Inorganic Chemicals Industry >
Research progress of process intensification of acid leaching technology from chromite ore and separation of chromium-iron
Received date: 2020-01-19
Online published: 2020-06-12
Chromite is the main raw material source for the production of chromium salts.The acid leaching technology from chromite ore has become a worldwide concern due to its no Cr（Ⅵ） pollution and high resource utilization.The research pro-gress of the acid leaching technology from chromite ore and its separation method of chromium-iron in recent years were summarized.The acid leaching technology from chromite ore is mainly leaching with sulfuric acid as the strong acid,and the auxiliary method such as mechanical activation,oxidizer and microwave heating could make the chromite ore be leached efficiently and rapidly.The separation methods of chromium-iron from leaching solution including goethite method,jarosite process,extraction method,oxalic acid precipitate method,ferric ferrocyanide method and diammonium ferrous sulfate method etc..The combination of various strengthening methods and reaction processes has become an important research direction of chromite sulfuric acid leaching process.
Xianfeng Qin , Xuejun Quan , Peng Ye , Chengfei Feng , Gang Li . Research progress of process intensification of acid leaching technology from chromite ore and separation of chromium-iron[J]. Inorganic Chemicals Industry, 2020 , 52(6) : 13 -19 . DOI: 10.11962/1006-4990.2019-0430
| [1] | 丁翼 . 中国铬盐生产状况与展望[J]. 化工进展, 2004,23(4):345-348. |
| [2] | Zheng S, Zhang Y, Li Z , et al. Green metallurgical processing of ch-romite[J]. Hydrometallurgy, 2006,82(3):157-163. |
| [3] | Xu H B, Zhang Y, Li Z H , et al. Development of a new cleaner pro-duction process for producing chromic oxide from chromite ore[J]. Journal of Cleaner Production, 2006,14(2):211-219. |
| [4] | 张树龙, 张焕祯, 王智丽 , 等. 铬盐清洁生产工艺研究进展[J]. 无机盐工业, 2014,46(2):6-9. |
| [5] | Zhang B, Shi P, Jiang M . Advances towards a clean hydrometallur-gical process for chromite[J]. Minerals, 2016,6(1):7. |
| [6] | 纪柱 . 铬铁矿酸溶生产三价铬化合物[J]. 无机盐工业, 2012,44(12):1-5. |
| [7] | Shi P Y, Liu C J, Zhao Q , et al. Study on mechanisms of different sul-furic acid leaching technologies of chromite[J]. International Jour-nal of Minerals Metallurgy & Materials, 2017,24(9):983-990. |
| [8] | Vieceli N, Nogueira C A ,Pereira M F C, et al..Recovery of lithium car-bonate by acid digestion and hydrometallurgical processing from me-chanically activated lepidolite[J]. Hydrometallurgy, 2018,175:1-10. |
| [9] | 王兵, 李育彪, 张世鹏 , 等. 机械活化黄铜矿浸出动力学研究[J].中国矿业, 2018(2):136-140. |
