Inorganic Chemicals Industry >
Research and application progress of hydrocracking reaction kinetics model
Received date: 2020-08-17
Online published: 2021-02-06
Hydrocracking technology has played an important role in petrochemical industry.In order to deeply investigate the laws of hydrocracking reaction,optimize the process operating conditions and products distribution of industrial installation,and achieve the goal of petrochemical enterprises intellectualization and interest maximization,the research of hydrocracking reaction kinetics model has received wide attention.In this paper,the related research and application progress of hydrocrack-ing reaction kinetics models were reviewed,and the research history of hydrocracking reaction kinetics model was introduced.The objectives of hydrocracking reaction kinetics model research had developed from simple macroscopic correlation models in early phase to traditional and continuous lumping models which lumps were divided by fraction or other product programs,then the objectives had developed to be complex microscopic molecular lumping models.Application conditions of different hydrocracking reaction kinetic models were summarized; industrial practicability of traditional lumped model and raw mate-rials & products applicability of molecular lumping models were highlighted.It was pointed out that it is great significance and challenge to develop a comprehensive hybrid kinetic model combining with correlation models and lumping models （especi-ally molecular lumping） effectively in the research of hydrocracking and other petroleum processing reaction kinetic models in the future.
Key words： hydrocracking; kinetic model; correlation model; lumping model; molecular lumping
Naifeng Yan , Zhizhong Hu . Research and application progress of hydrocracking reaction kinetics model[J]. Inorganic Chemicals Industry, 2021 , 53(2) : 28 -33 . DOI: 10.11962/1006-4990.2020-0132
| [1] | 彭冲, 曾榕辉, 吴子明, 等. 高效加氢裂化催化剂级配技术开发及应用[J]. 炼油技术与工程, 2016,46(3):49-51. |
| [2] | 杜艳泽, 王凤来, 孙晓艳, 等. FRIPP加氢裂化催化剂研发新进展[J]. 当代化工, 2011,40(10):1029-1033. |
| [3] | 韩龙年, 方向晨, 彭冲, 等. 减压蜡油加氢裂化反应动力学模型研究进展[J]. 化工进展, 2012,31(11):2435-2441. |
| [4] | 吴青. 流程工业智慧炼化建设的研究与实践[J]. 无机盐工业, 2017,49(12):1-8. |
| [5] | 吴青. 炼化企业数字化工厂建设及其关键技术研究[J]. 无机盐工业, 2018,50(2):1-7. |
| [6] | 黄汤舜, 王子军, 张书红, 等. 重油加氢裂化过程动力学模型的研究进展[J]. 化工进展, 2017,36(S1):149-154. |
| [7] | Wiser W H, Singh S, Qader S A, et al. Catalytic hydrogenation of multiring aromatic coal tar constituents[J]. Industrial & Engineer-ing Chemistry, 1970,9(3):350-357. |
| [8] | 韩崇仁. 加氢裂化工艺与工程[M]. 北京: 中国石化出版社, 2001, 593-594. |
| [9] | Ancheyta J, Sancheza S, Rodriguze M A. Kinetic modeling of hydro-cracking of heavy oil fractions:A review[J]. Catalysis Today, 2005,109(1):76-92. |
| [10] | Qader S A, Hillg R. Hydrocracking of gas oil[J]. Industrial & En-gineering Chemistry Process Design and Development, 1969,8(1):98-105. |
| [11] | Yui S M. Mild hydrocracking of bitumen-derived coker and hydro-cracker heavy gas oils:Kineties,product yields and product pro-perties[J]. Industrial and Engineering Chemistry Research, 1989,28(9):1178-1284. |
| [12] | Sadighi S, Ahmad A. 4-lump kinetic model for vacuum gas oil hy-drocracker involving hydrogen consumption[J]. Korean Journal of Chemical Engineering, 2010,27(4):1099-1108. |
| [13] | 朱豫飞, 张治和. 加氢裂化反应动力学模型初步探讨[J]. 炼油设计, 1990,20(3):18-23. |
| [14] | 郑明方, 张素贞. 加氢裂化反应器数学模型的研究[J].石油化工自动化,1998(4):31-34. |
| [15] | Krishima R, Saxena A K. Use of axial-dispersion model for kinetic description of hydrocracking[J]. Chemical Engineering Science, 1989,44(3):703-712. |
| [16] | 韩崇仁. 加氢裂化工艺与工程[M]. 北京: 中国石化出版社, 2001: 621-622. |
| [17] | Laxminarasimhan C S, Verma R P. Continuous lumping model for simulation of hydrocracking[J]. AIChE Journal, 1996,42(4):2645-2653. |
| [18] | Becker P J, Celse B, Guillame D, et al. Hydrotreatment modeling for a variety of VGO feedstocks:A continuous lumping approach[J]. Fuel, 2015,139(8):133-143. |
| [19] | Boosari S S H, Makouei N, Stewart P. Application of bayesian app-roach in the parameter estimation of continuous lumping kinetic model of hydrocracking process[J]. Scientific Research, 2017,7(3):257-269. |
| [20] | Liguras D K, Allen D T. Structural models for catalytic cracking model compound reactions[J]. Industrial & Engineering Chemistry Research, 1989,28(6):665-673. |
| [21] | Martens G G, Marin G B. Kinetics for hydrocracking based on struc-tural classes:Model development and application[J]. AIChE Jo-urnal, 2001,47(7):1607-1622. |
| [22] | Hu S Y, Zhu X X. A general frame work for incorporating molecular modeling into overall refinery optimization[J]. Applied Thermal Engineering, 2001,21(14):1331-1348. |
| [23] | Song W J, Mahalec L, Long J, et al. Modeling the hydrocracking process with deep neural networks[J]. Industrial & Engineering Chemistry Research, 2020,59(7):3077-3090. |
| [24] | Froment G F. Single event kinetic modeling of complex catalytic processes[J]. Catal.Rev.Sci.Eng., 2005,47(1):83-124. |
| [25] | 史权, 张霖宙, 赵锁奇, 等. 炼化分子管理技术:概念与理论基础[J]. 石油科学通报, 2016,1(2):270-278. |
| [26] | Campbell D M, Bennett C, Hou Z, et al. Attribute-based modeling of resid structure and reaction[J]. Industrial & Engineering Chemi-stry Research, 2009,48(4):1683-1693. |
| [27] | de Oliveira L P, Verstraete J J, Kolb M. Simulating vacuum residue hydroconversion by means of Monte-Carlo techniques[J]. Cataly-sis Today, 2014,222(1):208-220. |
| [28] | Sharifi K, Safiri A, Asl M H, et al. Development of SVM model for prediction of hydrocracking product yields[J]. Petroleum Chemi-stry, 2019,59(2):233-238. |
| [29] | 喻胜飞, 罗武生. 重油加氢裂化四集总反应动力学模型的研究[J]. 石油化工设计, 2007,24(1):15-17. |
| [30] | Sadighi S, Ahmad A. An optimization approach for increasing the profit of a commercial VGO hydrocracking process[J]. The Cana-dian Journal of Chemical Engineering, 2013,91(6):1077-1091. |
| [31] | Powell R T. Kinetic hydrocracker model helps engineers predict yields,targets,operations[J]. Oil and Gas, 1989,87(2):61-64. |
| [32] | 方向晨. 加氢裂化[M]. 北京: 中国石化出版社, 2008: 306-318. |
| [33] | Chen Z Y, Feng S, Zhang L Z, et al. Molecular-level kinetic modell-ing of fluid catalytic cracking slurry oil hydrotreating[J]. Chemical Engineering Science, 2019,195(23):619-630. |
/
| 〈 |
|
〉 |