Northeastern University,Shenyang,110819,China
    2. School of Resourcesand Materials,Northeastern University at Qinhuangdao
    3. Qinhuangdao Key Laboratory of Water Conservation and Pollution Control and Ecological restoration

Received date: 2020-09-12

  Online published: 2021-03-11

Abstract

Chlorine dioxide has been widely used as a kind of high effective broad-spectrum and disinfectant.However,it is difficult to be prepared to stable formulations because of its active properties,which limits its application and promotion. The chemical properties and effects of pH,light,temperature and chlorinated substance to the stability of chlorine dioxide were reviewed.It is pointed out that ClO2 cannot exist stably in water.It can only slow down the decomposition and disproportionation process by adjusting the environmental conditions or use the principle of equilibrium to keep the concentration stable,which provides a theoretical basis for the development of high purity and ready-to-use stable ClO2 products.On this basis,the kinetics of ClO2 conversion should be further studied,and methods such as complexation should be tried to improve the stability of ClO2 related products.

Cite this article

Yuhe Liu , Mingsong Wu , Xinshu Wang , Nannan Huang , Xiuyan Zhou . Review of basic properties and influence factors related to stability of chlorine dioxide[J]. Inorganic Chemicals Industry, 2021 , 53(3) : 18 -23 . DOI: 10.11962/1006-4990.2020-0233

