分子筛快速合成技术研究进展

doi:10.19964/j.issn.1006-4990.2024-0180

Abstract

Abstract:

Zeolite is a widely used inorganic crystalline material，but its synthesis process usually takes a long time，which reduces its synthesis efficiency.Therefore，the development of rapid synthesis technology of zeolite is the key technology to improve the synthesis efficiency of zeolite，but also an important means to reduce the cost and increase the efficiency of zeolite for the actual industrial production.The progress of rapid synthesis of zeolite at home and abroad commonly used technology was introduced.The rapid synthesis technology was classified and elaborated from three aspects，including the addition of crystallization promoter，process intensification technology and other synthesis technology.The inner reason for each technology to accelerate the zeolite synthesis speed was explained and at the same time their advantages and disadvantages were analyzed.Finally，based on the characteristics of each technology combined with the current requirements for environmental protection in the actual production of zeolites，the future development direction of molecular sieve rapid synthesis technology was proposed.

Key words: zeolite, fast synthesis, synthesis efficiency, process intensification

CLC Number:

O643.36

LIU Huangfei, ZHANG Li, LIU Tao. Research progress of fast synthesis technologies of zeolites[J]. Inorganic Chemicals Industry, 2025, 57(2): 36-43.

Figures/Tables 4

Table 1

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Table 2

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项目	优点	缺点
晶种	对环境友好；成本相对较低	结构导向作用相对模板剂较弱
模板剂	结构导向作用强；部分模板剂含有造介孔的额外功能	价格相对昂贵；脱除过程需焙烧，增加成本的同时会产生对环境有害的气体
晶化促进剂	价格低廉	结构导向作用较弱，通常需配合晶种或模板剂使用
离子液体	能使分子筛在较高的温度下晶化且不会带来骨架结构的崩塌	部分离子液体对生物细胞有害；价格相对昂贵

技术	优点	缺点
超重力	能强化物料间传质且操作简单；装置易于工业化	目前使用超重力合成分子筛样本较少；装置本身不涉及传热，加速晶化效果不明显
微波	升温快，加热均匀，加速效果明显	装置自身原因导致不适合工业放大
超声波	操作简单，能强化物料间传质与均质过程	装置自身原因导致不适合工业放大；晶化加速效果相对不明显
管式反应器	装置升温快，内部凝胶不存在温度梯度	产物产量极少，且装置本身构造导致其无法大量合成分子筛
连续流动合成反应器	加速晶化效果明显，能实现分子筛的秒级合成；连续化的合成模式导致其具有工业放大潜质	对体系黏度有要求，体系黏度过高会堵塞孔道
微通道反应器	传质传热效率高；产物形貌均一	随着合成体系体量的增加，孔道堵塞概率增加，且监测难度增加

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