Inorganic Chemicals Industry >
Preparation of spherical alumina and its application in PDH
Received date: 2020-01-18
Online published: 2020-06-12
Alumina precursors synthesized by neutralization method,hydrothermal method,alcoholic aluminium method and aluminium powder-hydrochloric acid reflux method were used as raw materials to prepare spherical alumina carriers which are marked as ZH、SR、ST and SOL respectively.The samples were characterized by strength tester,XRF,BET,SEM and NH3-TPD,etc.The effect of the alumina support on the performance of Pt-Sn-K/Al2O3 catalysts in the dehydrogenation of propane was investigated.The results showed that the alumina precursors synthesized by different methods have been used to prepared spherical alumina supports with high strength.Especially the alumina supports prepared by hydrothermal method and alcoholic aluminium method also had large pore volume and moderate specific surface area.The preparation methods of precursors had greater influence on the acidity of catalysts,while neutralization catalyst was mainly weak-medium-strong acid center and other catalysts were mainly weak acid center,and the order of acidity was ZH-CAT>SOL-CAT>ST-CAT>SR-CAT.The evaluation results showed that the supports prepared by alcoholic aluminium method and hydrothermal method had good performance for propane dehydrogenation catalyst,which was equivalent to or even superior to the industrial catalyst.
Key words: dehydrogenation; propane; alumina; catalyst
Wenjian Yang , Guangying Meng , Xiaoyun Li , Yanmin Sun , Qi Cai , Qiushuang Guo . Preparation of spherical alumina and its application in PDH[J]. Inorganic Chemicals Industry, 2020 , 52(6) : 87 -91 . DOI: 10.11962/1006-4990.2019-0412
[1] | 刘杰, 刘昌呈, 马爱增 , 等. Pt系催化剂在丙烷脱氢反应中的研究进展[J]. 石油学报:石油加工, 2015,31(5):1218-1231. |
[2] | 朱静 . 低碳烷烃脱氢负载型铂锡催化剂的研究[D]. 南京:东南大学, 2006. |
[3] | Zangeneh F T, Mehrazma S, Sahebdelfar S . The influence of solvent on the performance of Pt-Sn/θ-Al2O3 propane dehydrogenation cat-alyst prepared by co-impregnation method[J]. Fuel Processing Te-chnology, 2013,109:118-123. |
[4] | 杨维慎, 吴荣安, 林励吾 . PtSn/Al2O3负载型催化剂丙烷脱氢性能的改进[J]. 石油化工, 1992,21(8):511-515. |
[5] | 郭松 . 丙烷脱氢多组分铂催化剂的研究[D]. 南京:南京大学, 2002. |
[6] | Yu C L, Ge Q J, Xu H Y , et al. Effects of Ce addition on the Pt-Sn/γ-A12O3 catalyst for propane dehydrogenation to propylene[J]. App-lied Catalysis A:General, 2006,315:58-67. |
[7] | T·V·沃斯科博尼克弗, D·H·魏, J·W·A·萨驰特勒 , 等 .脱氢催化剂组合物:中国,1649672A[P]. 2005 -08-03. |
[8] | Luo S, Wu N, Zhou B , et al. Effect of alumina support on the perfor-mance of Pt-Sn-K/γ-Al2O3 catalyst in the dehydrogenation of iso-butene[J]. Journal of Fuel Chemistry and Technology, 2013,41(12):1481-1487. |
[9] | He S B, Sun C L, Bai Z W , et al. Dehydrogenation of long chain par-affins over supported Pt-Sn-K/Al2O3 catalysts:A study of the alu-mina support effect[J]. Applied Catalysis A:General, 2009,356(1):88-98. |
[10] | 杨文建, 孟广莹, 李晓云 , 等. 球形ZSM-5分子筛催化剂的制备及其在甲醇制芳烃反应中的应用[J]. 石油炼制与化工, 2017,48(4):87-91. |
[11] | 李波, 邵玲玲 . 氧化铝、氢氧化铝的XRD鉴定[J]. 无机盐工业, 2008,40(2):54-57. |
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