Inorganic Chemicals Industry >
Research progress in supported lithium ion sieve absorbents
Received date: 2019-03-20
Online published: 2020-06-10
Lithium ion sieve absorbent could extract lithium ion from brine or seawater economically.However,the lithium ion sieve absorbent usually is fine powder material.It is needed to make into filler for industrial use.The critical point in this pro-cess is to obtain absorbent with high adsorption capacity and long cycle life.The existing granulation and mold forming pro-cess result in lower adsorption capacity of lithium ion sieve absorbent.It is hoped to develop supported lithium ion sieve ab- sorbent without using organic polymer binder.Several commonly used lithium ion sieve absorbents,carrier materials and loading methods were summarized.The technical requirements of supported lithium ion sieve absorbents were presented.The preparation methods of some new supported lithium ion sieve absorbents were introduced.It is recommended to focus on the development of glass fiber supported lithium ion sieve absorbent H4Ti5O12 and alumina supported lithium ion sieve absorbent LiCl·2Al（OH）3.
Key words： lithium ion sieve; absorbent; carrier
Bingguang Liu , Xiaodong Zu , Jiansheng Li , Junfeng Lu , Zejiang Wang . Research progress in supported lithium ion sieve absorbents[J]. Inorganic Chemicals Industry, 2019 , 51(9) : 12 -16 . DOI: 10.11962/1006-4990.2018-0570
| [1] | 赵旭, 张琦, 武海虹 , 等. 盐湖卤水提锂[J]. 化学进展, 2017,29(7):796-808. |
| [2] | 于潇, 孙淑英, 于建国 . 层状吸附剂提锂过程研究[J]. 无机盐工业, 2017,49(12):23-26. |
| [3] | 吴如云, 殷晓伟, 居沈贵 . 复合法制备LiMn2O4及最优条件的确定[J]. 应用化工, 2018,47(4):675-678. |
| [4] | 纪志永, 王妮, 袁俊生 , 等. 基于不同洗脱剂的单斜晶系钛基锂离子筛的制备及其吸附性能[J]. 材料导报, 2016,30(24):37-41. |
| [5] | Chaban M A, Rozhdestvenskaya L M, Palchik A V , et al. Selectivity of new inorganic ion-exchangers based on oxides of titanum and manganese at sorption of lithium from aqueous media[J]. Journal of Water Chemistry and Technology, 2016,38(1):8-13. |
| [6] | 徐占武, 岳德宇, 张蕾 , 等. 锂离子筛吸附剂及成型的研究进展[J]. 无机盐工业, 2014,46(6):12-16. |
| [7] | 王宏岩, 黄凯, 张玉生 , 等. PVC-MnO2的制备及其对锂离子的吸附行为[J]. 过程工程学报, 2018,18(4):821-827. |
| [8] | Sun D S, Meng M J, Yin Y J , et al. Highly selective,regenerated ion-sieve microfiltration porous membrane for targeted separation of Li+[J]. Journal of Porous Materials, 2016,23(6):1411-1419. |
| [9] | 李建生, 刘炳光, 王少杰 , 等. 大面积FTO透明导电薄膜制备技术研究进展[J]. 无机盐工业, 2017,49(8):1-4. |
| [10] | 王涛, 孟庆祥, 许海涛 , 等. 纳米纤维锂离子筛吸附剂的制备及表征[J]. 无机盐工业, 2016,48(3):29-33. |
| [11] | 李建生, 赵洋, 李仕增 , 等.一种玻璃纤维为基体的锂离子筛吸附膜及其制备方法:中国,108114693A[P]. 2018-06-05. |
| [12] | 刘炳光, 李建生, 刘希东 , 等. 钙钛矿太阳电池光吸收层纳米材料研究进展[J]. 无机盐工业, 2016,48(12):6-10. |
| [13] | 张理元, 杨东睿, 周大利 . 多孔陶瓷基锂离子吸附剂的制备及性能研究[J]. 四川大学学报:自然科学版, 2017,54(3):611-616. |
| [14] | 刘炳光, 尹浩南, 李仕增 , 等.一种开孔泡沫玻璃负载的锂离子筛填料及其制备方法:中国,108046368A[P]. 2018-05-18. |
| [15] | 李志勇, 李亦然, 张卫民 , 等. 磁性锂离子筛的制备及提锂性能研究[J].有色金属:冶炼部分, 2017(8):20-24. |
| [16] | Korea Institute of Geo-science and Mineral Resources.Recovery method of useful resources in seawater and brine:US,2017029920[P]. 2017-02-02. |
| [17] | Ryabtsev A D, Menzheres L T, Ten A V . Sorption of lithium from brine onto granular LiCl·2Al(OH)3·mH2O sorbent under dynamic conditions[J]. Russian Journal of Applied Chemistry, 2002,75(7):1069-1074. |
| [18] | Albemarle Corporation.Sorbents for recovery of lithium values from brines:US,2017333867[P]. 2017-11-23. |
| [19] | Albemarle Corporation.Processes for recovering lithium values from lithium-containing brines:US,2018245180[P]. 2018-08-30. |
| [20] | 四川天齐锂业股份有限公司.一种改性铝盐吸附剂及其制备方法和应用:中国,105664840A[P]. 2016-06-15. |
/
| 〈 |
|
〉 |