Study on membrane integration technology in treatment of wastewater from chlorinated titanium dioxide

  • Wenbo Peng ,
  • Jianjun Yun ,
  • Bangchao Ding ,
  • Zuguo Bai ,
  • Weiyi Xiao ,
  • Xiaohu Wang
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  • Jiangsu Jiuwu Hi-Tech Corporation Limited,Nanjing 211808,China

Received date: 2020-01-11

  Online published: 2020-06-12

Abstract

A large number of neutral wastewater will be produced in the process of chlorinated titanium dioxide by inorganic coating treatment technology,which contains a small amount of titanium dioxide and water-soluble salts.At present,the titanium dioxide and water-soluble salts are discharged outside by most of the enterprises.The membrane integration(ceramic membrane+reverse osmosis membrane+nanofiltration membrane) treatment process was used to study the chlorination titanium dioxide post-treatment wastewater.TiO2 was separated and recovered by ceramic membrane filtration;the clear liquid of ceramic membrane was concentrated by reverse osmosis membrane and the clean water was recycled;the concentrated liquid of reverse osmosis was separated by nanofiltration membrane to separate sodium sulfate and sodium chloride.The results showed that the average flux of ceramic membrane was 650 L/(m 2·h),the mass concentration of titanium dioxide in the concentrate was 90 g/L,and mass concentration of titanium dioxide in permeate was less than 0.001 g/L.With the filtration of reverse osmosis membrane,retention rate of sodium sulfate and sodium chloride could reached above 99.5% and the mass fraction of salt in concentrated water was above 4%.Sodium sulfate and sodium chloride in concentrated water were separated by nanofiltration membrane.With the filtration of nanofiltration membrane,retention rate of sodium sulfate could reached 97%.Sodium sulfate concentration can reach more than 14%.

Cite this article

Wenbo Peng , Jianjun Yun , Bangchao Ding , Zuguo Bai , Weiyi Xiao , Xiaohu Wang . Study on membrane integration technology in treatment of wastewater from chlorinated titanium dioxide[J]. Inorganic Chemicals Industry, 2020 , 52(6) : 76 -79 . DOI: 10.11962/1006-4990.2019-0369

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