INORGANICCHEMICALSINDUSTRY ›› 2011, Vol. 43 ›› Issue (11): 40-.

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A new process of producing borax by CO2- soda method with highefficiency,energy saving,and consumption reduction

 HU  De-Sheng, LU  Shuang-Jia, ZHONG  Jian-Chu   

  1. State Key Laboratory of Fine Chemicals,Department of Materials Science & Chemical Engineering,School of Chemical Engineering,Dalian University of Technology,Dalian 116024,China
  • Published:2011-11-09

Abstract: According to the analysis on the production of borax by CO2- soda process,the reaction in this process can be divided into three parts:initial,main,and final reaction stages.The adsorption rate is faster than the reaction rates in the initial-and final-reaction stages,while the adsorption rate is first faster than reaction rate and then gradually become the same in the main reaction stage.Based on these characters of this process,the measurements for raising CO2 partial pressure and reaction temperature were made to improve this process.The suitable process conditions were as follows:the carbonate decomposing rate for B2O3 in ascharite was 90%,reaction time was 9 h,CO2 recovery rate was more than 96% and steam consumption was 1 292 kg (1 t borax).Compared with old process,the reaction time of new process has been shorted to half one of old process and energy consumption has also been reduced significantly.The new process can reduce CO2 emission and improve environmental quality.  

Key words: CO2- soda process, borax;carbonate decomposing rate

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