| [10] | Vieceli N, Nogueira C A ,Pereira M F C,et al.Effects of mechanical activation on lithium extraction from a lepidolite ore concentra-te[J]. Minerals Engineering, 2017,102:1-14. |
| [11] | 伍凌, 陈嘉彬, 钟胜奎 , 等. 机械活化-盐酸常压浸出钛铁矿的影响[J].中国有色金属学报, 2015(1):211-219. |
| [12] | 李春, 陈胜平, 吴子兵 , 等. 机械活化方式对攀枝花钛铁矿浸出强化作用[J]. 化工学报, 2006,57(4):832-837. |
| [13] | Li X H, Zhang Y J, Pan L P , et al. Effect of mechanical activation on dissolution kinetics of neutral leach residue of zinc calcine in sulphuric acid[J]. Transactions of Nonferrous Metals Society of China, 2013,23(5):1512-1519. |
| [14] | Amer A M . Processing of Ras-Shait chromite deposits[J]. Hydrome-tallurgy, 1992,28(1):29-43. |
| [15] | Zhang Y, Zheng S L, Du H , et al. Effect of mechanical activation on alkali leaching of chromite ore[J]. Transactions of Nonferrous Metals Society of China, 2010,20(5):888-891. |
| [16] | 王正琛, 张洋, 聂瑶 , 等. 铬铁矿硫酸酸解过程强化[J]. 过程工程学报, 2016,16(2):245-251. |
| [17] | Stauter J C ,Um R T. Recovery of chromium values:US,4029734[P]. 1977 -06-14. |
| [18] | Vardar E, Eric R H, Letowski F K . Acid leaching of chromite[J]. Minerals Engineering, 1994,7(5/6):605-617. |
| [19] | Geveci A, Topkaya Y, Ayhan E . Sulfuric acid leaching of Turkish ch-romite concentrate[J]. Minerals Engineering, 2002,15(11):885-888. |
| [20] | Zhao Q, Liu C, Yang D , et al. A cleaner method for preparation of chromium oxide from chromite[J]. Process Safety and Environmen-tal Protection, 2016,105:91-100. |
| [21] | 刘承军, 史培阳 . 硫酸加入量对铬铁矿硫酸浸出行为的影响[J]. 工业加热, 2011,40(3):59-60. |
| [22] | Liu C J, Qi J ,Jiang M F. Experimental study on sulfuric acid leach-ing behavior of chromite with different temperature[J].Advanced Materials Research, 2011,361- 363:628-631. |
| [23] | Oghbaei M, Mirzaee O . Microwave versus conventional sintering:A review of fundamentals,advantages and applications[J]. Journal of Alloys and Compounds, 2010,494(1/2):175-189. |
| [24] | Madakkaruppan V, Pius A, Sreenivas T , et al. Influence of microwa-ves on the leaching kinetics of uraninite from a low grade ore in dilute sulfuric acid[J]. Journal of Hazardous Materials, 2016,313:9-17. |
| [25] | Yang K, Li S, Zhang L , et al. Microwave roasting and leaching of an oxide-sulphide zinc ore[J]. Hydrometallurgy, 2016,166:243-251. |
| [26] | Sadeghi S M, Vanpeteghem G , Neto I F F, et al..Selective leaching of Zn from spent alkaline batteries using environmentally friendly approaches[J]. Waste Management, 2017,60:696-705. |
| [27] | Turan M D, Sari Z A, Miller J D . Leaching of blended copper slag in microwave oven[J]. Transactions of Nonferrous Metals Society of China, 2017,27(6):1404-1410. |
