微晶玻璃研究进展

doi:10.19964/j.issn.1006-4990.2022-0246

Abstract

Abstract:

The research progress on categories，manufacturing methods and raw materials of glass?ceramics were reviewed.Among them，the glass?ceramics manufacturing technology aimed at waste immobilization was introduced emphatically.Starting from crystallization，the research status of crystallization process of glass ceramics was summarized，including the nucleation mechanism of different process，the development of nucleation theory and the progress of molecular dynamics simulation.The glass?ceramics technology research trends of diversification，complexity and refinement were summarized.It was considered that future research should not only pay attention to the application of various advanced characterization tools in the observation of glass crystallization process，but also need to combine experimental methods with mathematical modeling and theoretical calculation methods.In terms of application，four outstanding properties of glass?ceramics：transparency，luminescence，thermal expansion and mechanical strength were introduced，which gave it great potential in various high?tech fields.

Key words: glass?ceramics, CNT, waste immobilization, transparency, low thermal expansion

CLC Number:

TQ127.2

WANG Qin,WANG Na,HUANG Xin,WANG Ting,ZHOU Lina,BAO Ying,XIE Chuang,HAO Hongxun. Research progress on glass?ceramics[J]. Inorganic Chemicals Industry, 2022, 54(8): 1-11.

Figures/Tables 9

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体系	基础化学组成	主晶相	主要特征
硅酸盐微晶玻璃	Na₂O-Nb₂O₃-SiO₂	NaNbO₃	高透过率、强介电性
	Na₂O-CaO-MgO-SiO₂	硅灰石	易熔融
	PbO-TiO₂-SiO₂	PbTiO₃	强介电性
	Li₂O-MnO-Fe₂O₃-SiO₂	MnFe₂O₄	强磁性
	F-K₂O-MgF₂-MgO-SiO₂	四硅酸云母	易机械加工
	Li₂O-Al₂O₃-SiO₂	β-锂辉石、β-石英	低膨胀，白色不透明
	CaO-Al₂O₃-SiO₂	钙长石	耐腐蚀、耐磨
磷酸盐微晶玻璃	Na₂O-TiO₂-CaO-P₂O₅	β-Ca₂P₂O₇	良好的生物活性
磷酸盐微晶玻璃	P₂O₅-Al₂O₃-SiO₂	β-CaP₂O₃	抗高温蠕变、抗热振
硼硅酸盐微晶玻璃	BaO-Fe₂O₃-B₂O₃	BaO·6Fe₂O₃	强磁性
	PbO-ZnO-B₂O₃	硅锌矿	耐腐蚀
	ZnO-SiO₂-B₂O₃	硅锌矿	低膨胀、耐腐蚀

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Research progress on glass?ceramics

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