References

[1] 吴明松, 马仕慈, 刘博. 二氧化氯在医院消毒中的应用[J]. 中国消毒学杂志, 2019,36(1):60-63.
[2] 张晓娜. 二氧化氯消毒在饮用水处理中的应用[J]. 城镇供水, 2019(1):15-17.
[3] Ran Y, Qingmin C, Maorun F. Chlorine dioxide generation method and its action mechanism for removing harmful substances and maintaining quality attributes of agricultural products[J]. Food and Bioprocess Technology, 2019,12(7):1110-1122.
[4] 张晓娜, 刘清华, 陈卓华, 等. 稳定性二氧化氯活化试验研究[J]. 城镇供水, 2019(2):59-62.
[5] Pugliese S, Underwood K, Soluri A, et al. Stabilized chlorine dioxide co-mpositions and methods for use as disinfectants:US, 2017202876[P]. 2017-07-20.
[6] Gordon G. Is all chlorine dioxide created equal?[J]. Journal-Ameri-can Water Works Association, 2001,93(4):163-174.
[7] Vaida V, Simon J D. The photoreactivity of chlorine dioxide[J]. Sci-ence, 1995,268(5216):1443-1448.
[8] Vaida V, Goudjil K, Simon J D, et al. Comparisons between the reac-tivity of chlorine dioxide in the gas phase and water solution[J]. Journal of Molecular Liquids, 1994,61(1/2/3):133-152.
[9] Dunn R C, Anderson J L, Foote C S, et al. Solution photochemistry of chlorine dioxide:mechanisms for the generation of atomic chlo-rine[J]. Journal of the American Chemical Society, 1993,115(12):5307.
[10] 田朝晖, 裴元生. 二氧化氯在水溶液中的歧化反应趋势[J]. 甘肃环境研究与监测, 2003,16(1):92-94.
[11] Stanbury D M, Figlar J N. Vanishingly slow kinetics of the ClO2/Cl-reaction:its questionable significance in nonlinear chlorite reactio-ns [J]. Coordination Chemistry Reviews, 1999,187(1):223-232.
[12] 朱琨, 陈慧. 纯二氧化氯的稳定性及常规条件下储存方法研究[J]. 化工标准·计量·质量, 2005,25(9):35-38.
[13] 崔崇威. 二氧化氯消毒后给水管网中氯酸根和亚氯酸根的转化规律研究[J]. 中国消毒学杂志, 2018,35(12):881-885.
[14] Marcon J, Mortha G, Marlin N, et al. New insights into the decompo-sition mechanism of chlorine dioxide at alkaline pH[J]. Holzforsc-hung, 2017,71(7/8):599-610.
[15] Odeh I N, Francisco J S, Margerum D W. New pathways for chlo-rine dioxide decomposition in basic solution[J]. Inorganic Chemi-stry, 2002,41(24):6500-6506.
[16] 裴元生, 栾兆坤, 陈慧. 电子活度和pH对二氧化氯制备和稳定性的影响[J]. 无机化学学报, 2001,17(3):407-413.
[17] Wu V C H. Chlorine dioxide (ClO2)[M]. Siddiqui M W.Postharve-st management approaches for maintaining quality of fresh pro-duce. Switzerland:Springer,Cham, 2016: 209-218.
[18] Bishenden E, Haddock J, Donaldson D J. Resonance-enhanced mu-ltiphoton ionization(REMPI) measurement of atomic chlorine(2P3/2 and 2P1/2) produced in the photolysis of chlorine dioxide(OClO) from 355 to 370 nm[J]. The Journal of Physical Chemistry, 1991,95(6):2113-2115.
[19] 候宏卫, 贺启环. 二氧化氯的性质及其相关反应[C]// 成都:全国制浆造纸行业国产二氧化氯装备及节能减排新技术应用推介会论文集,北京:中国造纸学会, 2011: 64-69.
[20] Vaida V, Richard E C, Jefferson A, et al. Spectroscopy and photo-chemistry of chlorine dioxide[J]. Berichte Der Bunsengesellschaft Für Physikalische Chemie, 1992,96(3):391-394.
[21] Vaida V, Frost G J, Brown L A, et al. Spectroscopy and photoreacti-vity in complex environments[J]. Berichte Der Bunsengesellschaft Für Physikalische Chemie, 1995,99(3):371-377.
[22] Pursell C J, Conyers J, Alapat P, et al. Photochemistry of chlorine dioxide in ice[J]. The Journal of Physical Chemistry, 1995,99(26):10433-10437.
[23] Reid P J. Understanding the phase-dependent reactivity of chlorine dioxide using resonance raman spectroscopy[J]. Accounts of Che-mical Research, 2001,34(9):691-698.
[24] Chang Y J, Simon J D. Ultrafast dynamics of chlorine dioxide pho-tochemistry in water studied by femtosecond transient absorption spectroscopy[J]. The Journal of Physical Chemistry, 1996,100(16):6406-6411.
[25] Cosson H, Ernst W R. Photodecomposition of chlorine dioxide and sodium chlorite in aqueous solution by irradiation with ultraviolet light[J]. Industrial & Engineering Chemistry Research, 1994,33(6):1468-1475.
[26] 于玲红, 段浩洁, 李卫平, 等. 二氧化氯在小型给水管网系统中的衰减规律研究[J]. 科学技术与工程, 2016,16(26):291-296.
[27] 袁海涛, 康志娟, 赵海栋, 等. 二氧化氯水溶液的稳定性研究[J]. 河北工业科技, 2010,27(5):302-304.
[28] Mcwhorter T E, Kazlas P, Anand M, et al. Storage-stable aqueous solutions of chlorine dioxide and methods for preparing and using them:US,9045341B2[P]. 2015-06-02.
[29] 莫正波, 胡松涛, 胡德栋. 低浓度下亚氯酸钠与盐酸制备二氧化氯的试验研究[J]. 山东大学学报:工学版, 2017,47(2):100-105.
[30] Ahlstrom C, Boyd D W, Epstein I R, et al. Reaction between per-manganate ion and chlorine(Ⅲ):kinetics and mechanism of the initial reaction and the dissociation of chlorous acid[J]. Inorganic Chemistry, 1984,23(14):2185-2188.
[31] Kieffer R G, Gordon G. Disproportionation of chlorous acid.Ⅰ.stoic-hiometry[J]. Inorganic Chemistry, 1968,7(2):235-239.
[32] Kieffer R G, Gordon G. Disproportionation of chlorous acid.Ⅱ.kine-tics[J]. Inorganic Chemistry, 1968,7(2):239-244.
[33] Peintler G, Nagypal I, Epstein I R. Kinetics and mechanism of the reaction between chlorite ion and hypochlorous acid[J]. The Jour-nal of Physical Chemistry, 1990,94(7):2954-2958.
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