Inorganic Chemicals Industry >
Preparation and photocatalytic degradation property of cadmium hydroxide transformed from cadmium carbonate
Received date: 2019-10-15
Online published: 2020-04-22
Precipitated cadmium carbonate(P-CdCO3) was prepared by direct blend method with sodium carbonate solution poured into cadmium sulfate solution.Then,the as-prepared P-CdCO3 was used as raw materials to produce cadmium hydro-xide[Cd(OH)2] nanomaterials with sodium hydroxide as transforming agent.The structure and morphology of P-CdCO3 and Cd(OH)2 nanomaterials were characterized by powder X-ray diffraction(XRD) and field-emission scanning electron micro-scope(FESEM).Results showed that the structure of P-CdCO3 was destroyed and the morphology of completely transformed Cd(OH)2 was irregular sphere assembled by sheets and totally different from P-CdCO3. Photocatalytic degradation of Rhoda-mine B under irradiation of UV light tests demonstrated that the transformed products had better photocatalytic degradation property than P-CdCO3 and different transformed products had various degradation efficiencies.The Rhodamine B could be degraded completely in 180 min under irradiation of 300 W mercury lamp with addition of best transformed product when 20 mg of transformed product was added into 50 mL of 8 mg/L Rhodamine B solution and the system was stirred for 120 min in dark to reach adsorption equilibrium.
Qingchun Chen , Yu Bang , Wenjie Wan , Lean Yan , Huiyu Deng . Preparation and photocatalytic degradation property of cadmium hydroxide transformed from cadmium carbonate[J]. Inorganic Chemicals Industry, 2020 , 52(4) : 96 -99 . DOI: 10.11962/1006-4990.2019-0375
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