| [28] | Matern K, Kletti H, Mansfeldt T . Chemical and mineralogical ch-aracterization of chromite ore processing residue from two recent Indian disposal sites[J]. Chemosphere, 2016,155:188-195. |
| [29] | Li N, Chen J, Yan H , et al. Temperature rise characteristics of car-bon-containing chromite ore fines in microwave field[J]. Journal of Iron and Steel Research,International, 2008,15(1):1-5. |
| [30] | 李成, 常国华, 彭镜鑫 , 等. 微波选择性还原处理铬铁粉矿[J]. 中国有色金属学报, 2013,23(2):503-509. |
| [31] | 李海军, 杨洪英, 陈国宝 , 等. 中心复合设计针铁矿法从含钴生物浸出液中除铁[J].中国有色金属学报, 2013(7):2040-2046. |
| [32] | Chang Y, Zhai X, Li B , et al. Removal of iron from acidic leach liq-uor of lateritic nickel ore by goethite precipitate[J]. Hydrometa-llurgy, 2010,101(1):84-87. |
| [33] | 胡国荣, 李国, 邓新荣 , 等. 针铁矿法从铬铁合金硫酸浸出液中除铁[J]. 湿法冶金, 2006,25(4):198-201. |
| [34] | 刘佳宁, 姜茂发, 李昱彤 , 等. 针铁矿法分离铬铁矿硫酸浸出液中Cr 3+与Fe 3+ [J]. 过程工程学报, 2015,15(2):242-246. |
| [35] | Ju S, Zhang Y, Zhang Y , et al. Clean hydrometallurgical route torecover zinc,silver,lead,copper,cadmium and iron from hazardous jarosite residues produced during zinc hydrometallurgy[J]. Journal of Hazardous Materials, 2011,192(2):554-558. |
| [36] | 刘鹏飞, 张亦飞, 游韶玮 , 等. 热酸浸出回收黄钾铁矾渣中有价元素[J]. 过程工程学报, 2016,16(4):584-589. |
| [37] | 李志仁, 许万祥, 朱军 , 等. 从高酸湿法炼锌渣浸出液中分离铁及回收铜、锌试验研究[J].湿法冶金, 2013(5):326-328. |
| [38] | 陈亮, 唐新村, 张阳 , 等. 从废旧锂离子电池中分离回收钴镍锰[J]. 中国有色金属学报, 2011,21(5):1192-1198. |
| [39] | 张波, 杨达朋, 赵青 , 等. 铬铁矿硫酸浸出液中Cr 3+与Fe 3+的分离[J].有色金属:冶炼部分 , 2014(7):1-3. |
| [40] | Liu C J, Zhang Q S, Shi P Y , et al.Experimental study on the effec-tive separation of chromium-iron ions in multi-component solution system by ihleite method[J].Advanced Materials Research, 2014, 887-888:707-710. |
| [41] | 蓝桥发, 黄振华, 谢芳浩 , 等. 络合法除P507-N235体系中铁的研究[J]. 中国稀土学报, 2015,33(2):188-195. |
| [42] | 张魁芳, 刘志强, 曹洪杨 , 等. 用N235从富铁高酸度硫酸浸出液中萃取除铁[J].中国有色金属学报, 2015(5):1370-1377. |
| [43] | 淡维杰, 肖连生, 张贵清 , 等. 萃取法提取铬(Ⅲ)分离铁(Ⅱ)的研究[J]. 有色金属科学与工程, 2017,8(3):35-41. |
| [44] | 魏君怡, 李勇, 薛向欣 . 基于离子液体的“可设计性”和“软酸”性质萃取分离电镀污泥中Cr 6+/Fe 3+[J]. 化工学报 , 2017(9):3451-3458. |
| [45] | 高占博 . 铬铁矿硫酸浸出新工艺的实验研究[D]. 沈阳:东北大学, 2013. |
| [46] | 胡国华 .一种从碳素铬铁中生产三氧化二铬和草酸亚铁的方法:中国,101041466[P]. 2007-09-26. |
| [47] | 杨柳, 张洋, 乔珊 , 等. 铬铁酸浸液除铁过程的草酸亚铁回收及铁黑颜料制备[J]. 过程工程学报, 2016,16(2):317-322. |
| [48] | 邢宇, 郭雪辉, 徐蓓 , 等. 草酸亚铁法水热合成磷酸铁锂的晶化条件研究[J]. 精细化工, 2017,34(10):1102-1106. |
| [49] | 叶长福, 郑会元, 劳铭 , 等. 过渡金属离子掺杂对磷酸铁锂性能的影响[J]. 材料导报B, 2017,31(1):29-32. |
| [50] | 邬建辉, 阳伦庄, 湛菁 , 等. 铬铁合金中的铬、铁分离研究[J]. 湿法冶金, 2011,30(1):51-56. |
| [51] | 王成彦, 徐志峰, 袁文辉 , 等 .一种硫酸体系溶液中铬和铁的选择性分离方法:中国,103014340[P]. 2013-04-03. |
| [52] | 徐志峰, 剧智华, 月日辉 , 等. 选择性磷酸沉淀分离铬铁的新工艺[J]. 有色金属科学与工程, 2016,7(6):19-24. |
/
| 〈 |
|
〉 |