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Research on adsorption of Ni 2+ by carbonated hydroxyapatite/potash feldspar composite materials
Received date: 2019-08-18
Online published: 2020-02-26
The carbonated hydroxyapatite/potash feldspar composite adsorbent(CHAK) used to remove heavy metal nickel in water were prepared by liquid method with potash feldspar as the raw material.The effects of the adsorbent amount,initial so-lution pH,adsorption time and initial concentration of Ni 2+ on the adsorbability were investigated by static adsorption test.In addition,kinetics and thermodynamic were used to explore the adsorption mechanism.Results showed that with the increase of CHAK,the removal rate of Ni 2+ was increased,while the adsorption capacity of Ni 2+ was decreased.The optimal adsorption effect was obtained with the pH of 6.The adsorption equilibrium obtained with the adsorption time of 10 h.The adsorption ability of CHAK to Ni 2+ increased with the initial mass concentration of Ni 2+ at 50~4 000 mg/L,and then it reached stabilized. The saturated adsorption capacity of the CHAK was 7.1 times than that of the raw material.The kinetic and thermodynamic fitting results showed that the pseudo second order kinetic model more fitting the adsorption process.ΔH>0,it showed that the adsorption of Ni 2+ on CHAK was an endothermic process and raising the temperature was benefit to the adsorption process,ΔG<0 indicated that the adsorption was a spontaneous process.
Key words: potassium feldspar; carbonated hydroxyapatite; adsorption; Ni 2+
Ting Zhang , Huixia Zhu , Cong Han , Lina Sun , Ling Li . Research on adsorption of Ni 2+ by carbonated hydroxyapatite/potash feldspar composite materials[J]. Inorganic Chemicals Industry, 2020 , 52(2) : 30 -34 . DOI: 10.11962/1006-4990.2019-0187
[1] | Farooq U, Kozinski J A, Khan M A , et al. Biosorption of heavy metal ions using wheat based biosorbents-A review of the recent literat-ure[J]. Bioresource Technology, 2010,101:5043-5053. |
[2] | 刘羽, 胥焕岩, 黄志良 , 等. 羟基磷灰石吸附水溶液Cd 2+的影响因素的研究 [J]. 岩石矿物学杂志, 2001,20(4):583-586. |
[3] | 钱程, 张卫民 . 纳米HAP复合型材料吸附水中镍离子性能[J]. 无机盐工业, 2019,51(2):45-49. |
[4] | Yang Z M, Fang Z Q, Tang P E , et al. In situ remediation and phyto-toxiticy assessment of lead-contaminated soil by biochar-supported nHAP[J]. Journal of Environmental Management, 2016,182:247-251. |
[5] | He M, Shi H, Zhao X Y , et al. Immobilization of Pb and Cd in con-taminated soil using nano-crystallite hydroxyapatite[J]. Procedia Environmental Sciences, 2013,18:657-665. |
[6] | 车丽诗, 袁毳, 雷鸣 , 等. 改性活性炭和改性沸石去除电解锰渣淋洗液中锰离子的研究[J]. 水处理技术, 2017,43(7):76-80. |
[7] | Zhou Y T, Nie H L, Branford-White C , et al. Removal of Cu 2+ from aqueous solution by chitosan-coated magnetic nanoparticles modi-fied with aketoglutaric acid[J]. Journal of Colloid and Interface Science, 2009,330:29-37. |
[8] | Tseng R L, Wu F C . Analyzing liquid-solid phase countercurrent two-and three-stage adsorption process with the Freundlich equation[J]. Journal of Hazardous Materials, 2009,162(1):237-248. |
[9] | Yao Q, Xie J, Liu J , et al. Adsorption of lead ions using a modified lignin hydrogel[J]. Journal of Polymer Research, 2014,21(6):465-479. |
[10] | 马叶, 刘斌, 孙楠 , 等. 改性活性炭对水中铬离子(Ⅵ)的吸附性能[J]. 环境工程学报, 2014,8(7):2672-2676. |
[11] | 蓝梅, 王丽君, 张会宁 , 等. 柠檬酸改性活性炭对水中Cr(Ⅵ)的吸附性能研究[J]. 水处理技术, 2018,44(9):80-85. |
[12] | Alshameri A, Yan C, Al-Ani Y , et al. An investigation into the ad-sorption removal of ammonium by salt activated Chinese(Hulaodu)natural zeolite:Kinetics,isotherms,and thermodynamics[J]. Journal of the Taiwan Institute of Chemical Engineers, 2014,45(2):554-564. |
[13] | 马宏飞, 李薇, 韩秋菊 , 等. 废茶渣对Cr(Ⅵ)的等温吸附模型研究[J]. 科学技术与工程, 2012,12(25):323-325. |
[14] | Irani M, Amjadi M, Mousavian M A . Comparative study of lead so-rption onto natural perlite,dolomite and diatomite[J]. Chemical Engineering Journal, 2011,178(24):317-323. |
[15] | 付杰, 李燕虎, 叶长燊 , 等. DMF在大孔吸附树脂上的吸附热力学及动力学研究[J]. 环境科学学报, 2012,32(3):639-644. |
[16] | Gómez del Río J A, Morando P J, Cicerone D S . Natural materials for treatment of industrial effluents:Comparative study of the re-tention of Cd,Zn and Co by calcite and hydroxyapatite.Part Ι:Ba-tch experiments[J]. Journal of Environmental Management, 2004,71:169-177. |
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