Inorganic Chemicals Industry >
Strategy on safety of hydrogen peroxide oxidation process
Received date: 2020-08-05
Online published: 2021-01-08
Copyright
：China hydrogen peroxide green oxidation process is developing vigorously,but the process risk is high and there are many safety accidents,which seriously hinders the development and promotion of new process.In order to improve the process safety research and promote the process development,the process flow was divided into hydrogen peroxide storage system,material feeding system,reaction system,distillation system and other units.The safety problems involved in the unit system were elaborated,and the research methods and results at present were summarized and discussed.Through combing and analyzing the safety problems and safety research ideas in the whole process of hydrogen peroxide oxidation,suggestions and references were provided for relevant units to establish systematic safety research methods and strategies and comprehensively improve process safety.
Key words： hydrogen peroxide; oxidation; safety engineering; thermal hazard; explosion hazard
Zhu Hongwei , Jiang Jie , Sun Bing , Sun Feng , Xu Wei . Strategy on safety of hydrogen peroxide oxidation process[J]. Inorganic Chemicals Industry, 2021 , 53(1) : 77 -81 . DOI: 10.11962/1006-4990.2020-0099
| [1] | 刘洋, 曾庆乐, 唐红艳, 等. 绿色化学试剂过氧化氢在有机合成中的应用研究进展[J]. 有机化学, 2010,31(7):986-996. |
| [2] | 张振清. 过氧化氢氧化丙醇合成丙酸的工艺研究[D]. 青岛:青岛科技大学, 2019. |
| [3] | 杨超, 杨柳, 李向阳, 等. 多相氧化组合反应器与耦合分离新技术的研究构想与前景展望[J]. 工程科学与技术, 2018,50(2):13-23. |
| [4] | 吴德建, 钱新明, 黄平. 双氧水热爆炸研究进展[J]. 中国安全生产科学技术, 2011,7(8):14-20. |
| [5] | 姜杰, 谢传欣, 王振刚, 等. 氯丙烯环氧化反应器气相安全控制条件[J]. 化工学报, 2010,61(2):330-335. |
| [6] | 傅圣英. 浙江善高化学公司双氧水车间爆炸火灾事故J]. 现代班组, 2008(3):43. |
| [7] | 杨衍超, 廖菊英. 一起双氧水储罐爆炸事故的原因调查[J]. 工业安全与环保, 2009,35(2):29-30. |
| [8] | 新华网. 湖南岳阳巴陵石化厂区爆炸原因查明[EB/OL]. (2007-01-10).http://news.sina.com.cn/c/2007-01-10/172112001601.shtml. |
| [9] | 360百科. 9·15河北晋州货车爆炸事故[EB/OL]. (2015-08-01). https://baike.so.com/doc/4768390-4984053.html. |
| [10] | 刘小琴. 双氧水分解反应热危险性分析[D]. 青岛: 青岛科技大学, 2015. |
| [11] | 王犇, 马翔, 张淑娟, 等. 过氧化氢危险性分析[J]. 无机盐工业, 2013,45(3):15-18. |
| [12] | Chen K Y, Lin C M, Shu C M, et al. An evaluation on thermokine-tic parameters for hydrogen peroxide at various concentrations by DSC[J]. Journal of Thermal Analysis and Calorimetry, 2006,85(1):87-89. |
| [13] | 孙峰, 谢传欣, 张帆, 等. pH值对双氧水绝热分解特性的影响[J]. 化学工程, 2012(2):42-45. |
| [14] | 朱希增, 朱顺兵, 张文兴. 金属离子对双氧水热稳定性的影响研究[J]. 安全与环境学报, 2016,16(5):173-176. |
| [15] | Eto I, Akiyoshi M, Miyake A, et al. Hazard evaluation of runaway reaction of hydrogen peroxide-influence of contamination of vario-us ions[J]. Journal of Loss Prevention in the Process Industries, 2009,22(1):15-20. |
| [16] | Zeineb O, Hedi B A, Jeday M R, et al. Kinetic study of the catalytic decomposition of H2O2 in phosphoric acid medium[J]. Internatio-nal Journal of Hydrogen Energy, 2015,40(2):1278-1282. |
| [17] | 孙峰, 谢传欣, 薛岩, 等. 双氧水热失控时的泄放面积评估[J]. 工业安全与环保, 2012(11):54-56. |
| [18] | 杨守生, 江伟, 王学宝. 醇对双氧水热危险性的影响研究[J]. 安全与环境学报, 2010,10(4):165-167. |
| [19] | 朱红伟, 姜杰, 孙冰, 等. 氯丙烯直接环氧化工艺反应物料危险性研究[J]. 中国安全生产科学技术, 2018,14(1):173-178. |
| [20] | 张帆, 信云霞, 贾学五. 大孔树脂对过氧化氢热稳定性的影响[J]. 无机盐工业, 2017,49(8):73-76. |
| [21] | Townsend D I, Tou J C. Thermal hazard evaluation by an accelera-ting rate calorimeter[J]. Thermochimica Acta, 1980,37(1):1-30. |
| [22] | 姜杰, 徐伟, 苏晨, 等. 氯丙烯环氧化反应器热危险性评估[J]. 石油化工, 2011,40(2):161-165. |
| [23] | 鲁安监发[2012]110号. 关于山东国金化工厂双氧水生产装置“8.25”爆炸事故情况的通报[EB/OL]. (2012-09-06). http://yjt.shandong.gov.cn/zwgk/zfgw/201810/t20181025_2260915.html. |
| [24] | 李红梅. 氨肟化反应中双氧水分解的影响因素探讨[J]. 合成纤维工业, 2012,35(4):34-37. |
| [25] | 张帆, 信云霞, 贾学五. 含碱条件下的双氧水反应失控与安全泄放特性[J]. 无机盐工业, 2015,47(10):69-73. |
| [26] | 金满平, 朱云峰, 张婧, 等. 醋酸乙烯聚合体系热失控风险评估及失控抑制[J].中国安全科学学报, 2017(1):104-109. |
/
| 〈 |
|
〉 |